CAS: 93457-69-3; N-Butyl-N-Methylpyrrolidinium Bromide

该化合物是一种属于以火合二氮为基础的盐族的离子液体,具有丁基和甲基替代成分,配有溴阴离子.这种化合物在极地溶剂中具有高度的热稳定性,低挥发性,高溶性,适合电化学,催化和反应介质的应用.它的离子性质允许金枪鱼的物理化学特性,如粘合性和导电性,取决于加工条件.溴反作用进一步提高了其在卤化交换反应中的效用,并成为其他硅液的前体.在广泛温度范围内,这种化合物的稳定性成为专门合成和工业工艺的可靠选择.

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479500-35-1 330671-29-9 69227-51-6

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上下游产品

1-Methylpyrrolidine 1-bromo-butane butanone n-Butyl chloride 1-butyl-methylpyrrolidinium bis(trifluoromethylsulfonyl)amide 1-butyl-1-methylpyrrolidinium trifluoromethanesulfonate N-butyl-N-methylpyrrolidinium (fluorosulfonyl)(trifluoromethanesulfonyl)imide

合成工艺路线路线简述

  • 120-94-5 = 93457-69-3
    反应条件:1.1 Solvents: Acetonitrile; 5 - 10 Bar,40 - 45 °C
    标题:Synthesis,Characterization And Radiolytic Properties Of Bis(Oxalato)Borate Containing Ionic Liquids
    作者:Lall-Ramnarine,Sharon I.; Castano,Alejandra; Subramaniam,Gopal; Thomas,Marie F.; Wishart,James F.
    参考文献:Radiation Physics And Chemistry 日期:2009 卷标:78(12) 页码:1120-1125]

    120-94-5 = 93457-69-3
    反应条件:1.1 Solvents: Acetonitrile; 0 °C; 0 °C -> Rt; Overnight,Reflux
    标题:Physical-Chemical Characterization Of Binary Mixtures Of 1-Butyl-1-Methylpyrrolidinium Bis{(Trifluoromethyl)Sulfonyl}Imide And Aliphatic Nitrile Solvents As Potential Electrolytes For Electrochemical Energy Storage Applications
    作者:Neale,Alex R.; Schutter,Christoph; Wilde,Patrick; Goodrich,Peter; Hardacre,Christopher; Et Al
    参考文献:Journal Of Chemical & Engineering Data 日期:2017 卷标:62(1) 页码:376-390]

    120-94-5 = 93457-69-3
    反应条件:1.1 Solvents: Acetonitrile; 6 Min,45 °C; 2 Min,45 °C
    标题:Electron Solvation Dynamics And Reactivity In Ionic Liquids Observed By Picosecond Radiolysis Techniques
    作者:Wishart,James F.; Funston,Alison M.; Szreder,Tomasz; Cook,Andrew R.; Gohdo,Masao
    参考文献:Faraday Discussions 日期:2012 卷标:154 页码:353-363]

    120-94-5 = 93457-69-3
    反应条件:1.1 Solvents: Acetonitrile; Rt; 12 H,Rt; 3 H,70 °C; 70 °C -> Rt
    标题:A Recyclable Triethylammonium Ion-Tagged Diphenylphosphine Palladium Complex For The Suzuki-Miyaura Reaction In Ionic Liquids
    作者:Lombardo,Marco; Chiarucci,Michel; Trombini,Claudio
    参考文献:Green Chemistry 日期:2009 卷标:11(4) 页码:574-579]

    120-94-5 = 93457-69-3
    反应条件:1.1 2 D,Rt
    标题:Rationalising The Effects Of Ionic Liquids On A Nucleophilic Aromatic Substitution Reaction
    作者:Hawker,Rebecca R.; Wong,Michaela J.; Haines,Ronald S.; Harper,Jason B.
    参考文献:Organic & Biomolecular Chemistry 日期:2017 卷标:15(30) 页码:6433-6440]

    120-94-5 = 93457-69-3
    反应条件:1.1 Solvents: Acetonitrile; 0 °C; 0 °C -> Rt; Overnight,Reflux
    标题:Enhancement Of Whole Cell Dioxygenase Biotransformations Of Haloarenes By Toxic Ionic Liquids
    作者:Allen,C. C. R.; Boudet,C. J.; Hardacre,C.; Migaud,M. E.
    参考文献:Rsc Advances 日期:2014 卷标:4(38) 页码:19916-19924]

