CAS: 79917-88-7; 1,3-Dimethyl-1H-Imidazol-3-Ium Chloride

该化合物是一种有机化合物,其特点是其结构,其特点是五人芳香环,内含两个氮原子;该化合物一般是室内温度下白色至非白固体的白色,可溶于水和酒精等极地溶剂,在各种应用中有用,包括用作离子液体;二甲基组的存在增强了其溶性性和稳定性;作为四硝基铵盐,它表现出了有助于其传导性和在电化学应用中潜在用途的离子特性;此外,它可以作为有机合成中的催化剂或溶剂,并且由于与传统溶剂相比其挥发性小和环境影响较小,因此对绿色化学领域很感兴趣;其氯化铁离子可以参与各种化学反应,使其在合成化学中具有多种特性.总的来说,1,3-二甲基-1H-imidazol-3-ium氯化物因其独特的结构特性和功能而引人注目.

英文名称1,3-Dimethyl-1H-Imidazol-3-Ium Chloride
中文名称氯化1,3-二甲基咪唑
IUPAC名称1,3-dimethyl-1H-imidazol-3-ium chloride
其它别名1,3-二甲基-3-氯化咪唑鎓; 1,3-Dimethylimidazolium Chloride
CAS编号79917-88-7
MFCD编号:MFCD08276366
EINECS号:680-194-7
分子式:C5H9ClN2
分子量:132.59
产品CID: 1792860
产品分类有机原料→分子砌块→芳杂环类化合物→咪唑类化合物

相似结构搜索
InChIKey: IIJSFQFJZAEKHB-UHFFFAOYSA-M
InChI=1S/C5H9N2.ClH/c1-6-3-4-7(2)5-6;/h3-5H,1-2H3;1H/q+1;/p-1…
计算化学: 氢键受体数1.0氢键供体数0.0可旋转键数0.0

相似化合物

4333-62-4 243664-15-5 65039-11-4

MSDS等安全信息

GHS象形图
GHS符号GHS07;
注释: Exclamation mark
危险类别皮肤腐蚀/刺激类别2
严重眼刺激类别2
警示词Warning(警告)
危险描述H315 |造成皮肤刺激.
H319 |造成严重眼刺激.
防范说明P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501
危险品标志Xi
安全声明H303+H313+H333

欧盟法规

C&L通报

上下游产品

methylene chloride 1-(Trimethylsilyl)imidazole 1-methyl-1H-imidazole 1,3-dimethylimidazolim iodide norzooanemonin N,N'-dimethylimidazolium-2-carboxylate 1,3-dimethyl-1H-imidazol-3-ium hydrogen carbonate 1-methyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide

合成工艺路线路线简述

35487-17-3 = 79917-88-7
反应条件:1.1 Rt
标题:A Novel And Green Method For The Synthesis Of Ionic Liquids Using The Corresponding Acidic Ionic Liquid Precursors And Dialkyl Carbonate
作者:Xiao,Wenjun; Et Al
参考文献:Chemistry Letters 日期:2010 卷标:39(10) 页码:1112-1113]

4333-62-4 = 79917-88-7
反应条件:1.1 Reagents: Amberlite Solvents: Water; Rt1.2 Reagents: Hydrochloric Acid Solvents: Water; Ph 7
标题:A Magnetic Ionic Liquid Based On Tetrachloroferrate Exhibits Three-Dimensional Magnetic Ordering: A Combined Experimental And Theoretical Study Of The Magnetic Interaction Mechanism
作者:Garcia-Saiz,Abel; Et Al
参考文献:Chemistry - A European Journal 日期:2014 卷标:20(1) 页码:72-76]

4333-62-4 = 79917-88-7
反应条件:1.1 Reagents: Amberlite Irn 78 Solvents: Water; Rt1.2 Reagents: Hydrochloric Acid Solvents: Water; Neutralized
标题:Formation And Substructure Of Cellulose/ionic Liquid Complex Crystals: Results From Wide-Angle X-Ray Scattering And Solid-State 13C Nmr Spectroscopy
作者:Endo,Takatsugu; Et Al
参考文献:Crystal Growth & Design 日期:2022 卷标:22(12) 页码:7603-7610]

