CAS: 1607-57-4; 2-Bromo-1,1,2-Triphenylethylene

该化合物其结构特征为三苯乙烯框架所附的溴原子,该化合物具有高度芳香性,因为有三种苯基组,有助于其稳定性和独特的电子特性,通常在室温时是一种固体,在水中无法溶解,但在有机溶剂中可溶解;溴原子的存在引入了一个极地功能组,可影响其再活动,特别是在电益替代反应中.此外,1-溴-1,2,2-三苯乙烯可展示有趣的光物理特性,使其对材料科学和有机电子具有兴趣,其合成通常涉及三苯乙烯的溴化,并且可以作为各种化学变异的前体.

结构式图片

相似化合物

58-72-0 6304-33-2 25683-83-4

上下游产品

CAS号58-72-0 三苯乙烯 | CAS号107-06-2 1,2-二氯乙烷 | CAS号79-15-2 N-溴代乙酰胺 | CAS号2294-93-1 1,2,2-triphenyl... | CAS号74064-34-9 1,2-dibromo-1,1... | CAS号1520-42-9 1,1,2-三苯乙烷 | CAS号857788-03-5 1-bromo-1-nitro... | CAS号67-66-3 氯仿 | CAS号56-23-5 四氯化碳 | CAS号7726-95-6 溴素 | CAS号321-60-8 2-氟联苯 | CAS号1801-42-9 2.3-二苯基-1-二氢茚酮 | CAS号58-72-0 三苯乙烯 | CAS号844-20-2 PHENANTHRENE, 9... | CAS号63019-13-6 1,1,2-triphenyl... | CAS号62456-54-6 (1-methoxy-2,2-... | CAS号91083-70-4 Phenanthrene, 9... | CAS号62456-52-4 1,2,2-triphenyl... | CAS号119-61-9 二苯甲酮

合成工艺路线路线简述

  • 合成目标产物 Bromotriphenylethylene 主要起始原料 Triphenylethylene
  • (文献来源)合成步骤主要原料 Triphenylethylene
📜三苯乙烯置于溴体系中,用 氯仿 用作溶剂,以72%的收率获得三苯溴乙烯
参考文献:具有聚集诱导发光特性的 1-(1,2,2-三苯基乙烯基)-1H-吲哚的设计,合成,晶体结构和 Dft 分析
标题:具有聚集诱导发光特性的 1-(1,2,2-三苯基乙烯基)-1H-吲哚的设计,合成,晶体结构和 Dft 分析
摘要:各种 1-(1,2,2-三苯基乙烯基)-1H-吲哚是由简单易得的起始材料设计和合成的.通过不同的光谱方法对该化合物进行了表征,并通过单晶x射线衍射证实了其固态结构.该化合物在具有空间群的单斜晶系中结晶.光物理性能测试表明1-(1,2,2-三苯基乙烯基)-1H-吲哚具有明显的聚集诱导发光现象.还研究了这些化合物的电子结构和发光性质之间的关系.
Doi:10.1016/j.Molstruc.2022.134022

海关参考信息

专利信息


专利号:US-6545098-B1
优先权日:1997-12-31
标 题:Synthesis method for block polymers by controlled radical polymerization from dithioester compounds
发明人:BOUHADIR GHENWA; CHARMOT DOMINIQUE; CORPART PASCALE; ZARD SAMIR
权利人:RHODIA CHIMIE SA
摘要:The invention concerns a method for preparing, by radical polymerisation, block polymers of general formula (1), which consists in contacting: an ethylenically unsaturated monomer of formula CYY'(=CW-CW')a=CH2: and a precursor compound of general formula (II): a radical polymerization initiator.

专利号:US-7122694-B2
优先权日:1998-11-06
标 题 :Hydroboronation process
发明人:MARCUCCIO SEBASTIAN MARIO; RODOPOULOS MARY; WEIGOLD HELMUT
权利人:BORON MOLECULAR PTY LTD
摘要:The invention relates to processes for the synthesis of aryl or alkene borates which comprises reacting: (i) an olefinic compound having a halogen or halogen-like substituent in a vinylic substitution position, or (ii) an aromatic ring having a halogen or halogen-like substituent in a ring substitution position, with a disubstituted monohydroborane in the presence of a Group 8-11 metal catalyst. The invention also relates to the use of these borates in coupling reactions. The invention further relates to certain disubstituted monohydroboranes and aryl or alkene borates.

专利号:CN-107253968-B
优先权日:2011-08-29
标题:Universal and Stereoselective Synthesis of γ,δ-Unsaturated Amino Acids via Wittig Reaction

专利号:CN-104558570-A
优先权日:2015-01-22
标 题 :Synthesis of a Phosphorus-Containing Polyester Polyol and Its Application in Polyurethane

专利号:CN-111072439-A
优先权日:2019-11-25
标 题:A kind of luminescent material and its synthesis method and application

专利号:CN-111303181-A
优先权日:2020-03-03
标 题:Synthesis and application of solid fluorescent material of oxaspiro-bridged TPE (thermoplastic elastomer)

供应商参考报价(招募中)

品牌试剂参考报价(招募中)

📌 第三方产品分析报告

✅ COA系统入驻 | 共享模式

合成参考文献


摘要:Yoshikai, N.; Rayner, C. M.; Graham, M. A., Science of Synthesis Knowledge Updates, (2020) 2, 92.
摘要:Franck, X.; Durandetti, M., Science of Synthesis: Knowledge Updates, (2024) 3, 336.
摘要:Kwiatkowska, M.; Kiełbasiński, P., Science of Synthesis: Knowledge Updates, (2024) 3, 413.
摘要:Couve-Bonnaire, S.; Castanheiro, T.; Bouillon, J.-P., Science of Synthesis: Modern Strategies in Organofluorine Chemistry, (2025) 2.
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