专利号:US-4720573-A 优先权日:1986-07-31 标 题:Process for synthesis of glutamic acid from acrylate, amide and synthesis gas 发明人:LIN JIANG-JEN 权利人:TEXACO INC 摘要:A process for the synthesis of glutamic acid intermediate from an acrylate, amide and syngas by reacting them in the presence of a catalyst comprising a cobalt-containing compound, a bis-phosphine ligand and a solvent at a pressure of at least 500 psi and a temperature of at least 50° C. and thereafter extracting the glutamic acid.
专利号:US-4918222-A 优先权日:1984-07-27 标 题 :Process for synthesis of N-acetylglycine 发明人:LIN JIANG-JEN; KNIFTON JOHN F; YEAKEY ERNEST L 权利人:TEXACO INC 摘要:An N-acetylglycine is manufactured by reacting paraformaldehyde with an acetamide and carbon monoxide in the present of a cobalt-containing catalyst promoted by a sulfoxide or dinitride compounds. The presence of sulfoxide or dinitrile ligands are essential for the high yield synthesis of N-acetylglycine and good cobalt recovery.
专利号:EP-3549996-A1 优先权日:2018-04-03 标题:Olefins based on fischer-tropsch synthesis 权利人:EVONIK DEGUSSA GMBH 摘要:The present invention relates to a Fischer-Tropsch process for the synthesis of hydrocarbons, comprising contacting synthesis gas with at least one catalyst, the catalyst containing Co and Mn and an oxidic support.
专利号:US-4616097-A 优先权日:1984-10-22 标 题:Process for low pressure synthesis of ethylene glycol from synthesis gas plus formaldehyde 发明人:KNIFTON JOHN F 权利人:TEXACO INC 摘要:This invention relates to the manufacture of ethylene glycol and more particularly to a low pressure process for making ethylene glycol comprising reacting synthesis gas, i.e. a mixture of carbon monoxide and hydrogen, plus formaldehyde in the presence of a homogenous liquid catalyst containing an effective amount of cobalt-containing compound and a silicon-containing promoter at a temperature of at least 50 DEG C. and a pressure of at least 500 psi.
专利号:US-4565896-A 优先权日:1984-10-22 标 题 :Process for low pressure synthesis of ethylene glycol from synthesis gas 发明人:KNIFTON JOHN F; DURANLEAU ROGER G 权利人:TEXACO INC 摘要:This invention relates to the manufacture of ethylene glcyol and more particularly to a low pressure process for making ethylene glycol comprising reacting synthesis gas, i.e. a mixture of carbon monoxide and hydrogen, plus formaldehyde in the presence of a homogeneous liquid catalyst containing an effective amount of cobalt-containing compound and a silicon or germanium-containing promoter and a solvent at a temperature of at least 50 DEG C. and a pressure of at least 500 psi wherein said ethylene glycol product separates as a separate liquid phase from the solvent.
专利号:US-4609768-A 优先权日:1984-10-22 标题 :Process for synthesis of ethylene glycol from synthesis gas plus 1,3-dioxolane using 1,3-dioxolane as a solvent 发明人:KNIFTON JOHN F; LIN JIANG-JEN; GRICE NEAL J 权利人:TEXACO INC 摘要:This invention relates to the manufacture of ethylene glycol and more particularly to a low pressure process for making ethylene glycol comprising reacting synthesis gas, i.e. a mixture of carbon monoxide and hydrogen, plus 1,3-dioxolane in the presence of a homogenous liquid catalyst containing an effective amount of cobalt-containing compound, a silane or germane-containing promoter dispersed in a dioxolane solvent at a temperature of at least 50° C. and a pressure of at least 500 psi.
摘要:Currance, P.L. Clements, B., Bronstein, A.C. (Eds).; Emergency Care For Hazardous Materials Exposure. 3rd revised edition, Elsevier Mosby, St. Louis, MO 2007, p. 386 摘要:WHO; Cobalt and Inorganic Cobalt Compounds. Concise International Chemical Assessment Document 69. World Health Organization, Geneva, Switzerland (2006). Available from, as of Feb 7, 2017: 摘要:American Conference of Governmental Industrial Hygienists. Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices. ACGIH, Cincinnati, OH 2014, p. 21 摘要:40 CFR 116.4 (USEPA); U.S. National Archives and Records Administration's Electronic Code of Federal Regulations. Available from, as of March 6, 2017: 摘要:Richardson HW; Cobalt Compounds. Kirk-Othmer Encyclopedia of Chemical Technology (1999-2017). John Wiley & Sons, Inc. Online Posting Date: August 15, 2003