CAS: 219770-99-7; Dichloro(Phenylsulfanylmethylidene)Ruthenium,Tricyclohexylphosphane

📜Dichloromethylphenylsulphide,三环己基膦置于锌体系中,用 乙醇,甲苯 用作溶剂,化学反应 6.5H,以68%的收率获得双(三环己基磷)[(苯基硫)亚甲基]钌(II)二氯
参考文献:Process For Synthesis Of Organometallic Compounds
标题:Process For Synthesis Of Organometallic Compounds

专利信息

专利号:WO-2013082264-A1
优先权日:2011-12-02
标题:Synthesis of olefins
发明人：SCHOFER SUSAN; SAFIR ADAM; VAZQUEZ ROBERTO
权利人:AMYRIS INC
摘要:Described herein are methods for producing 1,3-butadiene and one or more of acrylic acid and esters of acrylic acid from muconic acid or a derivative thereof.

专利号:US-10384987-B2
优先权日:2014-12-16
标 题 :1,3-butadiene synthesis
发明人：DREISBACH CLAUS; SCHLENK STEFAN; HOFFMANN MARTINA; LARCHER CHRISTOPH; FOELLINGER THOMAS
权利人:ARLANXEO DEUTSCHLAND GMBH
摘要:The invention relates to a process for preparing 1,3-butadiene by means of ene-yne metathesis over at least one transition metal catalyst of the element ruthenium.

专利号:US-9328108-B2
优先权日:2011-10-28
标 题 :Process for preparing an intermediate of the macrocyclic protease inhibitor TMC 435
发明人：HORVATH ANDRAS; WUYTS STIJN; DEPRÉ DOMINIQUE PAUL MICHEL; COUCK WOUTER LOUIS J; CUYPERS JOZEF LUDO JAN; HARUTYUNYAN SYUZANNA; BINOT GREGORY FABIEN SEBASTIAN
权利人:JANSSEN PHARMACEUTICALS INC
摘要:The present invention relates to an improved process for preparing (2R,3aR,10Z,11aS,12aR,14aR)-cyclopenta[c]cyclopropa[g][1,6]diazacyclotetradecine-12a(1H)-carboxylic acid, 2,3,3a,4,5,6,7,8,9,11a,12,13,14,14a-tetradecahydro-2-[[7-methoxy-8-methyl-2-[4-(1-methylethyl)-2-thiazolyl]-4-quinolinyl]oxy]-5-methyl-4,14-dioxo-, ethyl ester. This compound is an intermediate in the overall synthesis route of the macrocyclic compound TMC 435. TMC 435 is an inhibitor of NS3/4A protease which plays an important role in the replication of the hepatitis C virus.

专利号:RU-2017125146-A
优先权日:2014-12-16
标 题 :SYNTHESIS OF 1,3-BUTADIENE

专利号:RU-2700413-C2
优先权日:2014-12-16
标题 :Synthesis of 1,3-butadiene

专利号:US-8993819-B2
优先权日:2011-07-12
标 题 :Process for preparing cycloheptene
发明人：TELES JOAQUIM HENRIQUE; LIMBACH MICHAEL; DEHN RICHARD; DEUERLEIN STEPHAN; DANZ MANUEL
权利人:TELES JOAQUIM HENRIQUE; LIMBACH MICHAEL; DEHN RICHARD; DEUERLEIN STEPHAN; DANZ MANUEL; BASF SE
摘要:The present invention provides a process for preparing cycloheptene and derivatives thereof by ring-closing metathesis of unsymmetric 1,8-dienes whose C—C double bond at the 8 position is nonterminal. Cycloheptene and the cycloheptanone, cycloheptylamine, cycloheptanecarbaldehyde, cycloheptanecarboxylic acid and cycloheptanecarbonyl chloride conversion products thereof, and the derivatives thereof, are important synthesis units for active ingredient compounds. The ring-closing metathesis is preferably performed as a reactive distillation. The unsymmetric 1,8-dienes for the ring-closing metathesis can be obtained by catalytic decarbonylation or oxidative decarboxylation from the corresponding unsaturated carboxylic acids or carboxylic acid derivatives.