CAS: 544-18-3; Cobalt Diformate

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    专利号:US-4720573-A
    优先权日:1986-07-31
    标 题:Process for synthesis of glutamic acid from acrylate, amide and synthesis gas
    发明人:LIN JIANG-JEN
    权利人:TEXACO INC
    摘要:A process for the synthesis of glutamic acid intermediate from an acrylate, amide and syngas by reacting them in the presence of a catalyst comprising a cobalt-containing compound, a bis-phosphine ligand and a solvent at a pressure of at least 500 psi and a temperature of at least 50° C. and thereafter extracting the glutamic acid.

    专利号:US-4918222-A
    优先权日:1984-07-27
    标 题 :Process for synthesis of N-acetylglycine
    发明人:LIN JIANG-JEN; KNIFTON JOHN F; YEAKEY ERNEST L
    权利人:TEXACO INC
    摘要:An N-acetylglycine is manufactured by reacting paraformaldehyde with an acetamide and carbon monoxide in the present of a cobalt-containing catalyst promoted by a sulfoxide or dinitride compounds. The presence of sulfoxide or dinitrile ligands are essential for the high yield synthesis of N-acetylglycine and good cobalt recovery.

    专利号:EP-3549996-A1
    优先权日:2018-04-03
    标题:Olefins based on fischer-tropsch synthesis
    权利人:EVONIK DEGUSSA GMBH
    摘要:The present invention relates to a Fischer-Tropsch process for the synthesis of hydrocarbons, comprising contacting synthesis gas with at least one catalyst, the catalyst containing Co and Mn and an oxidic support.

    专利号:US-4616097-A
    优先权日:1984-10-22
    标 题:Process for low pressure synthesis of ethylene glycol from synthesis gas plus formaldehyde
    发明人:KNIFTON JOHN F
    权利人:TEXACO INC
    摘要:This invention relates to the manufacture of ethylene glycol and more particularly to a low pressure process for making ethylene glycol comprising reacting synthesis gas, i.e. a mixture of carbon monoxide and hydrogen, plus formaldehyde in the presence of a homogenous liquid catalyst containing an effective amount of cobalt-containing compound and a silicon-containing promoter at a temperature of at least 50 DEG C. and a pressure of at least 500 psi.

    专利号:US-4565896-A
    优先权日:1984-10-22
    标 题 :Process for low pressure synthesis of ethylene glycol from synthesis gas
    发明人:KNIFTON JOHN F; DURANLEAU ROGER G
    权利人:TEXACO INC
    摘要:This invention relates to the manufacture of ethylene glcyol and more particularly to a low pressure process for making ethylene glycol comprising reacting synthesis gas, i.e. a mixture of carbon monoxide and hydrogen, plus formaldehyde in the presence of a homogeneous liquid catalyst containing an effective amount of cobalt-containing compound and a silicon or germanium-containing promoter and a solvent at a temperature of at least 50 DEG C. and a pressure of at least 500 psi wherein said ethylene glycol product separates as a separate liquid phase from the solvent.

    专利号:US-4609768-A
    优先权日:1984-10-22
    标题 :Process for synthesis of ethylene glycol from synthesis gas plus 1,3-dioxolane using 1,3-dioxolane as a solvent
    发明人:KNIFTON JOHN F; LIN JIANG-JEN; GRICE NEAL J
    权利人:TEXACO INC
    摘要:This invention relates to the manufacture of ethylene glycol and more particularly to a low pressure process for making ethylene glycol comprising reacting synthesis gas, i.e. a mixture of carbon monoxide and hydrogen, plus 1,3-dioxolane in the presence of a homogenous liquid catalyst containing an effective amount of cobalt-containing compound, a silane or germane-containing promoter dispersed in a dioxolane solvent at a temperature of at least 50° C. and a pressure of at least 500 psi.

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    摘要:Currance, P.L. Clements, B., Bronstein, A.C. (Eds).; Emergency Care For Hazardous Materials Exposure. 3rd revised edition, Elsevier Mosby, St. Louis, MO 2007, p. 386
    摘要:WHO; Cobalt and Inorganic Cobalt Compounds. Concise International Chemical Assessment Document 69. World Health Organization, Geneva, Switzerland (2006). Available from, as of Feb 7, 2017:
    摘要:American Conference of Governmental Industrial Hygienists. Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices. ACGIH, Cincinnati, OH 2014, p. 21
    摘要:40 CFR 116.4 (USEPA); U.S. National Archives and Records Administration's Electronic Code of Federal Regulations. Available from, as of March 6, 2017:
    摘要:Richardson HW; Cobalt Compounds. Kirk-Othmer Encyclopedia of Chemical Technology (1999-2017). John Wiley & Sons, Inc. Online Posting Date: August 15, 2003
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