2157-19-9 = 33213-65-9 + 959-98-8 反应条件:1.1 Reagents: Thionyl Chloride Solvents: Carbon Tetrachloride 标题:Stereoselective Preparation Of 6,7,8,9,10-10-Hexahalo-1,5,5A,6,9,9A-Hexahydro-6,9-Methano-2,4,3-Benzodioxathiepin-3-Oxides From 1,4,5,6,7,7-Hexahalo-5-Norbornene-2,3-Dimethanol And Cyclic Sulfite Ring Forming Reagents In The Presence Of Stereoisomer Directing Agents. 参考文献:World Intellectual Property Organization
专利号:US-2016073631-A1 优先权日:2013-03-04 标 题 :Process for the preparation of dihydropyrrole derivatives 发明人:EL QACEMI MYRIEM; SMITS HELMARS; CASSAYRE JEROME YVES; MULHOLLAND NICHOLAS PHILLIP; RENOLD PETER; GODINEAU EDOUARD; PITTERNA THOMAS 权利人:SYNGENTA PARTICIPATIONS AG; SYNGENTA LTD 摘要:The present invention provides stereoselective processes for the preparation of compounds of formula (I) n n n n n n n n n n n n wherein n P is phenyl, naphthyl, a 6-membered heteroaryl group containing one or two nitrogen atoms as ring members, or a 10-membered bicyclic heteroaryl group containing one or two nitrogen atoms as ring members, and wherein the phenyl, naphthyl and heteroaryl groups are optionally substituted; n R 1 is chlorodifluoromethyl or trifluoromethyl; n R 2 is optionally substituted aryl or optionally substituted heteroaryl; n n is 0 or 1; n including the process comprising n (a-i) reacting a compound of formula II n n n n n n n n n n n n n n n n wherein P, R 1 and R 2 are as defined for the compound of formula I; n with nitromethane in the presence a chiral catalyst to give a compound of formula III n n n n n n n n n n n n n n n n wherein P, R 1 and R 2 are as defined for the compound of formula I; and n (a-ii) reductively cyclising the compound of formula III to give the compound of formula I. n n n n n The invention also provides intermediates useful for processes for the synthesis of compounds of formula (I).
专利号:US-9700872-B1 优先权日:2016-07-01 标题:Superpolar chromatographic stationary phases and extraction sorbents and their methods of synthesis 发明人:KABIR ABUZAR; FURTON KENNETH G 权利人:KABIR ABUZAR; FURTON KENNETH G; UNIV FLORIDA INT 摘要:A superpolar sorbent network is a sol-gel network of at least one metal oxide precursor condensed and at least one polyhydroxy molecule. The metal oxide precursor is a silicate precursor, aluminate precursor, titanate precursor, zirconate precursor, germinate precursor, or any combinations thereof, and the polyhydroxy molecule has a multiplicity of hydroxyl groups. The polyhydroxy molecule can be an organic molecule derived from nature. The superpolar sorbent network can be used as a particulate or bulk sorbent for sampling or removal of analytes or contaminants from an environment or can be coated on a tube or particulate substrate for use as a chromatographic stationary phase.
专利号:CN-114196097-B 优先权日:2022-01-29 标 题:A kind of regenerated wooden sponge for hydroponic planting and its synthesis method
参考文献:10.1007/s10661-011-2167-7 摘要:Anjum R, Malik A. Mutagenicity assessment of contaminated soil in the vicinity of industrial area. Environmental Monitoring and Assessment. 2011 Jul 15;184(5):3013–26. doi: 10.1007/s10661-011-2167-7. 参考文献:10.1007/s00128-011-0353-5 摘要:Cantu-Soto EU, Meza-Montenegro MM, Valenzuela-Quintanar AI, Félix-Fuentes A, Grajeda-Cota P, Balderas-Cortes JJ, Osorio-Rosas CL, Acuña-García G, Aguilar-Apodaca MG. Residues of Organochlorine Pesticides in Soils from the Southern Sonora, Mexico. Bulletin of Environmental Contamination and Toxicology. 2011 Jul 15;87(5):556. doi: 10.1007/s00128-011-0353-5.