= 88-45-9 反应条件:1.1 Reagents: Sulfuric Acid; 35 °C; 35 °C -> 145 °C; 7 H,145 °C; 145 °C -> 90 °C1.2 Reagents: Water; < 100 °C; 100 °C -> 137 °C; 3 H,135 - 137 °C 标题:Synthesis Of 2,5-Diaminobenzenesulfonic Acid And Its Application In Dyestuffs 作者:Yang,Hongde; Et Al 参考文献:Ranliao Yu Ranse 日期:2011 卷标:48(2) 页码:41-44]
88-45-9 = 88-45-9 反应条件:1.1 Catalysts: Hydrogen Peroxide Solvents: Water,Ultravon Pl; 7 H,30 - 70 °C 标题:Peroxidase-Catalysed Coloration Of Wool Fabrics 作者:Netithammakorn,Nalinee; Et Al 参考文献:Coloration Technology 日期:2021 卷标:137(2) 页码:93-107]
61-73-4 = 88-45-9 + 98-89-5 反应条件:1.1 Catalysts: 2815266-06-7; 1 Bar,273 K 标题:Selective And Multicyclic Co2 Adsorption With Visible Light-Driven Photodegradation Of Organic Dyes In A Robust Metal-Organic Framework Embracing Heteroatom-Affixed Pores 作者:Singh,Manpreet; Et Al 参考文献:Inorganic Chemistry 日期:2022 卷标:61(28) 页码:10731-10742]
533-30-2 = 88-45-9 反应条件:1.1 Reagents: Sodium Hydroxide,Benzenesulfonamide,N-Bromo-,Sodium Salt (1:1) Catalysts: Chloro[2-[[(1H-Pyrrol-2-Yl-Kn)Methylene]Amino-Kn]Phenolato(2-)-Ko]Bis(Triphenylp... Solvents: Acetonitrile,Water; 260 Min,313 K 标题:Development Of An Efficient Ruthenium Catalyzed Synthetic Process And Mechanism For The Facile Conversion Of Benzothiazoles To Orthanilic Acids 作者:Jagadeesh,R. V.; Et Al 参考文献:Journal Of Molecular Catalysis A: Chemical 日期:2010 卷标:328(1-2) 页码:99-107]
96-75-3 = 88-45-9 反应条件:1.1 Reagents: Hydrogen; 1 Mpa,Rt -> 90 °C; 1 Mpa,90 - 100 °C1.2 Reagents: Hydrogen Ion 标题:Synthesis Of Tridiglycolamine 2,5-Diacetoacetylaminobenzene Sulfonate 作者:Li,Fu-Gang; Et Al 参考文献:Jingxi Yu Zhuanyong Huaxuepin 日期:2008 卷标:16 页码:30-31
专利信息
专利号:US-8034895-B2 优先权日:2004-02-04 标题 :Conjugated thiophenes having conducting properties and synthesis of same 发明人:SKENE WILLIAM G 权利人:UNIV MONTREAL 摘要:The present invention relates to conjugated oligomers and polymers comprising aromatic thiophene cores. The conjugated materials are obtained by simple and efficient condensation of an aryl diamine and an aryl dialdehyde or a bifunctional aryl moiety comprising both an aldehyde and an amine. Condensation of the complementary moieties at temperatures ranging from ambient to refluxing temperatures in various solvents resulted in conjugated oligomers and polymers that can subsequently be cast into thin films. Oligomerization and polymerization can be done under mild conditions with removal of the resulting water bi-product responsible for shifting the equilibrium in favor of the conjugated products. The resulting conjugated compounds can be made conducting with dopants affording electrically conducting materials of either p-type or n-type conductors depending on the dopant selected.
专利号:US-4719053-A 优先权日:1980-08-01 标题 :Beta-chloroethylsulfonylmethyl-benzoic halides as intermediates 发明人:SCHLAEFER LUDWIG; HAEHNLE REINHARD 权利人:HOECHST AG 摘要:New beta -chloroethylsuflonylmethyl-benzoic acid halides which can serve as fibre-reactive anchors for thesynthesis of novel organic, water-soluble compounds, preferably dyestuffs, having fibre-reactive and fibre-finishing properties, such as preferably dyestuff properties, and containing, as a fibre-reactive group, one or two beta -chloroethylsufonylmethylbenzoic acid amide groups. For the synthesis of these novel fibre-finishing compounds, said new beta -chloroethylsulfonylmethyl-benzoic acid halide compounds are reacted with an organic, water-soluble compound having fibre-finishing properties and continuing one or two amino groups. Also precursors of the fibre-finishing, fibre-reactive compounds, containing said beta -chloroethylsulfonylmethyl-benzxoic acid amid grouping, can be employed for their synthesis. The novel fibre-finishing compounds can be applied onto suitable fibre materials, such as especially cellulose fibre material and natural or synthetic polyamide fibre materials, and fixed on these fibre materials in a manner similar to application and fixation methods usual in the technique for fibre-reactive compounds. The fibre-finished material, such as dyed material, shows very good wet fastnesses.
专利号:US-7511113-B2 优先权日:2002-04-26 标题:Oligomeric hydroxy arylether phthalonitiles and synthesis thereof 发明人:KELLER TEDDY M; DOMINGUEZ DAWN D 权利人:US NAVY 摘要:An aromatic ether oligomer or polyaromatic ether comprising the formula:n n O—Ar n ;n nwherein Ar is an independently selected divalent aromatic radical; formed by reacting a dihydroxyaromatic with a dihaloaromatic; and wherein the reaction is performed in the presence of a copper compound and cesium carbonate. The polyaromatic ether is formed when neither the dihydroxyaromatic nor the dihaloaromatic is present in an excess amount. The aromatic ether oligomer is formed by using an excess of either dihydroxyaromatic or dihaloaromatic. A phthalonitrile monomer comprising the formula:n n nformed by reacting a 3- or 4-nitrophthalonitrile with a hydroxy-terminated aromatic ether oligomer. A thermoset formed by curing the phthalonitrile monomer. Processes for forming all the above.
专利号:US-2007287842-A1 优先权日:2004-02-04 标题 :Conjugated Thiophenes Having Conducting Properties and Synthesis of Same
专利号:CA-2718534-A1 优先权日:2008-03-26 标题 :Process for the synthesis of ethynylcyclopropane
专利号:US-2012004386-A1 优先权日:2004-02-04 标题 :Conjugated thiophenes having conducting properties and synthesis of same
[参考文献]: Hristina Hadzhiyska, Et Al. Laccase-Assisted Dyeing Of Cotton. Biotechnol Lett. 2006 May;28(10):755-9. [参考文献]: Tzanko Tzanov, Et Al. Effect Of Some Process Parameters In Enzymatic Dyeing Of Wool. Appl Biochem Biotechnol. 2003 Oct;111(1):1-13.
合成参考文献
参考文献:10.1002/cssc.201500755 摘要:Peng Y, Hu Z, Gao Y, Yuan D, Kang Z, Qian Y, Yan N, Zhao D. Synthesis of a Sulfonated Two-Dimensional Covalent Organic Framework as an Efficient Solid Acid Catalyst for Biobased Chemical Conversion. ChemSusChem. 2015 Oct 12;8(19):3208–12. doi: 10.1002/cssc.201500755.