    120-94-5 = 93457-69-3
    反应条件:1.1 Solvents: Acetonitrile; 16 H,Rt -> 60 °C
    标题:Femtosecond Raman-Induced Kerr Effect Study Of Temperature-Dependent Intermolecular Dynamics In Pyrrolidinium-Based Ionic Liquids: Effects Of Anion Species
    作者:Kakinuma,Shohei; Shirota,Hideaki
    参考文献:Journal Of Physical Chemistry B 日期:2019 卷标:123(6) 页码:1307-1323]

    120-94-5 = 93457-69-3
    反应条件:1.1 48 H,Rt
    标题:Spirocyclic Quaternary Ammonium Cations For Alkaline Anion Exchange Membrane Applications: An Experimental And Theoretical Study
    作者:Gu,Liang; Dong,Huilong; Sun,Zhe; Li,Youyong; Yan,Feng
    参考文献:Rsc Advances 日期:2016 卷标:6(97) 页码:94387-94398]

    120-94-5 = 93457-69-3
    反应条件:1.1 48 H,Rt
    标题:Understanding The Effects Of Ionic Liquids On A Unimolecular Substitution Process: Correlating Solvent Parameters With Reaction Outcome
    作者:Gilbert,Alyssa; Haines,Ronald S.; Harper,Jason B.
    参考文献:Organic & Biomolecular Chemistry 日期:2019 卷标:17(3) 页码:675-682]

    120-94-5 = 93457-69-3
    反应条件:1.1 Solvents: Pyrrolidinium,1-Butyl-1-Methyl-,Salt With Imidodisulfuryl Fluoride (1:1); Rt -> 75 °C; 5 Min,75 °C; 158 Min,75 °C -> 85 °C
    标题:Process For Producing Ionic Liquids
    参考文献:World Intellectual Property Organization]

    120-94-5 = 93457-69-3
    反应条件:1.1 Solvents: Acetonitrile; 273 K; 4 H,273 K; Overnight,273 K
    标题:Thermochemical Properties Of Some Bis(Trifluoromethyl-Sulfonyl)Imide Based Room Temperature Ionic Liquids
    作者:Jagadeeswara Rao,Ch.; Venkata Krishnan,R.; Venkatesan,K. A.; Nagarajan,K.; Srinivasan,T. G.
    参考文献:Journal Of Thermal Analysis And Calorimetry 日期:2009 卷标:97(3) 页码:937-943]

    120-94-5 + 71-36-3 = 93457-69-3
    反应条件:1.1 Reagents: Potassium Bromide Solvents: Acetonitrile,Water; 2 H,50 °C
    标题:Preparation Method Of N,N-Dialkylpyrrolidine Bromide Ionic Liquid By Electrolysis And Application Thereof As Solvent To Prepare Tripyridylmethylamine Compound
    参考文献:China]

    120-94-5 = 93457-69-3
    反应条件:1.1 Solvents: Acetonitrile; 70 °C; 10 Min,70 °C; 22 H,70 °C
    标题:Synthesis Of N,N-Butyl-D9-Methylpyrrolidinium Bis(Trifluoro-Methanesulfonyl)Imide
    作者:Weisshaart,Duane E.; Altena,Nicole J.; Anderson,Rachel S.; Mcmanus,Riley P.; Letcher,Austin R.; Et Al
    参考文献:Journal Of Undergraduate Chemistry Research 日期:2013 卷标:12(3) 页码:75-78]

    120-94-5 = 93457-69-3
    反应条件:1.1 < 40 °C; 1 D
    标题:Process For Preparation And Purification Of Ionic Liquids And Precursors
    参考文献:United States]

    120-94-5 = 93457-69-3
    反应条件:1.1 < 40 °C; 1 D,< 40 °C
    标题:The Large Scale Synthesis Of Pure Imidazolium And Pyrrolidinium Ionic Liquids
    作者:Burrell,Anthony K.; Del Sesto,Rico E.; Baker,Sheila N.; Mccleskey,T. Mark; Baker,Gary A.
    参考文献:Green Chemistry 日期:2007 卷标:9(5) 页码:449-454]

    120-94-5 = 93457-69-3
    反应条件:1.1 Solvents: Ethyl Acetate; 30 Min,Cooled; Overnight,Rt; 24 H,60 °C
    标题:Cation Structure-Dependence Of The Induced Free Charge Density Gradient In Imidazolium And Pyrrolidinium Ionic Liquids
    作者:Wang,Yufeng; Adhikari,Laxmi; Baker,Gary A.; Blanchard,G. J.
    参考文献:Physical Chemistry Chemical Physics 日期:2022 卷标:24(32) 页码:19314-19320]

