CAS: 33089-37-1; 1,4,7,10,13,16,19,22-Octaoxacyclotetracosane

该化合物是一个属于皇冠醚家族的圆形聚醚,其特点是能够有选择地捆绑石块,特别是钠和钾等碱性金属.其结构由8个氧原子与碳原子相交的8个冠状安排组成,形成一个24人环.这一独特的配置使其能够产生一种能封装花粉,便利复杂和溶解于各种溶剂的流体性孔.24-Crown-8经常用于协调化学,提取工艺,并作为一种阶段转移催化剂,因为它能够提高有机溶剂中离子化合物的溶解性.该化合物一般没有色,熔点较低,在实验室环境中易于处理.其应用范围扩大到分析化学,材料科学和有机合成等领域,在离子选择性电极和感应技术中发挥着关键作用.

结构式图片

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

tetraethylene glycol di(p-toluenesulfonate) Tetraethylene glycol °Ctaethylene glycol diethylene glycol 2O3*C16H32O8*C45H38N2CH2O3*C16H32O8*C45H38N2

合成工艺路线路线简述

    📜八乙二醇置于氢氧化钾,对甲苯磺酸体系中,化学反应生成24-冠-8-醚
    参考文献:Effect Of Crown Ethers On The Selectivity Of Electrophilic Aromatic Nitration
    标题:Effect Of Crown Ethers On The Selectivity Of Electrophilic Aromatic Nitration
    摘要:
    Doi:10.1021/jo00221A023

    海关参考信息

    专利信息


    专利号:US-2024400533-A1
    优先权日:2023-06-02
    标题 :General Solid-Phase Synthesis of Crown Ethers
    发明人:TRANT JOHN F; NASRI SARAH; HAYWARD JOHN J
    权利人:UNIV OF WINDSOR
    摘要:In a preferred embodiment, there is provided a method for preparing a crown ether, the method comprising: loading a resin having a resin functional group with a linking compound having a functional group selected for coupling to the resin functional group and at least two carbon atoms each having a substituent; coupling the linking compound to a polyethylene glycol having two terminal carbon atoms each bonded to an optionally protected terminal hydroxyl group to obtain a cyclized intermediate, whereby one said at least two carbon atoms or the substituent and an associated one of the two terminal carbon atoms or the hydroxyl groups undergo a coupling or substitution reaction; and removing the linking compound and the cyclized intermediate from the resin.

    专利号:US-9919297-B2
    优先权日:2013-08-05
    标题 :Zeolite, and production method and use therefor
    发明人:CHEN HAIJUN; TAKEWAKI TAKAHIKO; MATSUO TAKESHI
    权利人:MITSUBISHI CHEM CORP
    摘要:The present invention provides a novel high-silica zeolite having a high molar ration of a tetravalent element (Y) to a trivalent element (X) in terms of oxide. n A zeolite, comprising at least a trivalent element X and a tetravalent element Y, wherein a molar ratio n=YO 2 /X 2 O 3 in terms of oxide is 9.5 or more, and the zeolite comprises an RHO-type structure, or comprising at least a trivalent element X and a tetravalent element Y, wherein a molar ratio n=YO 2 /X 2 O 3 in terms of oxide is 9.5 or more, and a characteristic X-ray diffraction pattern. This zeolite is produced by hydrothermal synthesis of a zeolite from an aqueous gel that is prepared by adding a mixed solution comprising a crown ether, an alkali, and water to a solution containing an aluminum atom material, and by then dropwise adding a liquid containing a silicon atom material.

    专利号:WO-9003944-A1
    优先权日:1988-10-10
    标 题 :Synthesis of zeolites having a faujasite structure

    专利号:US-6984734-B2
    优先权日:2002-02-26
    标 题 :Cyclo[n]pyrroles and methods thereto
    发明人:SESSLER JONATHAN L; SEIDEL DANIEL; BOLZE FREDERIC R; KOEHLER THOMAS
    权利人:UNIV TEXAS
    摘要:The present invention provides an oxidative coupling procedure that allows efficient synthesis of novel cyclo[n]pyrrole macrocycles. Therefore, the present invention provides cyclo[n]pyrroles where n is 6, 7, 8, 9, 10, 11, or 12, and derivatives, multimers, isomers, and ion and neutral molecule complexes thereof as new compositions of matter. A protonated form of cyclo[n]pyrrole displays a gap of up to 700 nm between strong Soret and Q-like absorption bands in the electronic spectrum, demonstrating no significant ground state absorption in the visible portion of the electronic spectrum. Uses of cyclo[n]pyrroles as separation media, nonlinear optical materials, information storage media and infrared filters are provided.

    专利号:CN-113441183-B
    优先权日:2021-07-16
    标题 :Crown ether organic polymer loaded with alkali metal ions, preparation method and application of crown ether organic polymer in aspect of catalytic synthesis of cyclic carbonate

    专利号:EP-0364352-A1
    优先权日:1988-10-10
    标 题:Method for the synthesis of zeolites belonging to the structural family of faujasite, products obtained and their use in adsorption and catalysis

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    合成参考文献


    摘要:Drug and Chemical Toxicology., 8(451), 1985 []
    📝 需求与反馈
    尽可能描述清楚需求与问题信息
    ×

    通知