CAS: 6470-17-3; 5-Amino-2-Methoxybenzenesulfonic Acid

该化合物是一种由氨基和甲氧基功能组组成的全氟辛烷磺酸芳香化合物,其结构使它成为有机合成的多用途中间体,特别是用于生产染料,颜料和药品.全氟辛烷磺酸组在水介质中提高了溶性,而氨基和甲氧代基替代成分则提供了反应性场所,以进一步功能化.该化合物因其稳定性和与一系列化学变异的兼容性而得到评估,包括二氮化和混合反应.其一贯的纯度和明确界定的再活性特征使其适合于需要精细化学和工业工艺中精确分子修改的应用.

结构式图片

欧盟法规

REACH注册ECHA物质C&L通报REACH预注册

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CAS号104-94-9 对甲氧基苯胺 | CAS号3299-63-6 p-Oxanisidide | CAS号871896-30-9 6,6'-dimethoxy-... | CAS号52426-94-5 N,N'-bis(4-meth... | CAS号7664-93-9 硫酸 | CAS号22952-32-5 五氯二甲基苯磺酰氯化物 | CAS号2835-04-3 4-Hydroxy-3-sul...

合成工艺路线路线简述

    N,N'-Bis(4-Methoxyphenyl)Ethane-Bis(Imidoyl) Dichloride置于硫酸体系中,化学反应生成 对氨基苯甲醚-2-磺酸
    参考文献:Bauer,Chemische Berichte,1909,Vol. 42,P. 2110
    标题:Bauer,Chemische Berichte,1909,Vol. 42,P. 2110

    海关参考信息

    专利信息


    专利号:US-5189206-A
    优先权日:1989-03-16
    标题 :Process for the preparation of aminobenzenesulfonic acids
    发明人:HERZIG PAUL
    权利人:CIBA GEIGY CORP
    摘要:There is disclosed a process for the preparation of compounds of formula ##STR1## wherein the symbols are as defined in claim 1, which process comprises dissolving a compound of formula ##STR2## in sulfuric acid, adding this solution to oleum and reacting the mixture in the temperature range from 10° to 80° C. until a sulfo group has been completely introduced, and, in an optional further step, subjecting the reaction mixture to further reaction in the temperature range from 100° to 200° C. to introduce a second sulfo group. n The compounds of formula (1) obtainable by this process are useful intermediates for the synthesis of dyes and are particularly suitable diazo components for the synthesis of azo dyes.

    专利号:US-4035350-A
    优先权日:1975-01-30
    标 题:Process for the preparation of water-soluble azo dyestuffs by reacting an aromatic amine and a coupling component with alkali metal nitrite or alkyl nitrite in the absence of acid
    发明人:LANDLER JOSEF; WORFEL ERHARD
    权利人:HOECHST AG
    摘要:A new and very advantageous Process had been found for the preparation of azo dyestuffs by diazotation and coupling in which the synthesis is carried out without the hitherto usual addition of an acid, with the proviso that at least one of the diazo and coupling components contains at least one acid group. Besides the saving of reaction material and subsequently of alkali for neutralization of the reaction medium and isolation of the dyestuff, highly concentrated solutions of the dyestuff and salt-free or practically salt-free dyestuffs can be obtained, and waste-water is no longer charged with big amounts of salts.

    专利号:US-5389524-A
    优先权日:1989-07-28
    标 题:Method and a system for quantitatively monitoring a chemical component dissolved in a liquid medium
    发明人:LARSEN BJORN E H; VINTHER ARNE; MOLLER POUL; THORSSON JORN R; SOEBERG HENRIK; SORENSEN JESPER L; LARSEN LYKKE B
    权利人:KOEGE KEMISK VAERK
    摘要:PCT No. PCT/DK90/00196 Sec. 371 Date Mar. 24, 1992 Sec. 102(e) Date Mar. 24, 1992 PCT Filed Jul. 30, 1990 PCT Pub. No. WO91/02254 PCT Pub. Date Feb. 21, 1991.A method and apparatus for quantitatively monitoring a chemical component dissolved in a liquid medium utilize the creation, in a measurement cell, of an interface zone between the liquid medium and an analytical reagent or reference solution. The concentration or amount of the chemical component are determined by the measurement of a value of a measurement parameter in the interface zone, and the derivation from that value of the concentration or amount of the component in comparison with a baseline or reference value measured for the reagent or reference solution alone. Matrix effects and ghosting errors are avoided. The method and apparatus can be used advantageously for on-line optimization and control of industrial, chemical and biological processes, such as chemical reactions in progress, coupling reactions for the synthesis of azo compounds, and the monitoring of in vivo or in vitro biological systems as well as for conventional analytical purposes.
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    主要参考文献

    [参考文献]: M J Pacheco, Et Al. Electrochemical Degradation Of Aromatic Amines On Bdd Electrodes. J Hazard Mater. 2011 Feb 28;186(2-3):1033-41.

    合成参考文献


    参考文献:10.1208/s12248-023-00855-w
    摘要:Saunders C, de Villiers CA, Stevens MM. Single Particle Chemical Characterisation of Nanoformulations for Cargo Delivery. AAPS J. 2023 Oct 02;25(6):94. doi: 10.1208/s12248-023-00855-w.
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