CAS: 629-08-3; 3-Phenylpropionitrile

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2-壬酮置于aluminum (Iii) Chloride,Sodium Nitrite体系中,用 N,N-二甲基甲酰胺 作为反应溶剂,化学反应 4.0H,以83%的收率获得产物正庚腈
参考文献:无过渡金属的无应变c(sp 3)-c(sp 2)键的无酰化解离:从酮和醛到氰基和脂肪族腈的无氰化物访问
标题:无过渡金属的无应变c(sp 3)-c(sp 2)键的无酰化解离:从酮和醛到氰基和脂肪族腈的无氰化物访问
摘要:首先描述了一种无过渡金属的脱酰基c(sp 3)-c(sp 2)键裂解的方法,该方法用于合成和实际的酮和醛氧化胺化成腈,使用廉价且商业上充裕的nano 2作为氧化剂和氮源.可以从酮和醛中以高收率平稳地获得各种带有芳基,杂芳基,烷基和烯基的腈,避免了剧毒的氰化物或过渡金属.
DOI:10.1021/acs.Orglett.5B03367

专利信息

专利号:US-6159673-A
优先权日:1996-07-17
标 题:Oxonol compound, light-sensitive material and process for the synthesis of oxonol compound
发明人：NISHIGAKI JUNJI; DEGUCHI YASUAKI
权利人:FUJI PHOTO FILM CO LTD
摘要:An oxonol compound is represented by the following formula (I): in which Z is an atomic group that forms a cyclic amide ring; each of W1 and W2 independently is an atomic group that forms an acidic nucleus ring; and M is a cation. Other oxonol compounds, a light-sensitive material containing an oxonol compound and a process for the synthesis of an oxonol compound are also disclosed.

专利号:US-6096898-A
优先权日:1999-10-22
标 题:One pot synthesis of 1,2,4-triazoles
发明人：PODHOREZ DAVID E; HULL JR JOHN W; BRADY CHRISTINE H
权利人:DOW AGROSCIENCES LLC
摘要:One pot synthesis of 1,2,4-triazoles uses thioimidate intermediate and 1,2-dichloroethane solvent.

专利号:EP-1473330-B1
优先权日:1996-07-17
标题:Process for the synthesis of oxonol compound
发明人：NISHIGAKI JUNJI; DEGUCHI YASUAKI
权利人:FUJI PHOTO FILM CO LTD
摘要:An oxonol compound is represented by the following formula (I): in which each of Z, W<1> and W<2> independently is an atomic group that forms a heterocyclic ring; and M is a cation. A process for the synthesis of an oxonol compound is disclosed.

专利号:US-5206392-A
优先权日:1992-04-27
标 题:Facile synthesis of arylmaleic acids and anhydrides
发明人：DEAN WILLIAM D
权利人:AMERICAN CYANAMID CO
摘要:A process for making acrylmaleic acid and arylmaleic anhydride derivative useful as intermediates for the preparation of arylmaleimides in the synthesis of compounds having activity in the central nervous system. The process involves reacting arylacetonitriles with glyoxylic acid to provide novel intermediate 3-aryl-3-cyanopropeneoates which may be converted to the arylmaleic acid and arylmaleic anhydride derivatives.

专利号:US-2004024238-A1
优先权日:1999-07-02
标 题:Use of nitriles as polar aprotic solvents
发明人：LAURAIN NATHALIE; ZARD SAMIR
摘要:The invention concerns the use of aliphatic nitriles with relatively high molecular weight, as polar aprotic solvents, in particular in nucleophilic substitution reactions of the aromatic type. Said nitriles have a molecular mass more 79, preferably more than 90. The invention is useful for synthesis of fluorinated aromatic compounds.

专利号:US-4219684-A
优先权日:1979-04-02
标 题 :Synthesis of alcohols by hydroformylation with nitrile promoter
发明人：IMAI TAMOTSU
权利人:UOP INC
摘要:Alcohols may be synthesized by reacting an olefinic compound, carbon monoxide and hydrogen in the presence of a Group VIII organometallic complex catalyst at reaction conditions which include a temperature in the range of from about 50° to about 250° C. and a pressure in the range of from about 10 to about 300 atmospheres. In addition, the reaction is also effected in the presence of a promoter compound comprising a nitrile.