CAS: 852-38-0; 2-([1,1-Biphenyl]-4-yl)-5-Phenyl-1,3,4-Oxadiazole

该化合物是一种有机化合物,其特点是氧化二氮环结构,由五人环中的两个氮原子和三个碳原子组成,该化合物具有双联苯和苯基替代成分的特点,有助于其芳香特性,并有可能影响其电子特性.该化合物一般在室温下是固体,可能具有荧光性,因此对材料科学,特别是有机发光二极管(OLEDs)和其他光电学应用感兴趣.多种芳烃组的存在可增强有机溶剂的稳定性和溶性.此外,该化合物可能具有有趣的光物理特性,对光化学和光物理的研究很有价值.其合成通常涉及环化反应,并可能因其在有机合成中的潜在应用以及作为先进材料开发的构件而加以研究.

结构式图片

相似化合物

2043-06-3 725-12-2 825-56-9

物理性质

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上下游产品

Biphenyl-4-carboxylic acid [1-phenyl-meth-(E)-ylidene]-hydrazide benzoic acid hydrazide biphenyl-4-carboxylic acid 2-(4'-bromoacetylbiphenyl-4-yl)-5-phenyl-1,3,4-oxadiazole 2-(4'-bromobiphenyl-4'-yl)-5-phenyl-1,3,4-oxadiazole 2-(2',4',5'-tribromobiphenyl-4-yl)-5-phenyl-1,3,4-oxadiazole 4-(5-phenyl-1,3,4-oxadiazole-2-yl)-biphenyl-4'-yl sulfonic acid

合成工艺路线路线简述

  • 3597-91-9 + 613-94-5 = 852-38-0
    反应条件:1.1 Reagents: Tetraethylammonium Bromide,N-Hydroxyphthalimide,Tetraethylammonium P-Toluenesulfonate Solvents: Acetonitrile,2,2,2-Trifluoroethanol; 3 H,25 °C1.2 7 H,25 °C
    标题:Electrochemical One-Pot Synthesis Of Five-Membered Azaheterocycles Via [4 + 1] Cyclization
    作者:Wang,Qiang; Wang,Xincan; Liu,Qiang; Xie,Guanqun; Ding,Shujiang; Et Al
    参考文献:Organic Chemistry Frontiers 日期:2020 卷标:7(23) 页码:3912-3917]

    100989-00-2 = 852-38-0
    反应条件:1.1 Reagents: Phosphorus Oxychloride; 10 H,Reflux1.2 Reagents: Sodium Carbonate Solvents: Water; Neutralized
    标题:17O Nmr Studies Of Substituted 1,3,4-Oxadiazoles
    作者:Gierczyk,Blazej; Zalas,Maciej; Kazmierczak,Marcin; Grajewski,Jakub; Pankiewicz,Radoslaw; Et Al
    参考文献:Magnetic Resonance In Chemistry 日期:2011 卷标:49(10) 页码:648-654]

    613-94-5 + 3218-36-8 = 852-38-0
    反应条件:1.1 Reagents: Tetrabutylammonium Iodide,Sodium Carbonate Catalysts: Ferrocene,Platinum Solvents: Dimethylformamide,Water; 6 H,25 °C
    标题:Electrocatalytic Synthesis Of 2,5-Disubstituted 1,3,4-Oxadiazoles
    作者:Li,Mengfan; Wang,Rong; Hao,Wenjuan; Jiang,Bo
    参考文献:Youji Huaxue 日期:2020 卷标:40(6) 页码:1540-1548]

    100989-00-2 = 852-38-0
    反应条件:1.1 Reagents: Trichloroacetonitrile,Triphenylphosphine (Polymer-Supported) Solvents: Acetonitrile; 20 Min,150 °C
    标题:A Simple And Efficient One Step Synthesis Of 1,3,4-Oxadiazoles Utilizing Polymer-Supported Reagents And Microwave Heating
    作者:Wang,Ying; Sauer,Daryl R.; Djuric,Stevan W.
    参考文献:Tetrahedron Letters 日期:2006 卷标:47(1) 页码:105-108]

    412956-37-7 = 852-38-0
    反应条件:1.1 Reagents: Potassium Carbonate,Hydrogen Peroxide Catalysts: Iodine Solvents: Dimethyl Sulfoxide,Water; Rt; 7 H,Rt
    标题:Iodine-Catalysed Oxidative Cyclization Of Acylhydrazones To 2,5-Substituted 1,3,4-Oxadiazoles
    作者:Majji,Ganesh; Rout,Saroj Kumar; Guin,Srimanta; Gogoi,Anupal; Patel,Bhisma K.
    参考文献:Rsc Advances 日期:2014 卷标:4(11) 页码:5357-5362]

    613-94-5 + 3218-36-8 = 852-38-0
    反应条件:1.1 Solvents: Tert-Butanol; 2 - 3 H,Reflux; Reflux -> 0 °C1.2 Reagents: Sodium Hypochlorite Solvents: Water; 1 - 2 H,Rt
    标题:Sodium Hypochlorite-Mediated Synthesis Of 2,5-Disubstituted 1,3,4-Oxadiazoles From Hydrazides And Aldehydes
    作者:Paidi,Karuna Raman; Kolli,Murali Krishna; Reddy,Eeda Koti; Pedakotla,Venkata Ramana
    参考文献:Chemistry Of Heterocyclic Compounds (New York 日期:2020 卷标:56(3) 页码:371-376]

    591-50-4 + 7188-38-7 + 18622-23-6 = 852-38-0
    反应条件:1.1 Reagents: Sodium Acetate Catalysts: 1,3-Bis(Diphenylphosphino)Propane,Palladium Chloride Solvents: Dimethylformamide; 3 H,130 °C
    标题:Palladium-Catalyzed One-Pot Synthesis Of Diazoles Via Tert-Butyl Isocyanide Insertion
    作者:Fan,Xiang-Yuan; Jiang,Xiao; Zhang,Ying; Chen,Zhen-Bang; Zhu,Yong-Ming
    参考文献:Organic & Biomolecular Chemistry 日期:2015 卷标:13(41) 页码:10402-10408
📜4-联苯基羧酸肼置于吡啶,三氯氧磷体系中,化学反应 10.0H,反应生成 2-(4-联苯基)-5-苯基恶二唑
参考文献:取代的1,3,4-恶二唑的17 O NMR研究.
标题:取代的1,3,4-恶二唑的17 O NMR研究.
摘要:通过(17)o NMR光谱研究了三个系列的取代的1,3,4-恶二唑.化学位移值与经验的哈米特参数以及计算的键长和化学屏蔽值相关.
DOI:10.1002/mrc.2804

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[参考文献]: Wang C, Et Al. Polymeric Alkoxy Pbd [参考文献]: Coleman T Turgeon, Et Al. Streamlined Determination Of Lysophosphatidylcholines In Dried Blood Spots For Newborn Screening Of X-Linked Adrenoleukodystrophy. Mol Genet Metab. 2015 Jan;114(1):46-50.
[参考文献]: Guizhong Zhang, Et Al. Tipe2 Protein Prevents Injury-Induced Restenosis In Mice. Biochim Biophys Acta. 2015 Aug;1852(8):1574-84.
[参考文献]: Hyun-Kyung Ko, Et Al. Suppression Of Chemotaxis By Ssecks Via Scaffolding Of Phosphoinositol Phosphates And The Recruitment Of The Cdc42 Gef, Frabin, To The Leading Edge. Plos One. 2014 Oct 30;9(10):E111534.
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摘要:Weaver, G. W., Science of Synthesis, (2004) 13, 238.
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