CAS: 95910-36-4; (1Ar,4R,7R,7Bs)-1,1,4,7-Tetramethyl-1A,2,3,4,5,6,7,7B-Octahydrocyclopropa[e]Azulene

英文名称(1Ar,4R,7R,7Bs)-1,1,4,7-Tetramethyl-1A,2,3,4,5,6,7,7B-Octahydrocyclopropa[e]Azulene
中文名称(-)-异喇叭烯
其它别名1H-Cycloprop[e]azulene,1a,2,3,4,5,6,7,7b-°Ctahydro-1,1,4,7-tetramethyl-, [1aR-(1aa,4a,7a,7ba)]-; (-)-Isoledene; Isoledene
CAS编号95910-36-4
MFCD编号:MFCD00043330
分子式:C15H24分子量:204.35
产品CID: 2013766
产品分类分析化学 → 标准品 → 食品和饮料标准品

相似结构搜索
InChIKey: NUQDPKOFUKFKFD-BGOOENEXSA-N
1S/C15H24/c1-9-6-8-12-14(15(12,3)4)13-10(2)5-7-11(9)13/h9-10,12,14H,5-8H2,1-4H3/t9-,10-,12-,14-/m1/s1
计算化学: 氢键受体数*氢键供体数0.0可旋转键数0.0

物理性质

沸点95 °C5 mm Hg(文献)
闪点102.7 °C
密度0.902 g/mL at 20 °C(文献)
LogP:4.415
折射率n20/D 1.493
蒸汽压0.014 mmHg at 25 °C
储存条件2-8°C
产品应用该化合物用于使用气体色谱法与质谱测量技术结合,对ZINGIBER OFFICINALE和URTICA DIOICA L.的提取物中分析物进行定量.

上下游产品

(+)-aromadendrene [1R-(1α,3aβ,4α,7β)]-1,2,3,3a,4,5,6,7-°Ctahydro-1,4-dimethyl-7-(1-methylethenyl)-azulene 7-isopropyl-1,4-dimethyl-azulene cubenol

合成工艺路线路线简述

489-39-4 = 95910-36-4
反应条件:1.1 Catalysts: Alumina,Potassium Solvents: Hexane; 20 °C
标题:Potassium On Alumina
作者:Fuerstner,Alois
参考文献:E-Eros Encyclopedia Of Reagents For Organic Synthesis 日期:2001 卷标:1 页码:1-2]

489-39-4 = 95910-36-4
反应条件:1.1 Reagents: Alumina,Potassium Solvents: Hexane; Overnight
标题:Chemistry Of (+)-Aromadendrene. Part 6: Rearrangement Reactions Of Ledene,Isoledene And Their Epoxides
作者:Moreno-Dorado,F. Javier; Lamers,Yvonne M. A. W.; Mironov,Grigore; Wijnberg,Joannes B. P. A.; De Groot,Aede
参考文献:Tetrahedron 日期:2003 卷标:59(39) 页码:7743-7750]

489-39-4 + 25246-27-9 = 95910-36-4
反应条件:1.1 Reagents: Alumina,Potassium Solvents: Hexane
标题:Thermal Rearrangement Of Bicyclogermacrane-1,8-Dione. Synthesis Of Humulenedione And (-)-Cubenol,Starting From Natural (+)-Aromadendrene. V
作者:Gijsen,Harrie J. M.; Wijnberg,Joannes B. P. A.; De Groot,Aede
参考文献:Tetrahedron 日期:1994 卷标:50(16) 页码:4745-54]

489-39-4 = 95910-36-4
反应条件:1.1 Reagents: Potassium Catalysts: Alumina; 200 °C; Rt -> 0 °C; 200 °C -> Rt1.2 Solvents: Hexane; 0 °C -> Rt; Overnight,Rt
标题:Convenient Synthesis Of Deuterium Labelled Sesquiterpenes
作者:Duhamel,Nina; Martin,Damian; Larcher,Roberto; Fedrizzi,Bruno; Barker,David
参考文献:Tetrahedron Letters 日期:2016 卷标:57(40) 页码:4496-4499]

489-39-4 = 95910-36-4
反应条件:1.1 Catalysts: Alumina,Potassium Solvents: Hexane
标题:Catalytic Conversion Of Sesquiterpene Hydrocarbons On Alkali Metal/aluminum Oxide Contacts
作者:Rienaecker,Roland; Graefe,Juergen
参考文献:Angewandte Chemie 日期:1985 卷标:97(4) 页码:348-9]

72747-25-2 = 95910-36-4
反应条件:1.1 Reagents: Potassium Solvents: Hexane; 20 °C
标题:Potassium On Alumina
作者:Fuerstner,Alois
参考文献:E-Eros Encyclopedia Of Reagents For Organic Synthesis 日期:2001

海关参考信息

2901210000-乙烯
2901220000-丙烯
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合成参考文献

参考文献:10.1002/ffj.1547
摘要:Raina VK, Verma SC, Dhawan S, Khan M, Ramesh S, Singh SC, Yadav A, Srivastava SK. Essential oil composition ofMurraya exotica from the plains of northern India. Flavour Fragr. J. 2005;21(1):140–2. doi: 10.1002/ffj.1547.
参考文献:10.1016/s0031-9422(99)00383-0
摘要:Warmers U, König WA. (−)-7-epi-Isojunenol and (+)-7-epi-junenol, constituents of the liverwort Tritomaria quinquedentata. Phytochemistry. 1999 Dec;52(8):1519–24. doi: 10.1016/s0031-9422(99)00383-0.