📜1-溴环己烷羧酸乙酯置于甲酸,乙醚,Magnesium,溶剂黄146,铂,苯体系中,化学反应生成 [1,1-双环己基]-1-羧酸 参考文献:Jacques; Weidmann,Bulletin De La Societe Chimique De France,1958,P. 1478,1482 标题:Jacques; Weidmann,Bulletin De La Societe Chimique De France,1958,P. 1478,1482
专利号:US-4361494-A 优先权日:1979-12-17 标 题 :Anisotropic cyclohexyl cyclohexylmethyl ethers 发明人:OSMAN MAGED A; REVESZ LASZLO 权利人:BBC BROWN BOVERI & CIE 摘要:New anisotropic compounds suitable for use in LC-display devices are disclosed and claimed. The new compounds are cyclohexyl cyclohexylmethyl ethers of formula (1): ##STR1## in which X and Y are respectively hydrogen, alkyl group with 1 to 12 C-atoms, alkoxy group with 1 to 12 C-atoms, monoalkylamino group with 1 to 12 C-atoms, nitrile group, nitro group, halogen, or cyclic radical of formula (1a) or (1b): ##STR2## in which R 1 and R 2 represent hydrogen alkyl group with 1 to 12 C-atoms, alkoxy group with 1 to 12 C-atoms, monoalkylamino group with 1 to 12 C-atoms, nitrile group, nitro group or halogen, and Z 1 and Z 2 represent simple covalent bonds or grounds of the formulas --COO--, --OOC--, --CH 2 O-- or --OCH 2 , with the requirement that only one of the groups X, Y can be a cyclicradical or formula (1a) or (1b). Also disclosed and claimed are LC-mixtures containing these compounds and methods for their synthesis.
参考文献:10.1007/s11178-005-0044-y 摘要:Kovganko VN, Kovganko NN, Bezborodov VS. Synthesis of new liquid crystalline compounds containing an α,β-unsaturated ketone and β-chloroketone groups in the side chain. Russian Journal of Organic Chemistry. 2004 Oct;40(10):1477–82. doi: 10.1007/s11178-005-0044-y.