CAS: 82-68-8; Pentachloronitrobenzene

该化合物是一种主要用作土壤杀菌剂和种子处理剂的氯化硝化物化合物,其化学结构由五氯原子和硝基化合物组成,具有很强的抗风素特性,特别是针对Rhizoctonia和Sclerotinia等土壤传播的病原体.PCNB因其在土壤中的持久性而具有价值,为棉花,马铃薯和装饰植物等作物提供长期保护,它通常作为一种湿润的粉末或颗粒产品,用于农业用途.虽然有效,但其使用需要遵守监管准则,但考虑到环境和毒性因素.适当的处理和应用对于最大限度地减少非目标影响至关重要.

结构式图片

欧盟法规

《欧盟PIC法规》统一分类与标签"欧盟管控危险化学品"ECHA物质工作场所安全标识要求ECHA物质OtherC&L通报REACH预注册废弃物危险特性清单

上下游产品

pentachlorobenzene 2,3,4,5,6-pentachloroiodobenzene pentachloro-isopropyl-benzene morpholinePentachloroanisole pentachlorofluorobenzene 2,3,4,5,6-pentachloroaniline pentachlorothiophenol

合成工艺路线路线简述

  • 合成目标产物 Quintozine 主要起始原料 Hexachlorobenzene
  • (文献来源)合成步骤主要原料 Hexachlorobenzene
Pentachloro-Isopropyl-Benzene置于硝酸体系中,化学反应生成 五氯硝基苯
参考文献:Qvist,Acta Academiae Aboensis,Series B: Mathematica Et Physica,1934,Vol. 8,# 4,P. 25
标题:Qvist,Acta Academiae Aboensis,Series B: Mathematica Et Physica,1934,Vol. 8,# 4,P. 25

海关参考信息

专利信息


专利号:WO-0027627-A1
优先权日:1998-11-12
标题 :Aryloxime linkers in the solid-phase synthesis of 3-aminobenzisoxazoles
发明人:WILEY MICHAEL ROBERT; LEPORE SALVATORE DONATO
权利人:LILLY CO ELI; WILEY MICHAEL ROBERT; LEPORE SALVATORE DONATO
摘要:In its first aspect, the invention is directed to a solid support mediated method for the synthesis of diverse polycyclic heterocycles according to general formula (V). A second aspect of the invention is directed to a solid support bound intermediate compound that optionally can be derivatized before a cyclization and displacement procedure provides a product. The intermediate is preferably stable to a wide range of chemical conditions thus allowing, if desired, for the chemical derivatization of the intermediate. A third aspect of the invention is directed to a library of polycyclic heterocycle compounds where said library contains a plurality of diverse library compounds of general formula (V). A fourth aspect of the invention is directed to a method for the synthesis of a library of diverse polycyclic heterocycles by the general method described. A fifth aspect of the invention is directed to an assay kit for the identification of lead compounds of the library described therein.

专利号:US-8071782-B2
优先权日:2007-10-02
标 题 :Synthesis of 1,3,4-trisubstituted and 1,3,4,5-tetrasubstituted pyrazoles
发明人:DENG XIAOHU; MANI NEELAKANDHA S
权利人:DENG XIAOHU; MANI NEELAKANDHA S; JANSSEN PHARMACEUTICA NV
摘要:This invention concerns the synthesis of highly substituted pyrazoles, which are structural components of pharmacological compounds, through reaction of hydrazones with nitroolefins.

专利号:US-9834570-B2
优先权日:2013-06-03
标 题 :One step process for regioselective synthesis of α-acyloxy carbonyls
发明人:SUDALAI ARUMUGAM; REDDI RAMBABU; MALEKAR PUSHPA
权利人:COUNCIL SCIENT IND RES
摘要:A regioselective N-Heterocyclic Carbene (NHC) catalyzed one step process for high yield synthesis of α-acyloxy carbonyl compounds is disclosed.

专利号:US-4683332-A
优先权日:1985-05-20
标 题 :Para-nitrodiphenylamine synthesis
发明人:STURM BUDD H
权利人:GOODYEAR TIRE & RUBBER
摘要:There is disclosed a process for the synthesis of para-nitrodiphenylamines via the Formanilide Process wherein the improvement is characterized in that a specific catalyst is utilized. More specifically, a zinc (II) compound (zinc in the plus two oxidation or valence state), is used as a catalyst in the preparation of para-nitrodiphenylamines via the formanilide process.

