CAS: 955-83-9; 2,5-Diphenylfuran

该化合物是一种有机化合物,其特点是以2和5个位置与苯基组相替代的呋喃环被替换,该化合物一般是黄色的白晶状固体,其分子式为C18H14O, 表明由于存在呋喃和苯基组,该化合物具有较高的芳香度;该化合物在乙醇和丙酮等有机溶剂中具有中等溶解性,同时在水中较不易溶解;2,5-二苯呋喃表现出有趣的化学特性,包括能够进行各种典型的呋喃和芳香化合物反应,例如电药用替代;经常研究其在有机合成和材料科学中的潜在应用,特别是在有机半导体的开发中,以及作为合成更复杂的分子的建筑块,安全数据表明,与许多有机化合物一样,该化合物应谨慎处理,因为如果浸入或吸入,可能会对健康造成危害.

结构式图片

相似化合物

17113-33-6 5471-63-6 60456-77-1

物理性质

MSDS等安全信息

上下游产品

4-bromo-3-nitro-1,4-diphenyl-butan-1-one 1,4-diphenylbut-2-ene-1,4-dione phenacylacetophenone 5-ethoxy-2,5-dihydrofuran-2-one 3-bromomethyl-2,5-diphenyl-furan 3,4-bis(bromomethyl)-2,5-diphenylfuran diphenyl-2,5 bis chloromethyl-3,4 furanne (Z)-1,4-diphenylbut-2-ene-1,4-dione

合成工艺路线路线简述

  • 合成目标产物 2,5-Diphenylfuran 主要起始原料 1-Phenyl-1,4-Pentanedione
  • 495-71-6 = 955-83-9
    反应条件:1.1 Catalysts: 1-Butyl-3-Methylimidazolium Hydrogen Sulfate Solvents: 1-Butyl-3-Methylimidazolium Hydrogen Sulfate; 2 H,150 °C
    标题:A Green Route To The Synthesis Of Furan Derivatives
    参考文献:China]

    495-71-6 = 955-83-9
    反应条件:1.1 Solvents: Toluene; 10 Min,140 °C
    标题:Preparation Of 2,5-Disubstituted Furans By Microwave-Assisted Cyclization From 1,4-Diketones
    参考文献:Japan]

    23637-56-1 = 955-83-9
    反应条件:1.1 Catalysts: Cobalt Tetraphenylporphine Solvents: Chloroform
    标题:Quantitative Rearrangement Of Monocyclic Endoperoxides To Furans Catalyzed By Cobalt(Ii)
    作者:O'Shea,Kevin E.; Foote,Christopher S.
    参考文献:Journal Of Organic Chemistry 日期:1989 卷标:54(14) 页码:3475-7]

    104737-98-6 = 955-83-9
    反应条件:1.1 Reagents: Cupric Chloride Catalysts: P-Toluenesulfonic Acid Solvents: Water; 20 Min,150 °C
    标题:Sequential Synthesis Of Furans From Alkynes: Successive Ruthenium(Ii)- And Copper(Ii)-Catalyzed Processes
    作者:Zhang,Min; Jiang,Huan-Feng; Neumann,Helfried; Beller,Matthias; Dixneuf,Pierre H.
    参考文献:Angewandte Chemie 日期:2009 卷标:48(9) 页码:1681-1684]

    495-71-6 = 955-83-9
    反应条件:1.1 Reagents: Trifluoromethanesulfonic Acid Solvents: Acetonitrile; Overnight,Rt -> 85 °C1.2 Reagents: Sodium Bicarbonate Solvents: Water
    标题:Diverse Synthesis Of C2-Linked Functionalized Molecules Via Molecular Glue Strategy With Acetylene
    作者:Yang,Bo; Lu,Shaodong; Wang,Yongdong; Zhu,Shifa
    参考文献:Nature Communications 日期:2022 卷标:13(1)]

    495-71-6 = 955-83-9
    反应条件:1.1 Catalysts: Trifluoromethanesulfonic Acid Solvents: Acetonitrile; 1 H,85 °C
    标题:The Rearrangement Of Tert-Butylperoxides For The Construction Of Polysubstituted Furans
    作者:Zheng,Xiaojian; Lu,Shenglin; Li,Zhiping
    参考文献:Organic Letters 日期:2013 卷标:15(21) 页码:5432-5435]

