CAS: 826-34-6; Cis-Dimethyl Cyclopropane-1,2-Dicarboxylate

• 英文名称Cis-Dimethyl Cyclopropane-1,2-Dicarboxylate
• 中文名称顺-1,2-环丙烷二羧酸二甲酯
• IUPAC名称dimethyl (1R,2S)-cyclopropane-1,2-dicarboxylate
• 其它别名(顺式)-1,2-双(甲氧羰基)环丙烷; Dimethyl Cis-1,2-Cyclopropanedicarboxylate
• CAS编号826-34-6
• MFCD编号:MFCD00062805
• EINECS号:689-250-5
• 分子式:C7H10O4分子量:158.15
• 产品CID: 1816660
• 产品分类有机原料→分子砌块→脂肪环类化合物→环丙烷类化合物

• 相似结构搜索
• 产品信息参考;;;;
• InChIKey: JBVOSZYUSFDYIN-SYDPRGILSA-N
• InChI=1S/C7H10O4/c1-10-6(8)4-3-5(4)7(9)11-2/h4-5H,3H2,1-2H3/t4-,5+
• 计算化学: 氢键受体数4.0氢键供体数*可旋转键数2.0

相似化合物

物理性质

• 沸点112°C at 18 mmHg
• 闪点99°C
• 密度1.231 g/cm3
• PSA:52.6
• LogP:-0.0315
• 折射率1.4445-1.4465
• 蒸汽压0.121 mmHg at 25 °C
• 敏感性常温常压下稳定，避免与不相容材料接触。与强氧化剂反应。
• 外观形态透明无色液体
• 储存条件2-8°C
• 产品应用该化合物用于环丙基基诱杀器的环丙丙基立体异构体化,由外二醇二氧基酶催化,并附半丙酮中间体的证据.

MSDS等安全信息

• GHS象形图
• GHS符号GHS07;
  注释: Exclamation mark
• 危险类别急性毒性 类别4(经口)
• 警示词Warning(警告)
• 危险描述H302 |吞咽有害.
• 防范说明P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501
• 危险品标志Xn
• 安全声明36/37/39-26
• 危险类别码22

欧盟法规

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合成工艺路线路线简述

• 869-09-0 = 826-34-6
  反应条件:1.1 Catalysts: Ethanol
  标题:Electrochemical Reductive Cyclization Of Dimethyl Dibromoalkanedioates
  作者:Satoh,Shohei; Et Al
  参考文献:Hokkaido Daigaku Kogakubu Kenkyu Hokoku 日期:1980 卷标:(102) 页码:33-43]
  
  31448-67-6 = 826-34-6 + 826-35-7
  反应条件:1.1 Solvents: Acetonitrile1.2 Solvents: Pentane,Hexane
  标题:Stereoselective 1,3-Debromination Reactions
  作者:Liu,Yingchun; Et Al
  参考文献:Canadian Journal Of Chemistry 日期:1993 卷标:71(2) 页码:258-62]
  
  624-48-6 + 74-95-3 = 826-34-6 + 826-35-7
  反应条件:1.1 Catalysts: Triphenylphosphine (Nickel Complex),Nickel (Complexes) Solvents: Acetonitrile
  标题:Indirect Electrochemical Activation Of Gem-Dihalo Compounds - Synthetic Applications
  作者:Leonel,Eric; Et Al
  参考文献:Proceedings - Electrochemical Society 日期:2001 卷标:2001 页码:2001-14]
  
  = 826-34-6 + 826-35-7
  反应条件:1.1 Reagents: Sodium Hydride Solvents: Methanol,Toluene
  标题:Cyclopropanediamines. 3. Pure Diastereomers Of 1,2-Cyclopropanedicarboxylic Acids And Derivatives
  作者:Von Der Saal,Wolfgang; Et Al
  参考文献:Liebigs Annalen Der Chemie 日期:1989 卷标:(8) 页码:703-12]
  
  = 826-34-6 + 826-35-7
  反应条件:1.1 Reagents: Sodium Hydride
  标题:The Synthesis And Cycloaddition Reactions Of 3-Azabicyclo[3.1.0]Hex-2-Ene 3-Oxide And 3-Azabicyclo[3.2.0]Hept-2-Ene 3-Oxide. Highly Strained Bicyclic Nitrones
  作者:Tufariello,Joseph J.; Et Al
  参考文献:Tetrahedron Letters 日期:1987 卷标:28(3) 页码:267-70]
  
  30630-38-7 = 826-34-6 + 826-35-7
  反应条件:1.1 Reagents: Acetic Acid,Ammonium Acetate
  标题:Stereochemistry Of Electroreduction Of Bromocyclopropanes. Iv. New Example Of The Relation Between Stereoselectivity And The Composition Of The Supporting Electrolyte
  作者:Hazard,R.; Et Al
  参考文献:Bulletin Des Societes Chimiques Belges 日期:1985 卷标:94(3) 页码:199-204]
  
  878-14-8 = 826-34-6 + 31420-47-0
  反应条件:1.1 Reagents: Water1.2 Reagents: Thionyl Chloride2.1 0.5 H,Heated
  标题:Studies And Potential Synthesis Of Muscarinic Agents
  作者:Garst,John E.
  参考文献:1974]
  
  75-18-3 = 826-34-6 + 28363-79-3 + 624-49-7 + 14661-79-1
  反应条件:1.1 Solvents: Acetone2.1 Reagents: Sodium Hydroxide Solvents: Dichloromethane,Water3.1 Solvents: Dichloromethane
  标题:Cyclopropanediamines. 3. Pure Diastereomers Of 1,2-Cyclopropanedicarboxylic Acids And Derivatives
  作者:Von Der Saal,Wolfgang; Et Al
  参考文献:Liebigs Annalen Der Chemie 日期:1989 卷标:(8) 页码:703-12]
  