288-32-4 = 79917-88-7
反应条件:1.1 Reagents: Hydrochloric Acid Solvents: Water; Rt; 1 H,Ph 3,Rt1.2 3 H,6 Bar,140 °C
标题:Nanocage Formation And Structural Anomalies In Imidazolium Ionic Liquid Glasses Governed By Alkyl Chains Of Cations
作者:Bakulina,Olga D.; Et Al
参考文献:Nanoscale 日期:2020 卷标:12(38) 页码:19982-19991]

154193-84-7 = 79917-88-7
反应条件:1.1 Reagents: Peroxynitrite Radical Solvents: Water; Cooled; 12 H,Rt1.2 Reagents: Hydrochloric Acid Solvents: Water; Neutralized
标题:Antithyroid Drugs And Their Analogues Protect Against Peroxynitrite-Mediated Protein Tyrosine Nitration - A Mechanistic Study
作者:Bhabak,Krishna P.; Et Al
参考文献:Chemistry - A European Journal 日期:2010 卷标:16(4) 页码:1175-1185]

6596-81-2 = 79917-88-7
反应条件:1.1 Reagents: Peroxynitrite Radical Solvents: Water; Cooled; 12 H,Rt1.2 Reagents: Hydrochloric Acid Solvents: Water; Neutralized
标题:Antithyroid Drugs And Their Analogues Protect Against Peroxynitrite-Mediated Protein Tyrosine Nitration - A Mechanistic Study
作者:Bhabak,Krishna P.; Et Al
参考文献:Chemistry - A European Journal 日期:2010 卷标:16(4) 页码:1175-1185]

616-47-7 = 79917-88-7
反应条件:1.1 Solvents: Tetrahydrofuran; 24 H,Heated
标题:On The Interaction Of N-Heterocyclic Carbene Ir+i Complexes With His And Cys Containing Peptides
作者:Daubit,Isabelle Marie; Et Al
参考文献:Dalton Transactions 日期:2019 卷标:48(36) 页码:13662-13673]

18156-74-6 = 79917-88-7 [标题:Reaction Conditions
标题:Convenient And General Synthesis Of Symmetrical N,N'-Disubstituted Imidazolium Halides
作者:Harlow,Karsten J.; Et Al
参考文献:Synthesis 日期:1996 卷标:(6) 页码:697-698]

616-47-7 = 79917-88-7
反应条件:1.1 Solvents: Water; 4 Min,Heated
标题:Study On The Microwave-Assisted Synthesis Of Ionic Liquids
作者:Hong,Shu-Cui
参考文献:Shandong Huagong 日期:2011 卷标:40(10) 页码:22-24]

616-47-7 = 79917-88-7
反应条件:1.1 Solvents: Dimethylformamide; 24 H,Reflux
标题:Effect Of Anion Type Of Imidazolium Based Polymer Supported Ionic Liquids On The Solvent Free Synthesis Of Cycloaddition Of Co2 Into Epoxide
作者:Jadhav,Arvind H.; Et Al
参考文献:Catalysis Today 日期:2016 卷标:265 页码:56-67]

536755-29-0 = 79917-88-7
反应条件:1.1 Reagents: Hydrochloric Acid Solvents: Ethanol,Water; Rt; 24 H,Rt
标题:Ionic Liquids Via Reaction Of The Zwitterionic 1,3-Dimethylimidazolium-2-Carboxylate With Protic Acids. Overcoming Synthetic Limitations And Establishing New Halide Free Protocols For The Formation Of Ils
作者:Smiglak,Marcin; Et Al
参考文献:Green Chemistry 日期:2007 卷标:9(1) 页码:90-98]

39678-28-9 = 79917-88-7
反应条件:1.1 Solvents: Ethanol,Water; 100 Min,35 °C
标题:An Efficient Ultrasonic-Assisted Synthesis Of Imidazolium And Pyridinium Salts Based On The Zincke Reaction
作者:Zhao,Sanhu; Et Al
参考文献:Ultrasonics Sonochemistry 日期:2010 卷标:17(4) 页码:685-689]

70042-96-5 = 79917-88-7
反应条件:1.1 Reagents: Amberlite Irn 781.2 Reagents: Hydrochloric Acid Solvents: Water; Neutralized
标题:Origin Of Low Melting Point Of Ionic Liquids: Dominant Role Of Entropy
作者:Endo,Takatsugu; Et Al
参考文献:Chemical Science 日期:2022 卷标:13(25) 页码:7560-7565]

