CAS: 13588-16-4; (2R,3R,Z)-5-Ethylidene-2-Hydroxy-2,3-Dimethylhexanedioic Acid

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上下游产品

Cis-Seneciphyllinsaeure Vom F: 112-114Grad 18003-17-3
Senecic Acid Lactone 28822-16-4
2(Z)-Ethylidene-5-(Methoxycarbonyl)-4,5-Dimethyl-5-Pentanolide 6582-61-2

合成工艺路线路线简述

    📜Alkaline Earth Salt Of/the/ Methylsulfuric Acid置于barium Dihydroxide,水体系中,化学反应生成千里光次酸
    参考文献:Richardson; Warren,Journal Of The Chemical Society,1943,P. 454
    标题:Richardson; Warren,Journal Of The Chemical Society,1943,P. 454

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    主要参考文献

    参考标题:Pyrrolizidine Alkaloids. The Biosynthesis Of Senecic Acid
    作者:D. H. G. Crout,N. M. Davies,E. H. Smith,D. Whitehouse
    摘要:Two Five-Carbon Units Derived From Isoleucine Are Specifically Incorporated Into Senecic Acid (Iv) In Senecio Magnificus. The Specific Incorporation Of The Methyl Carbon Atom Of Methionine Into C-3 Of Serine In Pea Seedlings Has Been Demonstrated. The Significance Of This Result In Relation To Necic Acid Biosynthesis Is Discussed.

    合成参考文献


    参考文献:10.1111/tpj.16211
    摘要:Chen H, Li X, Chapple C, Dilkes B, Li X. UGT76F1 glycosylates an isomer of the C7‐necic acid component of pyrrolizidine alkaloids in Arabidopsis thaliana. The Plant Journal. 2023 Apr 12;115(1):97–107. doi: 10.1111/tpj.16211.
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