Butyloxy-Diethyl-Phosphin 在 硫酸体系中,用 1,4-二氧六环作为反应溶剂,获得 Diethylphosphine Oxide 参考文献:Lower Dialkylphosphinous Acids (Secondary Phosphine Oxides) And Some Of Their Properties 标题:Lower Dialkylphosphinous Acids (Secondary Phosphine Oxides) And Some Of Their Properties 摘要: Doi:10.1007/Bf00849668
专利号:EP-3560936-A1 优先权日:2018-04-24 标题:Method for the synthesis of alkenyl-phosphorous compounds 发明人:SCHÄFER SASCHA WILHELM; ZHAO LIGANG; STUDER AMIDO 权利人:HENKEL AG & CO KGAA 摘要:The invention pertains to a method for the synthesis of specific alkenyl-phosphorous compounds according to formula (I)whereinR1and R2are independently selected from hydrogen or a substituted or unsubstituted C1-40hydrocarbon group, whereby the group optionally contains at least one heteroatom, preferably O, N or S;X is independently O or S;R3and R4are independently selected from a substituted or unsubstituted C1-40hydrocarbon group, whereby the group optionally contains at least one heteroatom, preferably O, N or S;m is independently 0 or 1; andn is an integer from 1 to 4. Furthermore, the invention relates to compounds obtained by this method, and compositions comprising the compounds of the present invention, wherein the compositions are compositions for lighting applications, optical applications, microelectronic compounds, optical brighteners or are detergent compositions. Finally, the invention relates to the use of the compounds of the present invention in lighting lighting applications, optical applications microelectronic compounds, optical brighteners or detergent compositions.
专利号:US-4581416-A 优先权日:1981-01-19 标题 :Process for the synthesis of tertiary phosphine oxides and sulfides, and new tertiary phosphine oxides and sulfides 发明人:BERGERET WILFRID; BOILEAU SYLVIE; GAUTIER JEAN-CLAUDE; RAYNAL SERGE 权利人:POUDRES & EXPLOSIFS STE NALE 摘要:The invention relates to processes for the synthesis of tertiary phosphine oxides and sulfides. The process according to the invention consists, in a first step, of reacting a secondary phosphine oxide or sulfide with an optionally activated alkali metal amide, and, in a second step, of reacting the mixture obtained in the first step with an organic halide containing at least one halogenophenyl radical or one halogenomethyl group. Tertiary phosphine oxides and sulfides are complexing agents of high stability.
专利号:EP-2030975-A1 优先权日:2007-08-06 标 题:CEFDINIR synthesis process 发明人:MANCA ANTONIO; FILIPPI MAURO; SALA BRUNO MAURIZIO; MONGUZZI RICCARDO AMBROGIO; FOGLIATO GIOVANNI 权利人:ACS DOBFAR SPA 摘要:Cefdinir preparation by synthesis of new key intermediates, isolable as variously solvated species complexed with thiophosphoric acid derivatives or with phosphoric acid derivatives.
专利号:US-6376662-B1 优先权日:1997-01-17 标题:Method for synthesizing C-glycosides of ulosonic acids 发明人:LINHARDT ROBERT J; VLAHOV IONTCHO R 权利人:UNIV IOWA RES FOUND 摘要:A method for synthesizing C-glycosides of ulosonic acids such as Neu5Ac, by which diastereocontrolled synthesis of α-C-glycosides of ulosonic acids is attained is disclosed. In the method of the present invention, an ulosonic acid sulfone or phosphite is reacted with an aldehyde or ketone compound in the presence of a lanthanide metal halide.
专利号:US-5191075-A 优先权日:1988-10-19 标 题:Process for the preparation of penems 发明人:O'NEILL BRIAN T; PHILLIPS DOUGLAS 权利人:PFIZER 摘要:An efficient, multistep process for the synthesis of certain 6-(1-hydroxyethyl) 2-substituted penem antibiotics from 2-[4R-(triphenylmethylthio)-3S-(1R-(dimethyl-t-butylsilyloxy)ethyl)-2-azetidon-1-yl]acetic acid esters.
专利号:US-5286857-A 优先权日:1988-10-19 标 题:Intermediate for the preparation of penems 发明人:O'NEILL BRIAN T; PHILLIPS DOUGLAS 权利人:PFIZER 摘要:An efficient, multistep process for the synthesis of certain 6-(1-hydroxyethyl) 2-substituted penem antibiotics from 2-[4R-(triphenylmethylthio)-3S-(1R-(dimethyl-t-butylsilyloxy)ethyl)-2-azetidon-1-yl]acetic acid esters.