616-47-7 = 79917-88-7
反应条件:1.1 Solvents: Ethyl Acetate; 0 °C; 2 H,0 °C2.1 Reagents: Amberlite Irn 78 Solvents: Water; Rt2.2 Reagents: Hydrochloric Acid Solvents: Water; Neutralized
标题:Formation And Substructure Of Cellulose/ionic Liquid Complex Crystals: Results From Wide-Angle X-Ray Scattering And Solid-State 13C Nmr Spectroscopy
作者:Endo,Takatsugu; Et Al
参考文献:Crystal Growth & Design 日期:2022 卷标:22(12) 页码:7603-7610]

616-47-7 = 79917-88-7
反应条件:1.1 Solvents: 1,4-Dioxane; 5 H,100 °C
标题:Selenium-N-Heterocyclic Carbene (Se-Nhc) Complexes With Higher Aromaticity Inhibit Microbes: Synthesis,Structure,And Biological Potential
作者:Kamal,Amna; Et Al
参考文献:Journal Of Coordination Chemistry 日期:2022 卷标:75(11-14) 页码:1915-1928]

616-47-7 = 79917-88-7
反应条件:1.1 Solvents: Acetone; 80 Min,40 °C2.1 Solvents: Ethanol,Water; 100 Min,35 °C
标题:An Efficient Ultrasonic-Assisted Synthesis Of Imidazolium And Pyridinium Salts Based On The Zincke Reaction
作者:Zhao,Sanhu; Et Al
参考文献:Ultrasonics Sonochemistry 日期:2010 卷标:17(4) 页码:685-689]

616-47-7 = 79917-88-7
反应条件:1.1 Reagents: Hydrochloric Acid; Neutralized2.1 Rt
标题:A Novel And Green Method For The Synthesis Of Ionic Liquids Using The Corresponding Acidic Ionic Liquid Precursors And Dialkyl Carbonate
作者:Xiao,Wenjun; Et Al
参考文献:Chemistry Letters 日期:2010 卷标:39(10) 页码:1112-1113

1,3-二甲基咪唑碘置于盐酸体系中,用水作为反应溶剂,以93%的收率获得产物氯化1,3-二甲基咪唑
参考文献:基于四氯高铁酸盐的磁性离子液体表现出三维磁有序性:电磁相互作用机理的组合实验和理论研究
标题:基于四氯高铁酸盐的磁性离子液体表现出三维磁有序性:电磁相互作用机理的组合实验和理论研究
摘要:合成并表征了具有3D反铁磁排序的新型磁性离子液体(mil).通过分析dft计算和磁结构相关性,可以补充从磁特性获得的信息.该结果没有直接铁相互作用的证据,证实了mil中的3D磁性有序是通过包含两个反磁性原子中间体的超交换耦合发生的.
DOI:10.1002/chem.201303602

专利信息

专利号:US-2005087449-A1
优先权日:2002-03-04
标题:Electrochemical synthesis of ammonia
发明人：DENVIR ADRIAN; MURPHY OLIVER J; CISAR ALAN; ROBERTSON PRISCILLA; USELTON KYLE
摘要:A method for electrochemical synthesis of ammonia gas comprising providing an electrolyte between an anode and a cathode, providing hydrogen gas to the anode, oxidizing negatively charged nitrogen-containing species present in the electrolyte at the anode to form an adsorbed nitrogen species, and reacting the hydrogen with the adsorbed nitrogen species to form ammonia. Preferably, the hydrogen gas is provided to the anode by passing the hydrogen gas through a porous anode substrate. It is also preferred to produce the negatively charged nitrogen-containing species in the electrolyte by reducing nitrogen gas at the cathode. However, the negatively charged nitrogen-containing species may also be provided by supplying a nitrogen-containing salt, such as lithium nitride, into the molten salt electrolyte mixture in a sufficient amount to provide some or all of the nitrogen consumed in the production of ammonia.

