CAS: 13759-87-0; Samarium Bromide

该化合物是一种无机化合物,由Samior,稀土元素和溴组成,通常看起来像是晶状固体,以其血压性质而著称,这意味着它能吸收空气中的湿度. Samior溴经常用于各种用途,包括作为有机合成的试剂和制备以Samior为基础的催化剂.由于存在含硫胺,具有未腐蚀的f-electron,该化合物显示出有趣的磁性.在溶解性方面,SmBr3在极地溶剂中溶解,因此在某些化学反应中有用.其结构由与溴离子协调的Samior离子组成,有助于其稳定性和再活性.在处理该化合物时,应当采取安全防范措施,因为它可能会对皮肤和眼睛产生刺激.

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CAS号7440-19-9 钐粉

合成工艺路线路线简述

    📜溴化铵钐 以 Neat (No Solvent) 用作溶剂,化学反应生成六水溴化钐
    参考文献:The Ammonium-Bromide Route To Anhydrous Rare Earth Bromides Mbr3
    标题:The Ammonium-Bromide Route To Anhydrous Rare Earth Bromides Mbr3
    摘要:
    Doi:10.1016/0022-5088(87)90372-9

    专利信息


    专利号:US-7485741-B2
    优先权日:2002-12-02
    标 题:Method of producing nitrile compounds from ethylenically-unsaturated compounds
    发明人:BOURGEOIS DAMIEN; GALLAND JEAN-CHRISTOPHE; DIDILLON BLAISE; MARION PHILIPPE
    权利人:RHODIA POLYAMIDE INTERMEDIATES
    摘要:The present invention relates to a process for hydrocyanating a hydrocarbon-based compound containing at least one ethylenic unsaturation by reaction in liquid medium with hydrogen cyanide in the presence of a catalyst comprising a metal element chosen from transition metals and an organophosphorus ligand, characterized in that the organophosphorus ligand is a monodentate organophosphorus compound. The present invention is in particular useful for the synthesis of adiponitrile from butadiene.

    专利号:US-12209104-B1
    优先权日:2018-07-11
    标 题:Metal complexes and methods of making the same
    发明人:KIPLINGER JAQUELINE; BEATTIE ROSS; PAGANO JUSTIN; ERICKSON KARLA
    权利人:TRIAD NAT SECURITY LLC
    摘要:Disclosed herein are embodiments of metal complexes and methods of making the same. The disclosed method embodiments provide a one-step approach to making metal complexes, such as complexes comprising lanthanide metals, rare earth metals, transition metals, main group metals, and/or actinide metals that can be used various applications, such as in separations technology, catalysis (e.g., catalysts for pharmaceutical synthesis and/or catalysts for biomass conversion), nuclear chemistry, LED phosphors, scintillator materials, magnetic materials, and nuclear fuels.

    专利号:US-4436837-A
    优先权日:1982-09-29
    标 题:Preparation of alkanols from synthesis gas
    发明人:LIN JIANG-JEN
    权利人:TEXACO INC
    摘要:This invention concerns a process for making alkanols and esters which comprises reacting a mixture of CO and H2 at a pressure of about 500 psig or greater and at a temperature of at least 150 DEG C. in the presence of a catalyst system comprising a ruthenium-containing compound, a samarium compound and a quaternary phosphonium salt, in the presence of an inert, oxygenated solvent.

    专利号:US-2023212024-A1
    优先权日:2020-04-14
    标 题:New lithium rare-earth halides
    发明人:BRAIDA MARC-DAVID
    权利人:SOLVAY
    摘要:The present invention concerns new lithium rare earth halides that may be used as solid electrolytes or in electrochemical devices. The invention also refers to wet and dry processes for the synthesis of such lithium rare earth halides and lithium rare earth halides susceptible to be obtained by these processes.

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    ✅ COA系统入驻 | 共享模式

    合成参考文献


    参考文献:10.1007/s10947-006-0233-8
    摘要:Giricheva NI, Shlykov SA, Chernova EV, Levina YS, Krasnov AV. Molecular structure of SmBr3 and DyBr3 according to the data of simultaneous electron diffraction and mass spectrometric experiment. Journal of Structural Chemistry. 2005 Nov;46(6):991–7. doi: 10.1007/s10947-006-0233-8.
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