CAS: 993-10-2; Trichloro(Methyl)Germane

上下游产品

germaniumtetrachloride methyl iodide germanium methylene chloridemagnesium chloride 7(C6H11)7O12GeCH3Si7(C6H11)7O12GeCH3 methylphenylisopropylgermanium bromide 1-methyl-1-chloro-2,3,4,5-tetraphenyl-1-germacyclopenta-2,4-diene

📜氯甲烷,四氯化锗 以 Neat (No Solvent) 作为反应溶剂,以0%的收率获得产物三氯甲基锗
参考文献:Organotrichlorogermane Synthesis By The Reaction Of Elemental Germanium,Tetrachlorogermane And Organic Chloride Via Dichlorogermylene Intermediate
标题:Organotrichlorogermane Synthesis By The Reaction Of Elemental Germanium,Tetrachlorogermane And Organic Chloride Via Dichlorogermylene Intermediate
摘要:有机三氯锗烷是通过元素锗,四氯化锗和有机氯化物(甲基,丙基,异丙基和烯丙基氯化物)反应合成的.元素锗与四氯化锗反应反应生成的二氯锗烯是反应中间体,该中间体插入有机氯化物的碳-氯键中,反应生成有机三氯锗烷.当使用异丙基或烯丙基氯化物作为有机氯化物时,即使在没有四氯化锗的情况下,也能形成有机三氯锗烷.这些氯化物会转化为氯化氢,后者与元素锗反应反应生成二氯锗烯中间体.元素锗,四氯化锗和有机氯化物的反应为合成有机三氯锗烷提供了一种简单易行的方法,并且所有原材料都易于获取.
DOI:10.1039/b404590D

专利信息

专利号:US-4565896-A
优先权日:1984-10-22
标 题 :Process for low pressure synthesis of ethylene glycol from synthesis gas
发明人：KNIFTON JOHN F; DURANLEAU ROGER G
权利人:TEXACO INC
摘要:This invention relates to the manufacture of ethylene glcyol and more particularly to a low pressure process for making ethylene glycol comprising reacting synthesis gas, i.e. a mixture of carbon monoxide and hydrogen, plus formaldehyde in the presence of a homogeneous liquid catalyst containing an effective amount of cobalt-containing compound and a silicon or germanium-containing promoter and a solvent at a temperature of at least 50 DEG C. and a pressure of at least 500 psi wherein said ethylene glycol product separates as a separate liquid phase from the solvent.

专利号:US-4609768-A
优先权日:1984-10-22
标题 :Process for synthesis of ethylene glycol from synthesis gas plus 1,3-dioxolane using 1,3-dioxolane as a solvent
发明人：KNIFTON JOHN F; LIN JIANG-JEN; GRICE NEAL J
权利人:TEXACO INC
摘要:This invention relates to the manufacture of ethylene glycol and more particularly to a low pressure process for making ethylene glycol comprising reacting synthesis gas, i.e. a mixture of carbon monoxide and hydrogen, plus 1,3-dioxolane in the presence of a homogenous liquid catalyst containing an effective amount of cobalt-containing compound, a silane or germane-containing promoter dispersed in a dioxolane solvent at a temperature of at least 50° C. and a pressure of at least 500 psi.

专利号:US-4568780-A
优先权日:1984-10-22
标 题 :Process for low pressure synthesis of ethylene glycol from synthesis gas plus 1,3-dioxolane
发明人：KNIFTON JOHN F
权利人:TEXACO INC
摘要:This invention relates to the manufacture of ethylene glycol and more particularly to a low pressure process for making ethylene glycol comprising reacting synthesis gas, i.e. a mixture of carbon monoxide and hydrogen, plus 1,3-dioxolane in the presence of a homogenous liquid catalyst containing an effective amount of cobalt-containing compound and a silane or germane-containing promoter dispersed in a hydrocarbon solvent at a temperature of at least 50 DEG C. and a pressure of at least 500 psi, where the particular solvents used allow the desired product to be separated from the reaction mixture by phase separation.

专利号:US-6843978-B2
优先权日:1999-11-24
标题:Microporous materials (TIQ-6 and METIQ-6) of high surface area active in oxidation reactions
发明人：CORMA CANOS AVELINO; FORNES SEGUI VICENTE; DIAZ MORALES URBANO; DOMINE MARCELO EDUARDO
权利人:CONSEJO SUPERIOR INVESTIGACION; UNIV VALENCIA POLITECNICA
摘要:The present invention refers to a microporous material formed by oxygen, silicon, germanium, aluminum, boron, gallium, zirconium and/or titanium in its composition, called TIQ-6, to its catalytic applications in oxidation reactions, and to a method of the TIQ-6 material's preparation based on the synthesis of a gel with a titanium and/or zirconium content, its hydrothermal treatment under controlled conditions, and the treatment of the resulting laminar material with a solution of an organic compound containing a proton accepting group. This swollen material is subjected to a specific treatment to obtain a high external area delaminated solid. A material, METIQ-6, similar to the TIQ-6 material, but also having organic groups anchored on its surface incorporated by a post-synthesis process onto the TIQ-6 material is also claimed.

专利号:US-4409405-A
优先权日:1982-05-13
标题:Production of ethanol from methanol and synthesis gas
发明人：LIN JIANG-JEN; KNIFTON JOHN F
权利人:TEXACO INC
摘要:Ethanol is formed by contacting a mixture of carbon monoxide, hydrogen and methanol with a catalyst comprising a cobalt-containing compound and a germanium-containing compound, such as dicobalt octacarbonyl and triphenylgermanium hydride in the presence of an inert, oxygenated hydrocarbon solvent at a temperature of about 50 DEG to about 350 DEG C. and at a pressure of about 500 psig or greater.

专利号:US-2018194700-A1
优先权日:2015-07-02
标题 :Catalyst and method of preparing light olefin directly from synthesis gas by one-step process