CAS: 555-10-2; 3-Isopropyl-6-Methylenecyclohex-1-Ene

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📜4-Isopropyl-1-Trimethylsilyloxy-1-Cyclohexen置于正丁基锂,氧气,Palladium Diacetate体系中,用 四氢呋喃,二甲基亚砜 作为反应溶剂,化学反应 37.67H,反应生成 3-异丙基-6-亚甲基-1-环己烯
参考文献:(+)-Adunctins C 和 D 的总合成:分配它们的绝对构型
标题:(+)-Adunctins C 和 D 的总合成:分配它们的绝对构型
摘要:(+)-Adunctin C (Ent-1) 和 (+)-Adunctin D (2) 是从piper Aduncum (Piperaceae) 中分离出来的两种单萜取代的二氢查尔酮,首次实现了全合成.开发了酰基间苯三酚与 (-)-β-水芹烯的区域选择性氧化 [3 + 2] 环加成,以构建其独特的螺苯并呋喃骨架.因此,通过这些努力分配了天然 Adunctins 1和2的绝对构型.
DOI:10.1039/d1Ob02055B

专利信息

专利号:US-2007276042-A1
优先权日:2006-05-26
标题:Preparation and utility of substituted carboxylic acid compounds
发明人：GANT THOMAS G; SARSHAR SEPEHR; WOO SOON HYUNG
权利人:AUSPEX PHARMACEUTICALS INC
摘要:The present disclosure is directed to modulators of cyclooxygenase (COX) enzymes and pharmaceutically acceptable salts and prodrugs thereof, the chemical synthesis thereof, and the medical use of such compounds for the treatment and/or management of the severity and duration of non-specific pain, tension-type pain, headache, migraine, lower back pain, sciatica, dental pain, muscular pain, pain associated with acute soft tissue injuries, bursitis, tendonitis, lumbago, periarthritis, tennis elbow, sprains, strains, muscular problems associated with sports injuries, muscular problems associated with accidents, period pain, primary dysmenorrhoea, acute sore throat pain, osteoarthritis, rheumatoid arthritis, cancer, any disorder requiring analgesic response, any disorder requiring anti-inflammatory response, any disorder requiring antipyretic response, any conditions mediated by cyclooxygenase, cystic fibrosis, dementia, Alzheimer's disease, and/or conditions mediated by levels of β-amyloid are described.

专利号:CN-114107368-A
优先权日:2021-11-29
标题 :Combined expression vector expressing trans chrysanthemic acid and its application in regulating the synthesis of trans chrysanthemic acid in tomato type VI glandular hairs

专利号:CN-117363635-A
优先权日:2023-11-27
标题:A gene and biological enzyme that catalyzes the synthesis of β-phellandrene and its application in the production of β-phellandrene

专利号:CN-114107368-B
优先权日:2021-11-29
标题 :A combined expression vector expressing trans chrysanthemic acid and its application in regulating the synthesis of trans chrysanthemic acid in tomato type VI glandular trichomes

专利号:US-8338663-B2
优先权日:2001-02-12
标 题:Isoprenoid synthases
发明人：AHARONI ASAPH; JONGSMA MAARTEN ANTHONIE; VERHOEVEN HENRICUS ADRIANUS; BOUWMEESTER HENDRIK JAN
权利人:AHARONI ASAPH; JONGSMA MAARTEN ANTHONIE; VERHOEVEN HENRICUS ADRIANUS; BOUWMEESTER HENDRIK JAN; MONSANTO INVEST NV; ENZA ZADEN BEHEER BV
摘要:The invention relates to the field of genetic engineering of flavor, fragrance and biocontrol agent development. More specifically it relates to a process for production of natural flavors, fragrances or bio-control agents by the control of one or more genes implicated in that process. The invention provides an isolated or recombinant nucleic acid or functional fragment thereof encoding a proteinaceous molecule essentially capable of flavor, fragrance and/or bio-control agent synthesis when provided with a suitable substrate under appropriate reaction conditions. The invention further provides a nucleic acid or functional fragment thereof encoding a proteinaceous molecule essentially capable of synthesizing at least a monoterpene alcohol linalool when contacted with geranyl diphosphate (GPP) and/or at least a sesquiterpene alcohol nerolidol when contacted with farnesyl diphosphate (FPP) under appropriate reaction conditions.

专利号:CN-107056587-A
优先权日:2017-05-17
标 题:A kind of method of synthesis L menthols