    120-94-5 = 93457-69-3
    反应条件:1.1 Solvents: Acetone; Rt; 24 H,Reflux
    标题:Cyclic Quaternary Ammonium Ionic Liquids With Perfluoroalkyltrifluoroborates: Synthesis,Characterization,And Properties
    作者:Zhou,Zhi-Bin; Matsumoto,Hajime; Tatsumi,Kuniaki
    参考文献:Chemistry - A European Journal 日期:2006 卷标:12(8) 页码:2196-2212]

    120-94-5 = 93457-69-3
    反应条件:1.1 48 H,Rt
    标题:Base Stable Pyrrolidinium Cations For Alkaline Anion Exchange Membrane Applications
    作者:Gu,Fenglou; Dong,Huilong; Li,Youyong; Sun,Zhe; Yan,Feng
    参考文献:Macromolecules (Washington 日期:2014 卷标:47(19) 页码:6740-6747]

    120-94-5 = 93457-69-3
    反应条件:1.1 22 H,Rt1.2 Solvents: Acetonitrile; 24 H,Rt
    标题:Controlling The Reactions Of 1-Bromogalactose Acetate In Methanol Using Ionic Liquids As Co-Solvents
    作者:Gilbert,Alyssa; Haines,Ronald S.; Harper,Jason B.
    参考文献:Organic & Biomolecular Chemistry 日期:2020 卷标:18(28) 页码:5442-5452
📜1-甲基吡咯烷,正溴丁烷 以 甲基叔丁基醚 作为反应溶剂,化学反应 24.0H,以71%的收率获得产物1-丁基-1-甲基吡溴化咯烷鎓
参考文献:阴离子催化基团转移聚合合成传统和离子型聚甲基丙烯酸甲酯
标题:阴离子催化基团转移聚合合成传统和离子型聚甲基丙烯酸甲酯
摘要:疏水离子液体1-丁基-1-甲基吡咯烷鎓双(三氟甲基磺酰基)亚胺已成功用作传统甲基丙烯酸酯(甲基丙烯酸甲酯,甲基丙烯酸正丁酯和甲基丙烯酸苄酯)和离子液体甲基丙烯酸酯(ilmas)的基团转移聚合的溶剂.这表明该离子液体可形成反应条件,而无需使用超干溶剂.ilma是n-[2-(甲基丙烯酰氧基)乙基] N,N-二甲基-N-烷基铵双带有甲基,乙基,丙基,丁基或己基取代基的(三氟甲基磺酰基)酰亚胺.在离子液体甲基丙烯酸酯和由它们衍生的聚合物的情况下,阳离子上烷基取代基尺寸的增加导致玻璃化转变温度的降低.此外,与离子液体甲基丙烯酸酯相比,这些聚合物的玻璃化转变温度明显更高,并且随着烷基取代基尺寸的增加,玻璃化转变温度降低的效果对于聚合物而言更强.提出了解释用于聚合的溶剂的离子液体的催化功能的机理.©2015 Wiley Periodicals,Inc. J. Polym.科学,A部分:Polym.化学
DOI:10.1002/pola.27760

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专利信息


专利号:FR-2941700-A1
优先权日:2009-02-02
标 题 :PROCESS FOR THE SYNTHESIS OF A BLOCK COPOLYMER ALLOY HAVING IMPROVED ANTISTATIC PROPERTIES

专利号:US-2011217553-A1
优先权日:2007-12-20
标 题 :Frozen Ionic Liquid Microparticles and Nanoparticles, and Methods for their Synthesis and Use
发明人：WARNER ISIAH M; TESFAI AARON; EL-ZAHAB BILAL M; BWAMBOK DAVID; BAKER GARY A; FAKAYODE SAYO O; LOWA MARK; TOLOCKA MICHAEL P; DE ROOY SERGIO
权利人:WARNER ISIAH M; TESFAI AARON; EL-ZAHAB BILAL M; BWAMBOK DAVID; BAKER GARY A; FAKAYODE SAYO O; LOWA MARK; TOLOCKA MICHAEL P; DE ROOY SERGIO
摘要:“Frozen ionic liquidâ€? microparticles and nanoparticles are disclosed, as are alternative methods of making the particles. The particles may be monodisperse or polydisperse, with spherical or other shapes. The particles may be prepared without specialized equipment, and without harsh conditions. The microparticles and nanoparticles have uses in biomedical, materials, analytical, and other fields.

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合成参考文献


参考文献:10.1007/s11696-025-03972-2
摘要:Saraswat J, Patel R. Augmenting nisin antibacterial activity: in-vitro analysis with 1-alkyl-1-methylpyrrolidin-1-ium bromide. Chem. Pap. 2025 Mar 12;79(5):2861–72. doi: 10.1007/s11696-025-03972-2.
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