📜全氟癸二酸置于lithium Aluminium Tetrahydride,硫酸体系中,用 四氢呋喃 作为反应溶剂,化学反应 37.0H,反应生成 1H,1H,10H,10H-全氟-1,10-癸二醇
参考文献:Structure Of 2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9-Hexadecafluorodecyl 1,10-Ditosylate By X-Ray Crystallography And 19 F-NMR Spectroscopy
标题:Structure Of 2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9-Hexadecafluorodecyl 1,10-Ditosylate By X-Ray Crystallography And 19 F-NMR Spectroscopy
摘要:2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9-Hexadecafluorodecyl 1,10-Ditosylate And Its Precursors Were Synthesized And Characterized By H-1-And F-19-NMR Spectroscopic Methods And X-Ray Crystallography. These Compounds Are Building Blocks For The Syntheses Of The Surfactants Containing Polyperfluoromethylene Spacer. The Molecule Has Extended All-Trans Conformation With Molecular Symmetry (1) Over Bar (C-I). There Is A Reasonably Strong C-H ... O Interaction In The Crystal And There Are Two F ... F Intermolecular Contact Distances Less Than The Sum Of Van Der Waals Radii. (C) 1999 Elsevier Science B.V. All Rights Reserved.
DOI:10.1016/s0022-2860(98)00797-2