专利号:US-6712950-B2
优先权日:2002-03-04
标题 :Electrochemical synthesis of ammonia
发明人：DENVIR ADRIAN; MURPHY OLIVER J; CISAR ALAN; ROBERTSON PRISCILLA; USELTON KYLE
权利人:LYNNTECH INC
摘要:A method for electrochemical synthesis of ammonia gas comprising providing an electrolyte between an anode and a cathode, providing hydrogen gas to the anode, oxidizing negatively charged nitrogen-containing species present in the electrolyte at the anode to form an adsorbed nitrogen species, and reacting the hydrogen with the adsorbed nitrogen species to form ammonia. Preferably, the hydrogen gas is provided to the anode by passing the hydrogen gas through a porous anode substrate. It is also preferred to produce the negatively charged nitrogen-containing species in the electrolyte by reducing nitrogen gas at the cathode. However, the negatively charged nitrogen-containing species may also be provided by supplying a nitrogen-containing salt, such as lithium nitride, into the molten salt electrolyte mixture in a sufficient amount to provide some or all of the nitrogen consumed in the production of ammonia.

专利号:US-6881308-B2
优先权日:2002-03-04
标题 :Electrochemical synthesis of ammonia
发明人：DENVIR ADRIAN J; MURPHY OLIVER J; CISAR ALAN J; ROBERTSON PRISCILLA; USELTON KYLE
权利人:LYNNTECH INC
摘要:A method for electrochemical synthesis of ammonia gas comprising providing an electrolyte between an anode and a cathode, providing hydrogen gas to the anode, oxidizing negatively charged nitrogen-containing species present in the electrolyte at the anode to form an adsorbed nitrogen species, and reacting the hydrogen with the adsorbed nitrogen species to form ammonia. Preferably, the hydrogen gas is provided to the anode by passing the hydrogen gas through a porous anode substrate. It is also preferred to produce the negatively charged nitrogen-containing species in the electrolyte by reducing nitrogen gas at the cathode. However, the negatively charged nitrogen-containing species may also be provided by supplying a nitrogen-containing salt, such as lithium nitride, into the molten salt electrolyte mixture in a sufficient amount to provide some or all of the nitrogen consumed in the production of ammonia.

专利号:US-2003164292-A1
优先权日:2002-03-04
标题:Electrochemical synthesis of ammonia

专利号:US-2008214386-A1
优先权日:2004-03-01
标题:Catalyst for Cyclic Carbonate Synthesis
发明人：TAKAHASHI TOSHIKAZU; WATAHIKI TSUTOMU; YASUDA HIROYUKI; SAKAKURA TOSHIYASU
权利人:TAKAHASHI TOSHIKAZU; WATAHIKI TSUTOMU; YASUDA HIROYUKI; SAKAKURA TOSHIYASU
摘要:Provided are a solid catalyst which gives a cyclic carbonate at a high yield and a high selectivity, which is stable and which may be readily separated after reaction; and a method of industrially advantageous, inexpensive and safe production of a cyclic carbonate by the use of the catalyst. The catalyst contains an inorganic solid substance having a surface modified with an ionic substance containing a Group 15 element; or contains an ionic substance containing a Group 15 element, and an inorganic solid substance. The modifying group for surface modification of an inorganic solid substance is an ionic substance containing a Group 15 element. The ionic substance containing a Group 15 element is at least one substance selected from organic phosphonium salts, organic ammonium salts, organic arsonium salts and organic antimonium salts.

专利号:CN-115945214-A
优先权日:2022-12-29
标题:Liquid phase catalytic solution for liquid phase synthesis of vinyl chloride by acetylene hydrochlorination, application, method and device for synthesizing vinyl chloride and using method

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主要参考文献

参考标题:Synthesis Of Imidazolidinone, Imidazolone, And Benzimidazolone Derivatives Through Oxidation Using Copper And Air
作者:Dazhi Li,Thierry Ollevier |发布日期:2019.5.17
摘要:Synthetic Method Of Urea Derivatives Using Copper And Air Was Developed. These Mild Conditions Provided Moderate To Very Good Yields For 15 Examples (53-93%), While Low Yields Were Obtained With Sterically Hindered Substrates (3 Examples). The Reaction Was Found To Go Through An In Situ Generated Copper-N-Heterocyclic Carbene, Which Was Then Oxidized Into Cyclic Urea Derivatives Possessing Alkyl, Benzyl

合成参考文献

参考文献:10.1007/s41061-017-0110-2
摘要:Schröder C. Proteins in Ionic Liquids: Current Status of Experiments and Simulations. Topics in Current Chemistry. 2017 Feb 07;375(2):25. doi: 10.1007/s41061-017-0110-2.

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