CAS: 99-14-9; Propane-1,2,3-Tricarboxylic Acid

该化合物是一种三色箱酸衍生物,其应用在有机合成和协调化学中,其三个碳箱基组可产生多种反应,使其作为发泡剂或复杂分子结构的构件发挥作用.化合物具有中等水溶性,可以参与蒸发,恐吓和金属-链和相互作用.其对称结构和多功能性有利于聚合物,脱丁鱼体或金属-有机框架的合成.酸的热稳定性和界定的异晶体测量法在受控反应中具有效用.技术级材料一般是白色晶状固体,纯度通过乳化或光谱法验证.正确处理需要箱酸的标准防范措施.

结构式图片

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

CAS号499-12-7 乌头酸 | CAS号149-91-7 没食子酸; 3,4,5-三羟基苯甲酸 | CAS号7686-77-3 3-环戊烯-1-甲酸 | CAS号97-65-4 衣康酸 | CAS号88326-51-6 cyclopent-3-ene... | CAS号2922-42-1 (-)-3-去氢莽草酸 | CAS号99-67-2 2-甲基戊-4-烯酸 | CAS号585-84-2 顺乌头酸 | CAS号5247-13-2 2,6-Di(4-morpho... | CAS号6138-26-7 1,2,3-丙烷三羧酸三甲酯 | CAS号250-84-0 噻吩[2,3-B]噻吩 | CAS号77461-97-3 3-Furanacetyl c... | CAS号98546-44-2 6a-methyl-3a,4-... | CAS号4756-10-9 Tricarballylic ...

合成工艺路线路线简述

  • 110-15-6 = 99-14-9 + 141-82-2 + 6915-15-7 + 923-42-2 + 1703-58-8 + 77-92-9 + 499-12-7
    反应条件:1.1 Solvents: Water
    标题:The Possible Role Of Hydrothermal Vents In Chemical Evolution: Succinic Acid Radiolysis And Thermolysis
    作者:Cruz-Castaneda,J.; Colin-Garcia,M.; Negron-Mendoza,A.
    参考文献:Aip Conference Proceedings 日期:2014 卷标:1607(1) 页码:104-110
乌头酸置于palladium 10% On Activated Carbon,氢气体系中,用 四氢呋喃 作为反应溶剂,20.0 °C,413.69 Kpa 条件下,以97 %的收率获得产物丙三羧酸
参考文献:由柠檬酸制成的可再生且可水降解的聚酰亚胺酯
标题:由柠檬酸制成的可再生且可水降解的聚酰亚胺酯
摘要:柠檬酸是一种丰富的天然小分子,与伯胺缩合时可形成环状酰亚胺.柠檬酸的还原衍生物和甘氨酸的反应产生环状酰亚胺二酸.该单体与多种直链二醇和糖衍生二醇共聚,产生玻璃化转变温度可调的共聚物,范围为t G = 25 至 134 oc.与大多数聚酯不同,这些聚酰亚胺酯在环境相关条件下水解,因此有望成为高tg商品塑料的可持续替代品.
DOI:10.1039/d3Gc01779F

海关参考信息

专利信息


专利号:US-2022089618-A1
优先权日:2019-01-29
标题:Solid-State Synthesis Of Precursors Of Metal-Organic Frameworks
发明人:MAJANO GERARDO J; FALKOWSKI JOSEPH M
权利人:EXXONMOBIL RES & ENG CO
摘要:Metal-organic frameworks (MOFs) are highly porous entities comprising a multidentate ligand coordinated to multiple metal atoms, typically as a coordination polymer. MOFs are usually produced from a solvent in powder form under hydrothermal or solvothermal synthesis conditions. Alternately, powder-form precursors of MOFs may be formed by milling or mulling a substantially solid mixture of a metal salt and a multidentate organic ligand, optionally in the presence of a small amount of a solvent. The powder-form precursors may then undergo heating, typically in the absence of applied shear, to produce the corresponding MOF. Mulling may be differentiated from milling at least in that mulling applies to the substantially solid mixture at a non-constant pressure and milling applies a constant pressure while forming the powder-form precursor. In some cases, mulling may promote more effective formation of the powder-form precursor compared to milling.

