CAS: 3368-21-6; 3-(4-Isopropylphenyl)Acrylic Acid

上下游产品

piperidine pyridine malonic acid (4-isopropylbenzaldehyde) p-nitr°Cinnamic acid 4-isopropylstyrene 3-(p-isopropylphenyl)propionic acid (E)-3-(4-isopropylphenyl)acryloyl chloride

📜4-(4-异丙基苯基)-3-丁烯-2-酮置于copper(L) Iodide,盐酸羟胺,氧气体系中,用 二甲基亚砜 作为反应溶剂,化学反应 12.0H,以61%的收率获得产物4-异丙基肉桂酸
参考文献:铜催化氧辅助的c(cnoh)-C(烷基)键裂解:芳基/芳烷基/乙烯基酮向芳族酸的便捷转化†
标题:铜催化氧辅助的c(cnoh)-C(烷基)键裂解:芳基/芳烷基/乙烯基酮向芳族酸的便捷转化†
摘要:描述了一种新型的铜催化的芳基/芳烷基/乙烯基酮的需氧氧化c(noh)-C(烷基)键裂解反应,用于合成芳族/丙烯酸.可以选择性地裂解在一端具有芳基/芳烷基/乙烯基而在另一端具有甲基至任何高级烷基的一系列酮,并通过肟中间体将其转化为相应的酸.
DOI:10.1039/c5Ob01569C

专利信息

专利号:US-8987504-B2
优先权日:2010-06-18
标题 :Aminohydroxylation of alkenes
发明人：MEE SIMON PETER HAROLD; LUXENBURGER ANDREAS; HARRIS LAWRENCE DANIEL
权利人:MEE SIMON PETER HAROLD; LUXENBURGER ANDREAS; HARRIS LAWRENCE DANIEL; VICTORIA LINK LTD
摘要:The invention relates to a process for the aminohydroxylation of alkenes using N-oxycarbamate reagents, e.g. N-acyloxycarbamate, N-alkyloxycarbonyloxycarbamate and N-aralkoxycarbonyloxycarbamate reagents. The invention particularly relates to an intermolecular aminohydroxylation reaction that can be carried out in the absence of added base. The invention also relates to novel N-oxycarbamate reagents that are stable crystalline materials. The process of the invention is useful in the synthesis of compounds having a vicinal amino alcohol moiety, such as biologically active compounds.

专利号:US-3975429-A
优先权日:1973-11-05
标题:Cyclopropanemethyl esters of cinnamic acid and derivatives thereof
发明人：HENRICK CLIVE A; STAAL GERARDUS B
权利人:ZOECON CORP
摘要:Organic esters and thioesters characterized by the presence of a cyclopropane moiety, synthesis thereof, and compositions thereof for the control of mites and ticks.

专利号:US-3928413-A
优先权日:1973-04-13
标 题:Cyclopropanemethyl esters
发明人：HENRICK CLIVE A; STAAL GERARDUS B
权利人:ZOECON CORP
摘要:Organic esters and thioesters characterized by the presence of a cyclopropane moiety, synthesis thereof, and compositions thereof for the control of mites and ticks.