📜3-(2',6',6'-Trimethylcyclohex-2'-En-1'-yl)Prop-2-Enal置于吡啶,Manganese(Iv) Oxide,氢氧化钾,Lipase Ps,Magnesium体系中,用 甲醇,乙醚,二氯甲烷 用作溶剂,化学反应 29.0H,反应生成Alpha-甲基紫罗兰酮 参考文献:The Enantiomers Of Iralia®: Preparation And Odour Evaluation 标题:The Enantiomers Of Iralia®: Preparation And Odour Evaluation 摘要:The Enantiomers Of Methyl Ionones 1 And 2 Were Prepared By An Enzyme-Catalysed Approach. Their Odour Properties Were Evaluated By Skilful Perfumers. (C) 2007 Elsevier Ltd. All Rights Reserved. Doi:10.1016/j.Tetasy.2007.04.022
专利号:US-2024240209-A1 优先权日:2021-04-20 标 题:Synthesis of enantiopure cis-a-irone from a renewable carbon source 发明人:CHEN XIXIAN; ZHANG CONGQIANG; T REHKA; SHUKAL SUDHA; SMITH DEREK; ANDRÉ ISABELLE; JEREMY ESQUE 权利人:AGENCY SCIENCE TECH & RES; INSTITUT NATIONAL DE RECH POUR L AGRICULTURE LALIMENTATION ET LENVIRONMENT; CENTRE NAT RECH SCIENT; INSTITUT NAT DES SCIENCES APPLIQUEES DE TOULOUSE 摘要:Synthesis of enantiopure cis-α-irone from a renewable carbon source Disclosed herein are natural and synthetic enzymes capable of performing a method of producing cis-α-irone. The method comprises providing an enzyme capable of converting psi-ionone to cis-α-irone; and contacting the enzyme and psi-ionone under suitable conditions to produce cis-α-irone. The enzyme may be a methyltransferase from Streptomyces albireticuli (SaMT), a promiscuous bifunctional methyltransferase/cyclase (pMT1) enzyme from Streptomyces, or a modified pMT1 enzyme with at least one substitution. The enzymes allow the in-vivo and in-vitro production of cis-α-irone including the use of glucose as feedstock for the biotransformation into cis-α-irone.
专利号:CN-108997096-A 优先权日:2018-07-27 标 题:A method for the synthesis of citral by highly selective oxidation of geraniol
专利号:WO-8911536-A1 优先权日:1988-05-27 标题:Microbial biocatalyst for production of terpenic aldehydes 发明人:DAVIS KAREN JOHANNA; BEST DAVID JOHN; BURFIELD ANTHONY GRAHAM; TAYLOR FRANK; TALBOT JANE STELLA 权利人:NOVALAL LTD 摘要:An active biocatalyst for converting alpha-pinene epoxide to terpenic aldehydes useful in perfumery, e.g. formula (I), is produced by growing a microorganism, preferably Pseudomonas fluorescens NCIB 40043, to late log phase in a medium containing carbohydrate (e.g. glucose) as the carbon source, and adding alpha-pinene. The resulting culture comprises active biocatalyst which is brought into contact with alpha-pinene epoxide for aldehyde synthesis.
专利号:US-4271046-A 优先权日:1978-10-12 标 题:Novel norcamphanyl-substituted pyrans, method for their synthesis and use thereof in perfumery 发明人:WILLIS BRIAN J; DITTRICK JOHN W 权利人:FRITZSCHE DODGE & OLCOTT INC 摘要:Norcamphanyl-substituted pyrans, their preparation and their use as olfactory components of perfume formulations are disclosed.
专利号:US-3647479-A 优先权日:1969-10-28 标 题 :Method of flavoring food by addition of benzoxepin-3-ones and benzodioxepin-3-ones 发明人:BEEREBOOM JOHN J; CAMERON DONALD P; STEPHENS CHARLES R 权利人:PLIZER INC 摘要:Benzoxepin-3-ones and Benzodioxepin-3-ones, prepared by a novel synthesis, are useful as flavor and odorant agents for foods and perfumes respectively to impart a watermelonlike taste and odor.
专利号:US-4197246-A 优先权日:1978-10-12 标 题 :Novel norcamphanyl-substituted pyrans, method for their synthesis and use thereof in perfumery 发明人:DITTRICK JOHN W; WILLIS BRIAN J 权利人:FRITZSCHE DODGE & OLCOTT INC 摘要:Norcamphanyl-substituted pyrans, their preparation and their use as olfactory components of perfume formulations are disclosed.
参考标题:Synthesis, Olfactory Evaluation And Determination Of The Absolute Configuration Of The β- And γ-Iralia® Isomers 作者:Assem Barakat,Elisabetta Brenna,Claudio Fuganti,Stefano Serra |发布日期:2008.10 摘要:Synthesis Of The Methyl-Ionone Isomers 6-9 Is Described. The Enantiomers Of The γ-Isomers 8 And 9 Are Prepared By Enzyme-Mediated Resolution Of The Corresponding 4-Hydroxy Derivatives Followed By Reductive Elimination Of The Hydroxy Group. The Absolute Configuration Of The Latter Compound Is Determined By Chemical Correlation With The Known α-Isomers. Since All The Isomers Obtained Are Components Of The
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摘要:S109 | PARCEDC | List of 7074 potential endocrine disrupting compounds (EDCs) by PARC T4.2 | DOI:10.5281/zenodo.10944198