  5617-74-3 = 826-34-6
  反应条件:1.1 Reagents: Sulfuric Acid Solvents: Methanol1.2 Solvents: Water1.3 Solvents: Dichloromethane
  标题:Enantioselective Synthetic Approaches To Cyclopropane And Cyclobutane β-Amino Acids: Synthesis And Structural Study Of A Conformationally Constrained β-Dipeptide
  作者:Martin-Vila,Marta; Et Al
  参考文献:Tetrahedron: Asymmetry 日期:2000 卷标:11(17) 页码:3569-3584]
  
  110-94-1 = 826-34-6
  反应条件:1.1 Reagents: Thionyl Chloride,Bromine,Phosphorus Tribromide2.1 Catalysts: Ethanol
  标题:Electrochemical Reductive Cyclization Of Dimethyl Dibromoalkanedioates
  作者:Satoh,Shohei; Et Al
  参考文献:Hokkaido Daigaku Kogakubu Kenkyu Hokoku 日期:1980 卷标:(102) 页码:33-43]
  
  5617-74-3 = 826-34-6 + 31420-47-0
  反应条件:1.1 0.5 H,Heated
  标题:Studies And Potential Synthesis Of Muscarinic Agents
  作者:Garst,John E.
  参考文献:1974]
  
  = 826-34-6 + 826-35-7
  反应条件:1.1 Reagents: Sodium Hydride Solvents: Toluene
  标题:Secondary Deuterium Kinetic Isotope Effects At The Termini Of Cis-1,2-Divinylcyclopropane And Cis-1,2-Divinylcyclobutane In Their 3,3-Sigmatropic Shifts: Evidence For Different Transition-State Structures
  作者:Gajewski,Joseph J.; Et Al
  参考文献:Journal Of Organic Chemistry 日期:1990 卷标:55(2) 页码:674-9]
  
  30630-39-8 = 826-34-6 + 826-35-7
  反应条件:1.1 Reagents: Acetic Acid,Sodium Acetate,Tetrabutylammonium Tetrafluoroborate
  标题:Stereochemistry Of Electroreduction Of Bromocyclopropanes. Iv. New Example Of The Relation Between Stereoselectivity And The Composition Of The Supporting Electrolyte
  作者:Hazard,R.; Et Al
  参考文献:Bulletin Des Societes Chimiques Belges 日期:1985 卷标:94(3) 页码:199-204]
  
  98034-52-7 = 826-34-6 + 826-35-7
  反应条件:1.1 -2.1 Reagents: Acetic Acid,Sodium Acetate,Tetrabutylammonium Tetrafluoroborate
  标题:Stereochemistry Of Electroreduction Of Bromocyclopropanes. Iv. New Example Of The Relation Between Stereoselectivity And The Composition Of The Supporting Electrolyte
  作者:Hazard,R.; Et Al
  参考文献:Bulletin Des Societes Chimiques Belges 日期:1985 卷标:94(3) 页码:199-204]
  
  53229-58-6 = 826-34-6 + 31420-47-0
  反应条件:1.1 Reagents: Thionyl Chloride; 4 H,Rt2.1 0.5 H,Heated
  标题:Studies And Potential Synthesis Of Muscarinic Agents
  作者:Garst,John E.
  参考文献:1974]
  
  869-09-0 = 826-34-6 + 826-35-7
  反应条件:1.1 Reagents: Sodium Hydride Solvents: Dimethylformamide2.1 Reagents: Acetic Acid,Sodium Acetate,Tetrabutylammonium Tetrafluoroborate
  标题:Stereochemistry Of Electroreduction Of Bromocyclopropanes. Iv. New Example Of The Relation Between Stereoselectivity And The Composition Of The Supporting Electrolyte
  作者:Hazard,R.; Et Al
  参考文献:Bulletin Des Societes Chimiques Belges 日期:1985 卷标:94(3) 页码:199-204]
  
  18915-90-7 = 826-34-6 + 28363-79-3 + 624-49-7 + 14661-79-1
  反应条件:1.1 Solvents: Dichloromethane
  标题:Cyclopropanediamines. 3. Pure Diastereomers Of 1,2-Cyclopropanedicarboxylic Acids And Derivatives
  作者:Von Der Saal,Wolfgang; Et Al
  参考文献:Liebigs Annalen Der Chemie 日期:1989 卷标:(8) 页码:703-12]
  
  19643-31-3 = 826-34-6 + 28363-79-3 + 624-49-7 + 14661-79-1
  反应条件:1.1 Reagents: Sodium Hydroxide Solvents: Dichloromethane,Water2.1 Solvents: Dichloromethane
  标题:Cyclopropanediamines. 3. Pure Diastereomers Of 1,2-Cyclopropanedicarboxylic Acids And Derivatives
  作者:Von Der Saal,Wolfgang; Et Al
  参考文献:Liebigs Annalen Der Chemie 日期:1989 卷标:(8) 页码:703-12

海关参考信息

• 2905121000-正丙醇
  2905399002-1,4-丁二醇
  2912110000-甲醛
  2912120000-乙醛
• 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
• 详情请参考：📖 海关编码查询和海关进出口税则

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• ➥ 象形图和危险代码
• ➥ 防范代码详解
• ➥ 危险代码说明
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• ➥ REACH监管