CAS: 27025-25-8; H-D-Glu(Ome)-Ome.Hcl

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methanol Glutamic acid D-Glutamic acidN-{4-[(2-oxo-benzooxazol-3-ylmethyl)-amino]-benzoyl}-glutamic acid dimethyl esterN-{4-[(2-oxo-benzooxazol-3-ylmethyl)-amino]-benzoyl}-glutamic acid dimethyl ester N-{4-[(2-thioxo-benzothiazol-3-ylmethyl)-amino]-benzoyl}-glutamic acid dimethyl esterN-{4-[(2-thioxo-benzothiazol-3-ylmethyl)-amino]-benzoyl}-glutamic acid dimethyl ester 16H20N2O7SC16H20N2O7S pyrimidin-6-yl)ethenyl>benzoyl>-L-glutamatedimethyl N-4-2-(2-amino-1,4-dihydro-5-methyl-4-oxopyrido2,3-dpyrimidin-6-yl)ethenylbenzoyl-L-glutamate

合成工艺路线路线简述

    📜甲醇,D-谷氨酸置于氯代叔丁烷体系中,化学反应生成D-谷氨酸二甲酯盐酸盐
    参考文献:毒素a及其立体异构体的全合成及其生物学活性的发现
    标题:毒素a及其立体异构体的全合成及其生物学活性的发现
    摘要:已经成功实现了纤溶酶a及其三种立体异构体的首次合成.合成方法涉及酰胺向酮酰胺基团的分子内亲核环化,以产生c-羟基二酮哌嗪骨架.最令人惊讶的发现是,Ta的四种立体异构体中的每一种均表现出不同的植物毒,杀真菌和抗病毒活性.
    Doi:10.1021/ol4026556

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    专利信息


    专利号:US-2025163089-A1
    优先权日:2023-11-17
    标 题:Branched Molecules for Redox Flow Batteries
    发明人:EVANS PAUL; SISTO THOMAS; BENCIVENGA ANTHONY; CHAMPSAUR ANOUCK
    权利人:XL BATTERIES INC
    摘要:Compounds with redox molecular cores and branched molecular tails comprising ionic functionalities for uses as electrolytes in redox flow batteries are described, as well as methods of synthesis and use thereof. The compounds have redox active perylene diimide or ferrocene molecular core decorated with the branched molecular tails having multiple ionic functionalities to improve water solubility of the molecular core, and, as such, its performance as the electrolyte.

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    ✅ COA系统入驻 | 共享模式

    合成参考文献


    参考文献:10.1134/s1070428019060046
    摘要:Musiyak VV, Nizova IA, Matveeva TV, Levit GL, Krasnov VP, Charushin VN. Synthesis of New Purine Derivatives Containing α- and ω-Amino Acid Fragments. Russian Journal of Organic Chemistry. 2019 Jun;55(6):762–70. doi: 10.1134/s1070428019060046.
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