CAS: 26054-67-1; (3Ar,4R,5R,6As)-5-Hydroxy-4-((S,E)-3-Hydroxyoct-1-En-1-yl)Hexahydro-2H-Cyclopenta[b]Furan-2-One

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(3'S)-3α,5α-Dihydroxy-2β-(3'-Hydroxy-Trans-1'-Octenyl)Cyclopentane-1α-Acetic Acid γ-Lactone 3-Tert-Butyldimethylsilyl Ether 64072-30-6
科立内脂二醇 (3Ar,4S,5R,6As)-5-Hydroxy-4-(Hydroxymethyl)Hexahydro-2H-Cyclopenta[b]Furan-2-One 32233-40-2
2H-环戊并[b]呋喃-2-酮,5-(苯甲酰氧基)六氢-4-[(1E,3S)-3-羟基-1-辛烯-1-基]-,(3Ar,4R,5R,6As)- [3Ar,4R(1E,3S),5R,6As]-5-Benzoyloxy-4-(3-Hydroxyocten-1-yl)-Hexahydro-2H-Cyclopenta[b]Furan-2-One 40834-88-6
3α,5α-Dihydroxy-2β-(3'-Oxo-Trans-1'-Octenyl)Cyclopentane-1α-Acetic Acid γ-Lactone 3-Tert-Butyldimethylsilyl Ether 64072-25-9
[1,1'-联苯]-4-羧酸,(3Ar,4R,5R,6As)-六氢-4-[(1E,3S)-3-羟基-1-辛烯-1-基]-2-氧代-2H-环戊并[b]呋喃-5-基酯(...) (1S,5R,6R,7R)-6-[(E)-3(S)-Hydroxy-1-Octenyl]-7-(4-Phenyl-Benzoyloxy)-2-Oxabicyclo[3.3.0]Octane-3-One 51014-26-7
(Z)-(1S,5R,6R,7R,1'S)-7-Benzoyloxy-6-(1'-Hydroxyoct-2'-Enyl)-2-Oxabicyclo[3.3.0]Octan-3-One 162992-65-6
(Z)-(1S,5R,6R,7R,1'R)-7-Benzoyloxy-6-(1'-Hydroxyoct-2'-Enyl)-2-Oxabicyclo[3.3.0]Octan-3-One 162897-38-3
(3Ar,4R,5R,6As)-六氢-2-氧代-4-[(1E)-3-氧代-1-辛烯基]-2H-环戊并[b]呋喃-5-基 [1,1’-联苯]-4-甲酸酯 (1S, 5R, 6R, 7R)-7-(P-Phenylbenzoyloxy)-6-<(E)-3-Oxo-1-Octenyl>-2-Oxabicyclo<3.3.0>Octan-3-One 31753-00-1 Ethyl 2-[(1R,2R,3R)-3-Hydroxy-2-[(1E,3S)-3-Hydroxyoct-1-En-1-Yl]-5-Oxocyclopentyl]Acetate 944269-24-3 (Z)-(1S,5R,6R,7R,1'R)-7-Benzoyloxy-6-(1'-N-Phenylcarbamoyloxyoct-2'-Enyl)-2-Oxabicyclo[3.3.0]Octan-3-One 162897-39-4

(1E,3S)-1-Iodo-3-(Tert-Butyldimethylsiloxy)-1-octene置于过氧乙酸,正丁基锂,Cuc5H11,硫酸,水体系中,化学反应生成2H-环戊并[b]呋喃-2-酮,六氢-5-羟基-4-[(1E,3S)-3-羟基-1-辛烯-1-基]-,(3Ar,4R,5R,6As)-(...)
参考文献:前列腺素e的对映体互补总不对称合成2和前列腺素2α
标题:前列腺素e的对映体互补总不对称合成2和前列腺素2α
摘要:使用积极发酵的酵母将外消旋酮(6)转化为非对映异构醇(7)和(8).将这些醇分离并转化为溴代醇(-)-(9)和(+)-(9).通过手性铜酸盐试剂(15)与三环酮(10)反应,将溴代醇(-)-(9)转化为前列腺素e 2(1)和前列腺素f2α(2),而溴代醇(+)-(9)通过环氧乙缩醛(11)与相同的铜酸盐试剂(15)反应而转化为前列腺素.
Doi:10.1039/p19810001317