CAS: 36993-94-9; 3-Methyl-6-Phenyl-1,2,4-Triazin-5-Ol

该化合物是三联环化合物,以三联苯核心替换成一个苯基组和一个甲基组,其分子结构可应用于制药和农用化学研究,特别是用作合成更复杂的分子的构件.该化合物在标准条件下具有稳定性,并显示出作为生物活性制剂开发中间体的潜力.其明确界定的再活性特征允许有选择地进行修改,使其成为医学化学的多用途试剂.芳基和三联苯基的出现有助于其设计具有定制电子和分子特性的化合物的效用.

英文名称3-Methyl-6-Phenyl-1,2,4-Triazin-5-Ol
中文名称3-甲基-6-苯基-1,2,4-三嗪-5-醇
IUPAC名称3-methyl-6-phenyl-1,2,4-triazin-5(4H)-one
其它别名3-Methyl-6-Phenyl-4H-[1,2,4]Triazin-5-One; 3-Methyl-6-Phenyl-2H-1,2,4-Triazin-5-One; 1,2,4-Triazin-5(2H)-One, 3-Methyl-6-Phenyl-; Metamitron Impurity 1 (Metamitron-Desamino); 3-Methyl-6-Phenyl-1,2,4-Triazin-5(2H)-One; 3-Methyl-6-Phenyl-1,2,4-Triazin-5-Ol
CAS编号36993-94-9
MFCD编号:MFCD01632383
分子式:C10H9N3O分子量:187.2
产品CID: 1379372
产品分类有机原料→分子砌块→芳杂环类化合物→三嗪类化合物

相似结构搜索
InChIKey: OUSYWCQYMPDAEO-UHFFFAOYSA-N
InChI=1S/C10H9N3O/c1-7-11-10(14)9(13-12-7)8-5-3-2-4-6-8/h2-6H,1H3,(H,11,12,14)
计算化学: 氢键受体数4.0氢键供体数1.0可旋转键数1.0

MSDS等安全信息

GHS符号GHS07
警示词Warning
危险描述H302-H315-H319
防范说明P264-P270-P280-P302+P352-P330-P362-P501

上下游产品

metamitron Benzoylformic acid acetamidrazone methyl 2-oxo-2-phenylacetate5-chloro-3-methyl-6-phenyl-as-triazine 3-Methyl-5-(4-phenoxy-phenyl)-6-phenyl-2,5-dihydro-[1,2,4]triazine 3-Methyl-5-naphthalen-1-yl-6-phenyl-2,5-dihydro-[1,2,4]triazine 3-Methyl-5-(1-methyl-1H-pyrrol-2-yl)-6-phenyl-2,5-dihydro-[1,2,4]triazine

合成工艺路线路线简述

📜苯嗪草酮置于titanium Dioxide P25,Sodium Persulfate体系中,用水作为反应溶剂,化学反应 1.83H,反应生成苯嗪草酮-Desamino
参考文献:Photocatalytic Mitigation Of Triazinone Herbicide Residues Using Titanium Dioxide In Slurry Photoreactor
标题:Photocatalytic Mitigation Of Triazinone Herbicide Residues Using Titanium Dioxide In Slurry Photoreactor
摘要:Heterogeneous Photocatalysis Offers An Alternative For The Treatment Of Wastewater Containing Refractory Pollutants. The Photocatalytic Degradation Of Metamitron And Metribuzin,Asymmetrical Triazine Compounds Used Worldwide As Herbicides,Was Investigated In Aqueous Suspension Of Different Commercial Tio2 Nanopowders With Different Composition Of Anatase/rutile Phases,Using Artificial Uv-A Light. In Addition,We Have Studied The Role Of The Most Important Operating Parameters (Catalyst Loading,Effect Of Electron Acceptor,Ph,Light Intensity,Initial Concentration Of Pollutants,And Interfering Substances) On The Photooxidation Of Both Herbicides. Tio2 P25 (70% Anatase/30% Rutile) Was Found To Be Highly Active For Herbicide Decomposition. The Progress Of Photocatalytic Degradation Of Both Herbicides Has Been Observed By Monitoring The Change In Substrate Concentration Using HPLC/ms2. Results Showed That The Addition Of Tio2 In Tandem With An Electron Acceptor Like Na2S2O8 Strongly Enhances The Degradation Rate Of Metamitron And Metribuzin In Comparison With Photolytic Test. The Degradation Of These Herbicides Followed A Pseudo-First Order Kinetics. The Time Required For 50% Degradation Was Lower Than 8 Min For Both. Thus,Complete Disappearance Was Achieved After 30 Min Of Illumination In The Tio2/na2S2O8 System. Both Herbicides Were Rapidly Deaminated. (C) 2014 Elsevier B.V. All Rights Reserved.
DOI:10.1016/j.Cattod.2014.12.011