CAS: 42152-46-5; Copper(I) Trifluoromethanesulfonate Benzene Complex

该化合物是一个高度反应性和稳定的协调化合物,在有机合成中广泛用作催化剂,其主要优点包括:普通有机溶剂中具有极好的溶性,有利于同质反应条件,以及由于三氟甲烷硫化硫化阴离子,促进高效催化活动而增加了刘易斯酸性;苯离子稳定铜(I)中心,防止氧化,并确保交叉相交,循环添加和其他过渡性金属催化反应的一致性能;该综合体因其空气和湿度稳定特性而特别受到重视,与较敏感的铜(I)试剂相比,简化了处理和储存;其多功能使得它更倾向于选择精细的化学和制药用途.

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欧盟法规

ECHA物质C&L通报REACH预注册

合成工艺路线路线简述

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    专利信息


    专利号:US-9090545-B2
    优先权日:2011-10-14
    标 题 :Asymmetric synthesis of organic compounds
    发明人:FLETCHER STEPHEN P; MAKSYMOWICZ REBECCA M; ROTH PHILIPPE M C
    权利人:ISIS INNOVATION
    摘要:The present invention provides processes for the production of chiral compounds in a stereoisomeric excess. The present processes involve reacting a hydrometallated alkene compound with a compound comprising a conjugated-bond system under conditions such that the compounds undergo an asymmetric 1,4- or 1,6-conjugate addition reaction, generating a chiral compound in a stereoisomeric excess. The reaction is performed in the presence of a metal catalyst, which catalyst preferably comprises a non-racemic chiral ligand.

    专利号:US-2014303385-A1
    优先权日:2011-10-14
    标题 :Asymmetric synthesis of organic compounds

    专利号:EP-2766324-A1
    优先权日:2011-10-14
    标题:Asymmetric synthesis of organic compounds

    专利号:WO-2013054131-A1
    优先权日:2011-10-14
    标 题 :Asymmetric synthesis of organic compounds

    专利号:CN-115716805-A
    优先权日:2022-11-17
    标 题 :Method for asymmetric catalytic synthesis of chiral pyrazolone derivatives containing propargyl alcohol structural fragments

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