
物理性质
- 熔点1200 °C
- 沸点1200 °C
- 密度4.25
- PSA:32.09
- LogP:0.6482
- 蒸汽压12600mmHg at 25°C
- 溶解性Soluble In Water But Insoluble In Alcohol.
- 敏感性易受潮
- 外观形态浅灰色至黄色粉末
- 储存条件储存注意事项储存于阴凉、干燥环境、通风良好的库房。远离火种、热源。包装必须密封保存,切勿受潮。应与氧化剂、酸类、食用化学品分开存放,切忌混储。不宜长久,以免变质。配备相应品种和数量的消防器材。储区应备有合适的材料收容泄漏物。
- 产品应用多硫化钡(21109-95-5)的用途:1.主要用于制造钡盐,立德粉和发光油漆,也用作橡胶硫化剂及皮革脱毛剂 .2.在农药中用作杀菌剂和杀螨剂,可防治小麦锈病和各种果树病害.3.主要用作制造各种钡盐,立德粉的原料;也用作橡胶硫化剂及皮革脱毛剂.分析化学中用以发生硫化氢.4.农业上作杀螨剂及灭菌剂.多硫化钡(21109-95-5)的作用方式,机理:既能杀螨也能杀菌,将它喷于植物上以后,分解出的元素硫,颗粒极细,能很好地粘附于叶面,起到杀螨和杀菌的效用.多硫化钡(21109-95-5)的防治对象:小麦锈病,黄瓜白粉病,马铃薯早疫病,棉花红腐病,棉花炭疽病,棉花角斑病等;同时还能防治多种红蜘蛛.
- 性质描述多硫化钡(21109-95-5)的理化性质:白色等轴晶系立方晶体,有时呈浅灰色或黄绿色,工业品为浅棕色或黑色粉末.不溶于醇.溶于水而分解成氢氧化钡和硫氢化钡.细微的硫化钡熔体BaS(40%~45%)和硫磺细粉(20%~25%)的机械混合物,其中含30%~35%的无毒混合物如煤,硫酸钡和二氧化硅等.这种混合物是细微深灰色粉末,加水溶解后,硫化钡与硫磺作用生成多硫化钡.其中主要是四硫化钡和五硫化钡,比重1.137.这种液溶为棕红色,其化学性质与多硫化钙相似,在酸中分解出元素硫和硫化氢气体.在水溶液中与硫酸铁或硫酸铜作用,生成不溶于水的深红色金属硫化物,如与脂肪酸的钾或钠盐溶液作用,则生成不溶于水的钡皂.毒性:对人的毒性未定,其粉尘能强烈地刺激鼻,喉,眼等粘膜.从多硫化钡中分解出的硫化氢对人有毒,需要注意.对作物比多硫化钙(石硫合剂)安全.剂型:粉剂,应用时配制成溶液,其浓度为1%.多硫化钡可与多硫化钙混合使用.
欧盟法规
统一分类与标签REACH注册ECHA物质工作场所安全标识要求ECHA物质C&L通报REACH预注册废弃物危险特性清单上下游产品
bismuth(III) nitrate 3,4,5-trihydroxybenzoic acid water hydrogen sulfidepotassium bromide sulfide ion sodium sulfide sulfurCYANAMID thiourea N-Cyanoguanidine 6-phenyl-1,3,5-triazinane-2,4-dithione4-Thi°Cyanatmethylpyridin thi°Cyanic acid thi°Cyanoacetone methyl thi°Cyanate Barium Sulfite 反应生成硫化钡
参考文献:Kempe,Gottfried;Bogel,Monika;Meyer,Gerhard,Z. Chem.,29,(1989) N,C. 11-15
标题:Kempe,Gottfried;Bogel,Monika;Meyer,Gerhard,Z. Chem.,29,(1989) N,C. 11-15
专利信息
专利号:US-2024010511-A1
优先权日:2019-05-02
标 题 :Methods and compositions for synthesis of phosphor and its incorporation in a polymer matrix for light conversion
发明人:SAHI SUNIL
权利人:SOLGO INC; SOLGRO INC
摘要:The invention relates to methods and compositions for synthesizing a phosphor and preparing a surface-modified phosphor comprising a phosphor, a silica, and a silane, and articles comprising same. The invention also relates to a method of dispersion of the disclosed surface-modified phosphor with a blue emitting agent in a polymer matrix and uses thereof.