专利号:US-11677077-B2
优先权日:2017-07-19
标 题:Synthesis of olivine lithium metal phosphate cathode materials
发明人:TALEBIESFANDARANI MAJID; MEHTA SEAN
权利人:NANO ONE MAT CORP
摘要:An improved process for forming a lithium metal phosphate cathode material, a precursor to the cathode material and a battery comprising the cathode material is described. The process comprising:n forming an first aqueous solution comprising a first molar concentration of Li+and a second molar concentration of PO 4 3− ; forming a second aqueous solution comprising organic acid or a salt of an organic acid and a metal selected from the group consisting of Fe, Ni, Mn and Co wherein said metal is present in a third molar concentration; allowing a precipitate to form; drying the precipitate; and calcining the precipitate thereby forming the lithium metal phosphate cathode material having a formula represented by LiMPO 4 /C wherein the lithium metal phosphate cathode material comprises up to 3 wt % carbon.

专利号:US-11505519-B2
优先权日:2019-01-17
标题 :Synthesis of organic acids from α-keto acids
发明人:SPRINGSTEEN GREGORY GARDNER; STUBBS ROBERT TRENT
权利人:FURMAN UNIV
摘要:Methods for syntheses of organic acids from α-keto acids, including methods for syntheses of isotopically enriched organic acids from α-keto acids are disclosed. The isotopically enriched organic acids are useful, for example, in metabolic flux analyses.

专利号:US-10737239-B2
优先权日:2015-11-27
标题 :Ultrafast high space-time-yield synthesis of metal-organic frameworks
发明人:BURCKHART JULIA; MARX STEFAN; ARNOLD LENA; HOFMANN CLAUS; Müller Ulrich
权利人:BASF SE
摘要:The invention relates to a process for the preparation of metal-organic frameworks (MOFs) in form of a homogenous powder, and a process wherein the metal-organic framework is molded into shaped bodies.

专利号:US-2025011531-A1
优先权日:2020-06-25
标 题:Synthesis of environmentally degradable alkyl polyesters
发明人:PARK KINAM; GARNER JOHN SOLOMON
权利人:AKINA INC
摘要:A solid crosslinked polyester composition that is environmentally degradable in less than about 180 days. The crosslinked polyester can be the polyesterification reaction product between one or more multi-hydroxylic alcohols, one or more hydroxy acids, and one or more multi-carboxylic acid compounds. Alternately, the crosslinked polyester can be the polyesterification reaction product of one or more multi-hydroxylic alcohols, one or more hydroxy acids, one or more multi-carboxylic acid compounds, and a cyclic ester. Provided, however that if the one or more hydroxy acids has only one carboxyl group, it has two or more hydroxyl groups, and if the one or more hydroxy acids has only one hydroxyl group, it has two or more carboxyl groups.

专利号:US-9951095-B2
优先权日:2014-05-16
标 题:Chromium metal organic frameworks and synthesis of metal organic frameworks
发明人:ZHOU HONG-CAI; Liu tian-fu; LIAN XIZHEN; ZOU LANFANG; FENG DAWEI
权利人:TEXAS A & M UNIV SYS
摘要:The present invention relates to monocrystalline metal organic frameworks comprising chromium ions and carboxylate ligands and the use of the same, for example their use for storing a gas. The invention also relates to methods for preparing metal organic frameworks comprising chromium, titanium or iron ions and carboxylate ligands. The methods of the invention allow such metal organic frameworks to be prepared in monocrystalline or polycrystalline forms.
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合成参考文献


摘要:E. Campi, G. Ostacoli, M. Meirone and G. Saini, J. Inorg. Nucl. Chem. 26, 553 (1964).
参考文献:10.1023/a:1010668521649
摘要:Spotti M, Pompa G, Caloni F. Fumonisin B1 Metabolism by Bovine Liver Microsomes. Veterinary Research Communications. 2001 Aug;25(6):511–6. doi: 10.1023/a:1010668521649.
参考文献:10.1016/j.jchromb.2004.03.052
摘要:Williams LD, Meredith FI, Riley RT. Fumonisin-ortho-phthalaldehyde derivative is stabilized at low temperature. J Chromatogr B Analyt Technol Biomed Life Sci. 2004 Jul 05;806(2):311–4. doi: 10.1016/j.jchromb.2004.03.052.
参考文献:10.1007/bf00497278
摘要:Mirocha CJ, Gilchrist DG, Shier WT, Abbas HK, Wen Y, Vesonder RF. AAL toxins, fumonisins (biology and chemistry) and host-specificity concepts. Mycopathologia. 1992 Feb;117(1-2):47–56. doi: 10.1007/bf00497278.
参考文献:10.1007/bf00497281
摘要:Norred WP, Wang E, Yoo H, Riley RT, Merrill AH. In vitro toxicology of fumonisins and the mechanistic implications. Mycopathologia. 1992 Feb;117(1-2):73–8. doi: 10.1007/bf00497281.
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