CAS: 17869-76-0; (But-3-Yn-2-Yloxy)Trimethylsilane

该化合物是有机硅化合物,其特点是存在三组甲基硅原子,并存在由1-甲基-2-丙基-1-醇衍生的烷氧化合物.该化合物一般是一种无色液体,由于存在丙基胺而以其活性而闻名,可参与各种化学反应,包括聚合和交叉连接过程.该化合物经常用于硅基材料的合成中,并用作硅聚合物配制中的混合剂.应当参考烷氧化合物组的存在,以提高其与有机亚酸酯的兼容性,使其在表面修改和吸附应用中有用.此外,三甲基[(1-甲基-2-丙基--1-yl)氧基]硅在一定条件下可能具有诸如低挥发性和稳定性等特性,尽管应对其处理时应当注意潜在的再活性.应当参考安全数据表,以便处理和存储建议.

结构式图片

欧盟法规

ECHA物质C&L通报

上下游产品

chloro-trimethyl-silane triethyl-(1-methyl-prop-2-ynyloxy)-stannane but-3-yn-2-ol 1,1,1,3,3,3-hexamethyl-disilazane 4-trimethylsilyl-3-butyn-2-ol (1R,4R,6S)-4-(tert-Butyl-dimethyl-silanyloxy)-2,2,6-trimethyl-1-((E)-3-trimethylsilanyloxy-but-1-enyl)-cyclohexanol (1S,4R,6S)-4-(tert-Butyl-dimethyl-silanyloxy)-2,2,6-trimethyl-1-((E)-3-trimethylsilanyloxy-but-1-enyl)-cyclohexanol 1,3,5-tris(1-(trimethylsilyloxy)ethyl)benzene

合成工艺路线路线简述

    📜3-丁炔-2-醇置于三甲基氯硅烷体系中,用60%的收率获得2-三甲基硅氧基-3-丁炔
    参考文献:Novel Acetylenic Compounds Useful As Starting Materials For Preparing An
    标题:Novel Acetylenic Compounds Useful As Starting Materials For Preparing An
    摘要:新型乙炔化合物,可用作制备β-单萜酮的起始材料.其制备过程和用途.

    海关参考信息

    专利信息


    专利号:US-4661641-A
    优先权日:1983-06-09
    标题 :Substituted alkynes useful as intermediates in the synthesis of carotenoids
    发明人:LUKAC TEODOR; SOUKUP MILAN; WIDMER ERICH
    权利人:HOFFMANN LA ROCHE
    摘要:Compounds of the formula ##STR1## wherein n is either 0 or 1; R 1 and R 2 is hydrogen and the other is hydrogen, hydroxy, oxo group, a protected hydroxy or protected oxo group; R 3 is hydroxy oxo group, â•?CH--CH 2 --OH, â•?CH--CHO or one of the foregoing groups where the hydroxy or oxo functions are protected; R 4 is --CO--OR 6 , --CO--R 6 , --CO--NR 6 R 7 , --CO--Cl or --SO 2 --R 6 ; R 6 is saturated or aromatic hydrocarbon; and R 7 is saturated or aromatic hydrocarbon or hydrogen, n are converted by cleavage of R 4 OH into corresponding cycloalkenes and protecting groups, if present, are hydrolyzed. n The compounds obtained are valuable intermediates in carotenoid syntheses.

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    ✅ COA系统入驻 | 共享模式

    合成参考文献


    摘要:Eagle, P. A. C., Science of Synthesis, (2003) 5, 748.
    摘要:Kantlehner, W., Science of Synthesis, (2005) 22, 815.
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