CAS: 4208-64-4; 1-(Furan-2-yl)Ethanol

该化合物是一种有机化合物,其特征是其呋喃环结构,即五人组成的含有一个氧原子的芳香环,该化合物的特征是附于呋喃环的氢氧甲基组(-CH2OH)和甲基组(-CH3),其独特的化学特性是其独特的化学特性.它一般是一种无色的淡黄色液体,具有独特的气味. -甲基-2-呋喃乙醇在水和有机溶剂中溶解,使其在各种应用中具有多种特性.它的再活性受水氧化甲基组的存在的影响,该组可参与各种化学反应,包括氧化和酯化.这一化合物对有机合成和材料科学领域具有兴趣,因为它可以作为更复杂的分子的建筑块.此外,它可能展示生物活动,使其成为医药化学研究的一个主题.

结构式图片

相似化合物

27948-61-4 112653-32-4 1192-62-7

物理性质

MSDS等安全信息

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上下游产品

CAS号98-01-1 糠醛 | CAS号74-88-4 碘甲烷 | CAS号1192-62-7 2-乙酰基呋喃 | CAS号917-54-4 甲基锂 | CAS号676-58-4 甲基氯化镁 | CAS号75-24-1 三甲基铝 | CAS号4208-64-4 DL-1-(2-呋喃基)乙醇 | CAS号33647-67-5 DL-1-(2,5-Dimet... | CAS号917-64-6 甲基碘化镁 | CAS号3249-33-0 4-羰基己酸乙酯 | CAS号508-93-0 (3beta,5beta)-3... | CAS号56311-37-6 5-乙基呋喃-2-羧酸 | CAS号482-39-3 阿福豆苷 | CAS号23535-17-3 4-hydroxy-2-met... | CAS号609-38-1 2-糠酰胺 | CAS号4208-64-4 DL-1-(2-呋喃基)乙醇 | CAS号118-71-8 麦芽酚 | CAS号33156-28-4 兰诺地近 | CAS号1192-62-7 2-乙酰基呋喃

合成工艺路线路线简述

    📜2-乙酰基呋喃置于sodium Tetrahydroborate体系中,用 甲醇 作为反应溶剂,化学反应生成 Dl-1-(2-呋喃基)乙醇
    参考文献:光学活性4-羟基-5-烷基环戊-2-烯-1-酮衍生物的化学酶学方法:圆二色谱和dft组合计算在绝对构型分配中的应用
    标题:光学活性4-羟基-5-烷基环戊-2-烯-1-酮衍生物的化学酶学方法:圆二色谱和dft组合计算在绝对构型分配中的应用
    摘要:由各自的2-呋喃基甲基甲醇经piancatelli重排,然后通过消旋体的酶促动力学拆分,制备了一系列具有代表性的4-羟基-5-烷基环戊-2-烯-1-酮的光学活性衍生物.证明了按摩方法(实验和计算的电子圆二色性[ecd]和振动圆二色性[vcd]光谱)可用于确定4-羟基-5-甲基环戊-2-烯-1-烯中两个立体反应生成中心的绝对构型.还证明了ecd和vcd光谱学的同时应用可用于确定两个立体反应生成中心的构型.手性26:300-306,2014.©2014 Wiley Periodicals,Inc.
    DOI:10.1002/chir.22322

    专利信息


    专利号:US-9944869-B2
    优先权日:2007-03-08
    标 题 :Synthesis of liquid fuels and chemicals from oxygenated hydrocarbons
    发明人：CORTRIGHT RANDY D; BLOMMEL PAUL G
    权利人:VIRENT INC
    摘要:Processes and reactor systems are provided for the conversion of oxygenated hydrocarbons to hydrocarbons, ketones and alcohols useful as liquid fuels, such as gasoline, jet fuel or diesel fuel, and industrial chemicals. The process involves the conversion of mono-oxygenated hydrocarbons to aromatics and gasoline range hydrocarbons where the oxygenated hydrocarbons are derived from biomass.

    专利号:US-8350108-B2
    优先权日:2008-08-27
    标题 :Synthesis of liquid fuels from biomass
    发明人：CORTRIGHT RANDY D; BLOMMEL PAUL G; WERNER MICHAEL J; VANSTRATEN MATTHEW R
    权利人:VIRENT INC; CORTRIGHT RANDY D; BLOMMEL PAUL G; WERNER MICHAEL J; VANSTRATEN MATTHEW R
    摘要:Processes and reactor systems are provided for the conversion of oxygenated hydrocarbons to paraffins useful as liquid fuels. The process involves the conversion of water soluble oxygenated hydrocarbons to oxygenates, such as alcohols, furans, ketones, aldehydes, carboxylic acids, diols, triols, and/or other polyols, followed by the subsequent conversion of the oxygenates to paraffins by dehydration and alkylation. The oxygenated hydrocarbons may originate from any source, but are preferably derived from biomass.

    专利号:US-2008300434-A1
    优先权日:2007-03-08
    标题 :Synthesis of liqiud fuels and chemicals from oxygenated hydrocarbons

    专利号:US-2010076233-A1
    优先权日:2008-08-27
    标 题 :Synthesis of liquid fuels from biomass

    专利号:EP-2698416-B1
    优先权日:2007-03-08
    标题:Synthesis of Liquid Fuels from Oxygenated Hydrocarbons
    发明人：CORTRIGHT RANDY D; BLOMMEL PAUL G
    权利人:VIRENT INC

    专利号:US-2008216391-A1
    优先权日:2007-03-08
    标题:Synthesis of liquid fuels and chemicals from oxygenated hydrocarbons

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    主要参考文献

    参考标题:2-Acyloxy-4,6-Dimethoxy-1,3,5-Triazine - A New Reagent For Ester Synthesis
    作者:Janina E. Kamińska,Zbigniew J. Kamiński,Józef Góra |发布日期:1999.4
    摘要:2-Acyloxy-4,6-Dimethoxy-1,3,5-Triazines Obtained In Reaction Between Carboxylic Acid And 2-Chloro-4,6-Dimethoxy-1,3,5-Triazine Were Used As Acylating Agents For The Synthesis Of Esters From Primary, Secondary, And Tertiary Alcohols. Because Of Mild Acylation Conditions The Method Could Be Applied To Esterification Of Labile Alcohols With Aromatic And Aliphatic (Also î+/--Branched) Acids In Good Yields.

    合成参考文献


    摘要:Scammells, P. J., Science of Synthesis Knowledge Updates, (2013) 2, 448.
    摘要:Stoltz, B.; Ebner, D. C.; Park, N., Science of Synthesis: Stereoselective Synthesis, (2011) 2, 210.
    摘要:Arai, N.; Ohkuma, T., Science of Synthesis: Stereoselective Synthesis, (2011) 2, 30.
    摘要:Scammells, P. J., Science of Synthesis Knowledge Updates, (2013) 2, 445.
    摘要:Zaidlewicz, M.; Pakulski, M. M., Science of Synthesis: Stereoselective Synthesis, (2011) 2, 90.
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