专利号:US-8487059-B2
优先权日:2011-11-22
标 题:Synthesis of dendritic polyolefins by metathesis insertion polymerization
发明人:YANG YONG; TSOU ANDY HAISHUNG
权利人:YANG YONG; TSOU ANDY HAISHUNG; EXXONMOBIL RES & ENG CO
摘要:A one step process for making a dendritic hydrocarbon polymer, e.g., dendritic polyolefin, by metathesis insertion polymerization. The process comprises polymerizing an amount of one or more cyclic olefins and one or more multi-functional (meth)acrylates in the presence of a metathesis catalyst and under conditions sufficient to produce the dendritic hydrocarbon polymer. The one or more multi-functional (meth)acrylates have a functionality of 3 or higher. The dendritic hydrocarbon polymer can be hydrogenated to produce a substantially saturated dendritic hydrocarbon polymer. The hydrogenation can take place in the same reaction vessel as the polymerization, i.e., one pot process.
专利号:US-6667022-B2
优先权日:2001-08-14
标题:Process for separating synthesis gas into fuel cell quality hydrogen and sequestration ready carbon dioxide
发明人:COLE JERALD A
权利人:GEN ELECTRIC
摘要:A method and apparatus for separating gas mixtures containing synthesis gas (syngas) into separate streams of wet hydrogen containing significantly reduced amounts of CO 2 and CO, with the CO 2 being “sequestration readyâ€? and containing less than 1% fixed gases. In the preferred embodiment, a mixture of limestone and iron oxide circulates between two fluidized beds whereby one bed is fluidized with a gas containing syngas, while the other bed is fluidized with a gas containing steam and oxygen. As the fluidizing gas containing syngas passes through the bed, the CO 2 reacts with CaO to form CaCO 3 . Virtually all of the CO is removed by a water gas shift reaction, forming hydrogen and CO 2 , with the remainder being removed by reaction with the iron oxide, reducing Fe 2 O 3 to FeO. Some hydrogen is also removed by reaction with the iron oxide, reducing Fe 2 O 3 to FeO, while the remainder of the hydrogen passes through the fluid beds, leaving in a purified state, i.e., PEM fuel cell quality.
专利号:WO-2025198684-A2
优先权日:2023-12-20
标题 :BaTiO3 NANOCRYSTALS AND NANOCOMPOSITES
发明人:SZYCHOWSKI BRIAN; GELLEN TOBIAS A; WIACEK ROBERT J; MONICKAM SELINA THOMAS; WILLIAMS ZEHRA SERPIL GONEN; FU GUOYI
权利人:PIXELLIGENT TECH LLC
摘要:The synthesis of barium titanate nanocrystals, the capping of barium titanate nanocrystals to disperse into solvents, including polar and nonpolar solvents, polyalphaolefins, lubricants, oils, and greases, monomers, oligomers, and polymers including acrylics, epoxies, siloxanes, and the preparation of nanocomposites of barium titanate in combination with these monomers, oligomers, and polymers. The barium titanate nanocrystals are monodispersed with sizes between 1-200 nm and have an ideal barium to titanium ratio. The nanocrystals of size greater than 80 nanometer can possess high dielectric constants and can be ideal candidates of ceramic conductors and RF sensors. Nanocomposites resulting from the barium titanate nanocrystals of size less than 40 nanometer in combination with the monomers, oligomers, and polymers can possess high refractive index, high transparency, low absorbance, and minimal change when exposed to heat or UV light.
专利号:US-2013131297-A1
优先权日:2011-11-22
标题:Synthesis of dendritic polyolefins by metathesis insertion polymerization
专利号:WO-2020223644-A1
优先权日:2019-05-02
标题:Methods and compositions for synthesis of phosphor and its incorporation in a polymer matrix for light conversion