专利号:US-4435599-A
优先权日:1982-11-26
标 题 :Para-nitrodiphenylamine synthesis
发明人:STURM BUDD H
权利人:GOODYEAR TIRE & RUBBER
摘要:There is disclosed a process for the synthesis of para-nitrodiphenylamines wherein the improvement is characterized in that a specific co-catalyst system is utilized. More specifically, a zinc (II) compound (zinc in the plus two oxidation or valence state), is used in conjunction with copper or a copper compound as a co-catalyst system in the preparation of para-nitrodiphenylamines.

专利号:US-2023111600-A1
优先权日:2019-12-17
标题 :Polymeric fatty acid compounds for the treatment of fibrous amino acid-based substrates, especially hair
发明人:WAGNER ROLAND; STREICHER KATHARINA; ROHMANN LAURA; WENSKE CHRISTIAN; HAVELI SHRUTISAGAR DATTATRAYA
权利人:MOMENTIVE PERFORMANCE MAT GMBH
摘要:The present invention is directed at mono-, di- or polyquaternary ammonium compounds of the formula (I) wherein x is 1 to 50, and F can be the same or different and is represented by the general formula (II) wherein at least one of the optionally substituted and optionally functional-group-containing hydrocarbon radicals R 1 , R 2 , R 3 , R 4 or R 5 contains at least one estolide moiety comprising two or more ester or amide moieties. The invention also relates to a process for the synthesis of such compounds, the use of the compounds in cosmetic formulations for skin and hair care, cosmetic compositions for the treatment of fibers, and compositions containing one or more of the compounds for the treatment of hair.
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主要参考文献


1: Nájera JFD, Castellanos JS, Hernández MV, Serna SA, Gómez OGA, Verduzco CV, Ramos MA. Diagnosis and Integrated Management of Fruit Rot in Cucurbita argyrosperma, Caused by Sclerotium rolfsii. Plant Pathol J. 2018 Jun;34(3):171-181. doi: 10.5423/PPJ.OA.08.2017.0185. Epub 2018 Jun 1.
2: Li J, Wang P, Shi S, Xue J. Background biomonitoring of residue levels of 137 pesticides in the blood plasma of the general population in Beijing. Environ Monit Assess. 2018 Apr 29;190(5):315. doi: 10.1007/s10661-018-6694-3. doi: 10.1016/j.ecoenv.2018.03.070. Epub 2018 Apr 2. doi: 10.1016/j.chemosphere.2017.03.138. Epub 2017 Apr 4. doi: 10.1007/s11356-017-8640-2. Epub 2017 Feb 25. doi: 10.1016/j.jchromb.2016.03.009. Epub 2016 Mar 9. doi: 10.1016/j.scitotenv.2015.10.148. Epub 2015 Nov 3. doi: 10.1016/j.chemosphere.2015.09.008. Epub 2015 Sep 25. doi: 10.1111/lam.12476. doi: 10.1021/acs.est.5b01303. Epub 2015 Aug 18. doi: 10.1007/s11356-014-3507-2. Epub 2014 Aug 30. doi: 10.1007/s11356-014-2648-7. Epub 2014 Mar 2. doi: 10.1016/j.talanta.2013.10.006. Epub 2013 Oct 16. Review. doi: 10.1021/ac400481w. Epub 2013 Apr 15. doi: 10.1016/j.jenvman.2013.02.004. Epub 2013 Mar 8. doi: 10.1016/j.jhazmat.2013.01.072. Epub 2013 Feb 4. doi: 10.1016/j.chemosphere.2012.03.058. Epub 2012 Apr 17. doi: 10.1016/j.jhazmat.2011.10.045. Epub 2011 Oct 18. doi: 10.1007/s11046-010-9339-9. Epub 2010 Jun 27. doi: 10.1021/jf903851h.

合成参考文献


参考文献:10.3390/ijerph8062265
摘要:Mnif W, Hassine AI, Bouaziz A, Bartegi A, Thomas O, Roig B. Effect of endocrine disruptor pesticides: a review. Int J Environ Res Public Health. 2011 Jun;8(6):2265–303.
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