CAS: 14275-61-7; (E)-1,2-Bis(Tributylstannyl)Ethene

该化合物是一种有机锡化合物,其特点是稳定的跨配置和双重三丁基斯坦尼基功能组,这种试剂在Stille交叉反应中特别宝贵,它作为合成聚合有机框架的多功能构件,包括聚合物和小分子,与丙烯和乙烯卤化物的高反应性能够在温和条件下高效形成碳碳-碳联结.由于化合物的稳定性和选择性,它适合于材料科学和制药中间体的应用.由于有机锡化合物的毒性,需要用于受控制的环境,适当的处理是必不可少的.建议在惰性条件下储存,以保持其再活动性.

结构式图片

相似化合物

7486-35-3 100073-15-2 24850-33-7

欧盟法规

C&L通报

上下游产品

CAS号495-71-6 1,2-联苯甲酰乙烷 | CAS号959-28-4 反-1,2-二苯甲酰乙烯 | CAS号81255-96-1 4-phenylcyclope...

合成工艺路线路线简述

    海关参考信息

    专利信息


    专利号:US-10954178-B1
    优先权日:2020-08-28
    标题 :Synthesis of haloindenes
    发明人:WNUK STANISLAW F; HOWLADER MD ABU HASAN
    权利人:WNUK STANISLAW F; HOWLADER MD ABU HASAN; THE FLORIDA INTERNATIONAL UNIV BOARD OF TRUSTEES
    摘要:The subject invention provides an expedited synthesis of 5, 6, and 7-iodoindenes from the corresponding aminoindan-1-ones in more than 70% yield, employing readily available precursors and reagents. A three-step sequence involves diazotization-iodination of aminoindan-1-one followed by reduction and dehydration. The method has a general character and can be extended for the preparation of various 4-, 5-, 6- or 7-haloindenes using different halogen sources for diazotization-halogenation reaction.

    专利号:WO-9741109-A1
    优先权日:1996-04-26
    标 题 :Synthesis of (±) - calicheamicinone, precursors, intermediates and derivatives
    发明人:CLIVE DERRICK L J; DAIGNEAULT SYLVAIN; BO YUNXIN; TAO YONG
    权利人:UNIV ALBERTA; CLIVE DERRICK L J; DAIGNEAULT SYLVAIN; BO YUNXIN; TAO YONG
    摘要:This invention relates to calicheamicinone and related compounds, and processes for the preparation of these compounds and derivatives or analogs thereof. Many of the products that can be synthesized using these compounds have antibiotic activity including, but not limited to, anticancer, antifungal or antimicrobial activity.

    专利号:US-5693792-A
    优先权日:1992-02-18
    标 题 :β-lactam and cephem compounds and processes for their production
    发明人:TORII SHIGERU; TANAKA HIDEO; SASAOKA MITIO; SHIROI TAKASHI; KAMEYAMA YUTAKA
    权利人:OTSUKA KAGAKU KK
    摘要:The object of the invention is to provide a β-lactam compound and a 2-substituted methyl-3-cephem compound, both of which are of value as intermediates for the synthesis of cephem antibiotics. n The β-lactam compound of the invention may be represented by the general formula ##STR1## wherein R 1 represents a protected amino group, for instance; R 2 represents hydrogen, for instance; R 3 represents hydrogen or a carboxy-protecting group; R 4 represents an aryl group which may be substituted; R 5 represents an alkenyl group which may be substituted, for instance. The 2-substituted methyl-3-cephem compound of the invention may be represented by the general formula ##STR2## wherein R 1 , R 2 and R 3 are as defined above; R 6 represents an aryl group which may be substituted.

    专利号:TW-I458750-B
    优先权日:2011-05-05
    标题 :Synthesis of low energy gap carbazole copolymerized polymer with electron donor-electron acceptor-electron donor monomer structure and its application in organic polymer solar cell

    专利号:EP-1935869-A1
    优先权日:2000-10-02
    标题:Retinoids for the treatment of emphysema
    发明人:LAPIERRE JEAN MARC; ROTSTEIN MARC; SJOGREN ERIC BRIAN
    权利人:HOFFMANN LA ROCHE
    摘要:The current invention provides novel retinoid compounds and methods for their synthesis, the use of such compounds for the preparation of medicaments for treating or preventing emphysema, cancer and dermatological disorders, methods for such deseases and pharmaceutical compositions suitable for the treatment or prevention of emphysema, cancer and dermatological disorders.

    专利号:AT-521203-A1
    优先权日:2018-05-14
    标题:Synthesis of alkylthio-substituted poly (p-phenylene-vinylene) polymers

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    合成参考文献


    摘要:Koo, S., Science of Synthesis, (2010) 45, 1382.
    摘要:Pu, L., Science of Synthesis, (2010) 45, 689.
    摘要:Koo, S., Science of Synthesis, (2010) 45, 1351.
    摘要:Negishi, E.; Wang, G., Science of Synthesis, (2009) 46, 315.
    摘要:Negishi, E.; Wang, G., Science of Synthesis, (2009) 46, 256.
    📝 需求与反馈
    尽可能描述清楚需求与问题信息
    ×

    通知