CAS: 13428-80-3; Ethanolate,Hafnium(4+)

该化合物是有机金属化合物,其特征是它与过渡性金属相协调,通常看起来像是无色的淡黄色液体,以其血色为蓝色,以其血红色性质而著称,意思是它很容易吸收空气中的湿度.该化合物在诸如酒精和醚等有机溶剂中溶解,使其在各种化学应用中有用,特别是在材料科学和催化领域.氢氧化物经常被用作氢氧化物薄膜合成的前体,这在半导体技术和光学涂层中非常重要.该化合物可以进行水解,导致氧化形成,特别是在水中.由于它具有再活性,处理氢氧化亚氢需要谨慎,因为它能够与水和其他核素发生反应.

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ethanol

合成工艺路线路线简述

    📜Hafnium Borohydride置于c2H5Oh体系中,用 正戊烷 用作溶剂,化学反应生成乙醇铪,硼酸三乙酯
    参考文献:Petrova,L. A.; Borisov,A. P.; Makhaev,V. D.,Koordinatsionnaya Khimiya,1992,Vol. 18,P. 425-428
    标题:Petrova,L. A.; Borisov,A. P.; Makhaev,V. D.,Koordinatsionnaya Khimiya,1992,Vol. 18,P. 425-428

    海关参考信息

    专利信息


    专利号:US-9896523-B2
    优先权日:2015-06-26
    标题 :Ziegler-Natta catalyst synthesis and process thereof
    发明人:SINGH GURMEET; KUMAR NARESH; KAUR SUKHDEEP; BANTU BHASKER; KAPUR GURPREET SINGH; SHASHIKANT
    权利人:INDIAN OIL CORP LTD
    摘要:The present invention describes a process of preparing a catalyst for olefin polymerization comprising: (i) treating a magnesium metal with an organohalide along with an internal donor to obtain a reaction mixture having solid component (A); (ii) treating the reaction mixture having solid component (A) with an acyl halide to obtain a reaction mixture having solid component (B); and (iii) treating the reaction mixture having solid component (B) of step (ii) with a transition metal compound to obtain the catalyst. The present invention also relates to a process for preparation of a catalyst system from said catalyst and preparation of a polyolefins from the catalyst system.

    专利号:US-12257557-B2
    优先权日:2018-08-02
    标题 :Bonded body, separation membrane module equipped with same, and method for producing alcohol
    发明人:ONUKI MASAMICHI; SAKAMOTO NAOYUKI; TSUTSUMINAI SUSUMU; ENDOU KOETSU; FUJITA NAOKO; HARA MISA; KUJIME MASAHIRO; TORATANI NOBUO
    权利人:MITSUBISHI CHEM CORP; JAPAN TECH RESEARCH ASSOCIATION OF ARTIFICIAL PHOTOSYNTHETIC CHEMICAL PROCESS
    摘要:The present invention addresses the problem of providing a bonded body which has a high airtightness and exhibits excellent durability under high-temperature and high-pressure conditions. This problem is solved by a bonded body in which a complex of a zeolite and an inorganic porous support, and a dense member are bonded together by an inorganic glass or an inorganic adhesive. The inorganic glass or the inorganic adhesive has a thermal expansion coefficient of 30×10−7/K to 90×10−7/K, and the inorganic glass has a softening point of 550° C. or lower. The present invention also addresses the problem of providing a method of efficiently producing an alcohol by installing a separation membrane in an alcohol synthesis reactor based on a bonding method that gives good sealing performance and durability under high-temperature and high-pressure conditions and in the presence of methanol vapor. This problem can be solved by an alcohol production method of obtaining an alcohol by allowing a raw material gas, which contains at least hydrogen and carbon monoxide and/or carbon dioxide, to react in the presence of a catalyst in a reactor. In the reactor for carrying out the reaction, an alcohol-selective permeable membrane bonded with a dense member is installed, and an alcohol generated by the reaction permeates and is recovered through the selective permeable membrane.

    专利号:US-8920675-B2
    优先权日:2010-10-27
    标题 :Synthesis, capping and dispersion of nanocrystals
    发明人:XU WEI; GONEN WILLIAMS ZEHRA SERPIL; WANG YIJUN; WIACEK ROBERT J; BAI XIA; GOU LINFENG; THOMAS SELINA I; XU JUN
    权利人:XU WEI; GONEN WILLIAMS ZEHRA SERPIL; WANG YIJUN; WIACEK ROBERT J; BAI XIA; GOU LINFENG; THOMAS SELINA I; XU JUN; PIXELLIGENT TECHNOLOGIES LLC
    摘要:Preparation of semiconductor nanocrystals and their dispersions in solvents and other media is described. The nanocrystals described herein have small (1-10 nm) particle size with minimal aggregation and can be synthesized with high yield. The capping agents on the as-synthesized nanocrystals as well as nanocrystals which have undergone cap exchange reactions result in the formation of stable suspensions in polar and nonpolar solvents which may then result in the formation of high quality nanocomposite films.

    专利号:US-9856581-B2
    优先权日:2010-04-23
    标 题 :Synthesis, capping and dispersion of nanocrystals
    发明人:GONEN WILLIAMS ZEHRA SERPIL; WANG YIJUN; WIACEK ROBERT J; BAI XIA; GOU LINFENG; THOMAS SELINA I; XU WEI; XU JUN; PATEL RAKESH
    权利人:PIXELLIGENT TECH LLC
    摘要:Preparation of semiconductor nanocrystals and their dispersions in solvents and other media is described. The nanocrystals described herein have small (1-10 nm) particle size with minimal aggregation and can be synthesized with high yield. The capping agents on the as-synthesized nanocrystals as well as nanocrystals which have undergone cap exchange reactions result in the formation of stable suspensions in polar and nonpolar solvents which may then result in the formation of high quality nanocomposite films.

    专利号:US-9359689-B2
    优先权日:2011-10-26
    标 题:Synthesis, capping and dispersion of nanocrystals
    发明人:XU WEI; WANG YIJUN; WIACEK ROBERT J; BAI XIA; GOU LINFENG; THOMAS SELINA I; GONEN WILLIAMS ZEHRA SERPIL; XU JUN; PATEL RAKESH
    权利人:PIXELLIGENT TECHNOLOGIES LLC
    摘要:Preparation of semiconductor nanocrystals and their dispersions in solvents and other media is described. The nanocrystals described herein have small (1-10 nm) particle size with minimal aggregation and can be synthesized with high yield. The capping agents on the as-synthesized nanocrystals as well as nanocrystals which have undergone cap exchange reactions result in the formation of stable suspensions in polar and nonpolar solvents which may then result in the formation of high quality nanocomposite films.

    专利号:CN-109678702-B
    优先权日:2017-10-19
    标题:Synthesis of M4L6 (M=Ti, Zr, Hf) Molecular Cage with Coordination Assembly Function

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