专利号:US-2022089618-A1 优先权日:2019-01-29 标题:Solid-State Synthesis Of Precursors Of Metal-Organic Frameworks 发明人:MAJANO GERARDO J; FALKOWSKI JOSEPH M 权利人:EXXONMOBIL RES & ENG CO 摘要:Metal-organic frameworks (MOFs) are highly porous entities comprising a multidentate ligand coordinated to multiple metal atoms, typically as a coordination polymer. MOFs are usually produced from a solvent in powder form under hydrothermal or solvothermal synthesis conditions. Alternately, powder-form precursors of MOFs may be formed by milling or mulling a substantially solid mixture of a metal salt and a multidentate organic ligand, optionally in the presence of a small amount of a solvent. The powder-form precursors may then undergo heating, typically in the absence of applied shear, to produce the corresponding MOF. Mulling may be differentiated from milling at least in that mulling applies to the substantially solid mixture at a non-constant pressure and milling applies a constant pressure while forming the powder-form precursor. In some cases, mulling may promote more effective formation of the powder-form precursor compared to milling.
专利号:US-11677077-B2 优先权日:2017-07-19 标 题:Synthesis of olivine lithium metal phosphate cathode materials 发明人:TALEBIESFANDARANI MAJID; MEHTA SEAN 权利人:NANO ONE MAT CORP 摘要:An improved process for forming a lithium metal phosphate cathode material, a precursor to the cathode material and a battery comprising the cathode material is described. The process comprising:n forming an first aqueous solution comprising a first molar concentration of Li+and a second molar concentration of PO 4 3− ; forming a second aqueous solution comprising organic acid or a salt of an organic acid and a metal selected from the group consisting of Fe, Ni, Mn and Co wherein said metal is present in a third molar concentration; allowing a precipitate to form; drying the precipitate; and calcining the precipitate thereby forming the lithium metal phosphate cathode material having a formula represented by LiMPO 4 /C wherein the lithium metal phosphate cathode material comprises up to 3 wt % carbon.
专利号:US-11505519-B2 优先权日:2019-01-17 标题 :Synthesis of organic acids from α-keto acids 发明人:SPRINGSTEEN GREGORY GARDNER; STUBBS ROBERT TRENT 权利人:FURMAN UNIV 摘要:Methods for syntheses of organic acids from α-keto acids, including methods for syntheses of isotopically enriched organic acids from α-keto acids are disclosed. The isotopically enriched organic acids are useful, for example, in metabolic flux analyses.
专利号:US-10737239-B2 优先权日:2015-11-27 标题 :Ultrafast high space-time-yield synthesis of metal-organic frameworks 发明人:BURCKHART JULIA; MARX STEFAN; ARNOLD LENA; HOFMANN CLAUS; Müller Ulrich 权利人:BASF SE 摘要:The invention relates to a process for the preparation of metal-organic frameworks (MOFs) in form of a homogenous powder, and a process wherein the metal-organic framework is molded into shaped bodies.
专利号:US-2025011531-A1 优先权日:2020-06-25 标 题:Synthesis of environmentally degradable alkyl polyesters 发明人:PARK KINAM; GARNER JOHN SOLOMON 权利人:AKINA INC 摘要:A solid crosslinked polyester composition that is environmentally degradable in less than about 180 days. The crosslinked polyester can be the polyesterification reaction product between one or more multi-hydroxylic alcohols, one or more hydroxy acids, and one or more multi-carboxylic acid compounds. Alternately, the crosslinked polyester can be the polyesterification reaction product of one or more multi-hydroxylic alcohols, one or more hydroxy acids, one or more multi-carboxylic acid compounds, and a cyclic ester. Provided, however that if the one or more hydroxy acids has only one carboxyl group, it has two or more hydroxyl groups, and if the one or more hydroxy acids has only one hydroxyl group, it has two or more carboxyl groups.
专利号:US-9951095-B2 优先权日:2014-05-16 标 题:Chromium metal organic frameworks and synthesis of metal organic frameworks 发明人:ZHOU HONG-CAI; Liu tian-fu; LIAN XIZHEN; ZOU LANFANG; FENG DAWEI 权利人:TEXAS A & M UNIV SYS 摘要:The present invention relates to monocrystalline metal organic frameworks comprising chromium ions and carboxylate ligands and the use of the same, for example their use for storing a gas. The invention also relates to methods for preparing metal organic frameworks comprising chromium, titanium or iron ions and carboxylate ligands. The methods of the invention allow such metal organic frameworks to be prepared in monocrystalline or polycrystalline forms.