CAS: 14128-84-8; Copper,(Z)-3-Oxo-1-Phenylbut-1-En-1-Olate

该化合物是一个协调化合物,由2个1-苯-1,3-丁基分泌核素混合而形成铜色(II)的铜色;这一复合体由于在铜中心周围形成方平方平面几何学的β-单方字形组的招标协调而表现出很强的稳定;它通常用作化学蒸气沉降(CVD)和原子层沉积(ALD)过程的前体,用于生产高纯度铜薄膜,因为它的有利挥发性和热分解特性;苯基替代体提高了有机溶剂的溶性,便于其在基于溶液的应用中使用;其明确界定的结构和连续反应性使其适合于先进的材料合成和催化研究.

英文名称Copper,(Z)-3-Oxo-1-Phenylbut-1-En-1-Olate
中文名称苯甲酰丙酮铜
IUPAC名称copper bis((Z)-3-oxo-1-phenylbut-1-en-1-olate)
其它别名Copper,bis(1-phenyl-1,3-butanedionato)- (6CI,7CI,8CI); Copper,bis(1-phenyl-1,3-butanedionato-O,O')-; Copper, bis(1-phenyl-1,3-butanedionato-kO,kO')- (9CI); Bis(1-phenyl-1,3-butanedionato)copper; Bis(benzoylacetonato)copper; Bis(benzoylacetonato)copper(II); Copperbis(benzoylacetonate); Copper(II) benzoylacetonate
CAS编号14128-84-8
MFCD编号:MFCD00041717
分子式:C20H18CuO4分子量:385.907
产品CID: 631170
产品分类有机原料 → 有机金属类化合物 → 有机铜

相似结构搜索
InChIKey: MODLMZHNDHXAHS-UHFFFAOYSA-N
1S/2C10H10O2.Cu/c2*1-8(11)7-10(12)9-5-3-2-4-6-9;/h2*2-7,12H,1H3;/q;;+2/p-2/b2*10-7-;
计算化学: 氢键受体数6.0氢键供体数0.0可旋转键数2.0

MSDS等安全信息

警示词Warning
危险描述H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]
H319 (100%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]
H335 (100%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]
防范说明P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501
UN编号NONH for all modes of transport
安全声明S24/25
危险类别码R36/37/38

上下游产品

copper diacetate 1-phenylbutan-1,3-dione copper(II) sulfate

合成工艺路线路线简述

📜Copper(II) Sulfate,1-苯基-1,3-丁二酮置于三乙胺,溶剂黄146体系中,用甲醇,水用作溶剂,化学反应 0.75H,反应生成苯甲酰丙酮铜
参考文献:Synthesis And Structural Studies Of 1-Phenyl-1,3-Butanedione Copper(II) Complexes As An Excellent Antimicrobial Agent Against Methicillin-Resistant Staphylococcus Aureus
标题:Synthesis And Structural Studies Of 1-Phenyl-1,3-Butanedione Copper(II) Complexes As An Excellent Antimicrobial Agent Against Methicillin-Resistant Staphylococcus Aureus
摘要:The Copper Based Metal Complexes (Cmc) Were Synthesized Using 1-Phenyl-1,3-Butanedione With Two Different Solvents,Methanol And Water:Acetic Acid. The X-Ray Structural Analysis Of The Two Cmcs Indicates That,Coordination Environment Around The Complex 1 [cu(C10H10O2)(2)(Ch4O)] Exhibits Distorted Square-Pyramidal Geometry With Trans-Isomer Favored Structure Whereas Complex 2 [cu(C10H10O2)(2)] Exhibits Distorted Squareplanar Geometry With Cis-Isomer Favored Structure. Both Copper Complexes Were Characterized By Sem,Edx,Mass And Tga. Further,The Cmcs Were Showed Promising Antibacterial Activity By Disc Diffusion And Minimum Inhibitory Concentration Assay Against Gram Positive And Gram Negative Bacteria. The Studied Model Showed Cmc Were Potent Against Methicillin-Resistant Staphylococcus Aureus (Mrsa) Validated By Inhibition Of Electron Transport Chain. The Formation Of Membrane Pore/damage By Cmc Leads To Changes In The Bioelectrochemistry Of The Mrsa Was Assessed And Mechanism Involved In Membrane Damage Was Confirmed By Sem. The Study Concludes That The Complex 1 Showed Potent Antibacterial Action Compared To Standard Drug Ampicillin.
Doi:10.1016/j.Ica.2018.09.049