CAS: 132339-37-8; (4S,4As,6S,7R,7As)-6-Hydroxy-4-(Hydroxymethyl)-7-Methylhexahydrocyclopenta[c]Pyran-3(1H)-One

英文名称(4S,4As,6S,7R,7As)-6-Hydroxy-4-(Hydroxymethyl)-7-Methylhexahydrocyclopenta[c]Pyran-3(1H)-One
中文名称4-Epialyxialactone; (4S,4aS,6S,7R,7aS)-六氢-6-羟基-4-(羟基甲基)-7-甲基环戊并[c]吡喃-3(1H)-酮
IUPAC名称(4S,4aS,6S,7R,7aS)-6-hydroxy-4-(hydroxymethyl)-7-methylhexahydrocyclopenta[c]pyran-3(1H)-one
其它别名(4S)-Hexahydro-6α-Hydroxy-4α-(Hydroxymethyl)-7α-Methylcyclopenta[c]Pyran-3(4H)-One; 4-Epialyxialactone; (4S,4As,6S,7R,7As)-Hexahydro-6-Hydroxy-4-(Hydroxymethyl)-7-Methylcyclopenta[c]Pyran-3(1H)-One; Cyclopenta[c]Pyran-3(1H)-One, Hexahydro-6-Hydroxy-4-(Hydroxymethyl)-7-Methyl-, (4S,4As,6S,7R,7As)-
CAS编号132339-37-8
MFCD编号:MFCD20260606
分子式:C10H16O4分子量:200.23
产品CID: 489430
产品分类天然产物 → 环烯醚萜衍生物

相似结构搜索
InChIKey: DYRWCEDTDIXFOD-OKNNCHMLSA-N
InChI=1S/C10H16O4/c1-5-8-4-14-10(13)7(3-11)6(8)2-9(5)12/h5-9,11-12H,2-4H2,1H3/t5-,6-,7-,8-,9+/m1/s1
计算化学: 氢键受体数4.0氢键供体数2.0可旋转键数1.0

MSDS等安全信息

危险描述H303May be harmful if swallowed+H313Skin contact may be harmful+H333Inhalation may be harmful to the body
防范说明P264+P280+P305+P351+P338+P337+P313
安全声明H303+H313+H333

上下游产品

methyl-(1R,6S,7R)-1,6-dihydroxy-7-methyl-1,4a,5,6,7,7a-hexahydr°Cyclopenta[c]pyran-4-carboxylate loganic acid loganin

合成工艺路线路线简述

📜马钱子苷置于sodium Tetrahydroborate体系中,用甲醇用作溶剂,化学反应 1.5H,反应生成4-Epialyxialactone; (4S,4As,6S,7R,7As)-六氢-6-羟基-4-(羟基甲基)-7-甲基环戊并[c]吡喃-3(1H)-酮
参考文献:Abeliosides A 和 B,来自 Abelia Grandiflora 的 Secoiridoid Glucosides
标题:Abeliosides A 和 B,来自 Abelia Grandiflora 的 Secoiridoid Glucosides
摘要:摘要 Twp 新的二环环烯醚萜苷,Abeliosides A 和 B,与 Cantleyoside 和 Sylvestroside Ii 一起从 Abelia Grandiflora 中分离出来.根据光谱和化学证据,这些新的糖苷被鉴定为芥子油酸酯与可能来自马钱苷的环烯醚萜内酯.Cantleyoside 也从 A. Spathulata 和 A. Serrata 中分离出来.
Doi:10.1016/s0031-9422(00)83036-8