    1191988-22-3 = 955-83-9
    反应条件:1.1 Catalysts: Chloro(Triphenylphosphine)Gold,[1,1,1-Trifluoro-N-[(Trifluoromethyl)Sulfonyl-Ko]Methanesulfonamidato-Ko]Silver Solvents: Toluene; 10 H,Rt1.2 Reagents: Ammonium Chloride Solvents: Water
    标题:Cationic Gold(I)-Mediated Intramolecular Cyclization Of 3-Alkyne-1,2-Diols And 1-Amino-3-Alkyn-2-Ols: A Practical Route To Furans And Pyrroles
    作者:Egi,Masahiro; Azechi,Kenji; Akai,Shuji
    参考文献:Organic Letters 日期:2009 卷标:11(21) 页码:5002-5005]

    23637-56-1 = 955-83-9
    反应条件:1.1 Reagents: Carbon Tetrabromide,Triphenylphosphine Solvents: Dichloromethane; 20 Min,0 °C1.2 Solvents: Dichloromethane; 0 °C -> Rt; 16 H,Rt
    标题:A Biosynthetically Inspired Route To Substituted Furans Using The Appel Reaction: Total Synthesis Of The Furan Fatty Acid F5
    作者:Lee,Robert J.; Lindley,Martin R.; Pritchard,Gareth J.; Kimber,Marc C.
    参考文献:Chemical Communications (Cambridge 日期:2017 卷标:53(47) 页码:6327-6330]

    495-71-6 = 955-83-9
    反应条件:1.1 Catalysts: 1-Butyl-3-Methylimidazolium Hydrogen Sulfate Solvents: 1-Butyl-3-Methylimidazolium Hydrogen Sulfate; 2 H,150 °C; 150 °C -> Rt
    标题:Ionic Liquid As Catalyst And Reaction Medium. A Simple And Efficient Procedure For Paal-Knorr Furan Synthesis
    作者:Wang,Gangqiang; Guan,Zhi; Tang,Rongchang; He,Yanhong
    参考文献:Synthetic Communications 日期:2010 卷标:40(3) 页码:370-377]

    = 955-83-9
    反应条件:1.1 Reagents: Pyridine N-Oxide,Sodium Tetrakis[3,5-Bis(Trifluoromethyl)Phenyl]Borate Catalysts: 2857964-10-2 Solvents: Toluene; 2 H,60 °C
    标题:Synthesis Of Disubstituted Furans Catalysed By [(Aucl)2(μ-Bis(Phosphino)Metallocene)] And Na[barf24]
    作者:Gwinn,Reilly K.; Boggess,Anna E.; Winter,Elizabeth P.; Nataro,Chip
    参考文献:Dalton Transactions 日期:2022 卷标:51(44) 页码:17000-17007]

    495-71-6 = 955-83-9
    反应条件:1.1 Catalysts: Dowex 50Wx8-200 Solvents: Water; 7 H,130 °C
    标题:Method For Green Synthesis Of Polysubstituted Furan With Water As Solvent And Strongly Acidic Cation Exchange Resin As Heterogeneous Catalyst
    参考文献:China]

    3420-38-0 = 955-83-9
    反应条件:1.1 Solvents: Chloroform-D; 4 D,50 °C
    标题:A New Route To Diastereomerically Pure Cyclopropanes Utilizing Stabilized Phosphorus Ylides And γ-Hydroxy Enones Derived From 1,2-Dioxines: Mechanistic Investigations And Scope Of Reaction
    作者:Avery,Thomas D.; Taylor,Dennis K.; Tiekink,Edward R. T.
    参考文献:Journal Of Organic Chemistry 日期:2000 卷标:65(18) 页码:5531-5546]

    = 955-83-9
    反应条件:1.1 Reagents: Potassium Tert-Butoxide Catalysts: Magnetite (Fe3O4) (Copper Impregnated),Copper Oxide (Cuo) (Magnetite Impregnated); 3 D,60 °C1.2 Reagents: Potassium Hydroxide Solvents: Dimethyl Sulfoxide,Water; 1 D,80 °C1.3 Reagents: Water
    标题:Copper-Impregnated Magnetite As A Heterogeneous Catalyst For The Homocoupling Of Terminal Alkynes
    作者:Perez,Juana M.; Cano,Rafael; Yus,Miguel; Ramon,Diego J.
    参考文献:Synthesis 日期:2013 卷标:45(10) 页码:1373-1379]

    342400-98-0 = 955-83-9
    反应条件:1.1 Catalysts: Silver Nitrate Solvents: Dichloromethane; 4 H,Rt
    标题:Methods For The Synthesis Of Heteroaromatic Compounds By Immobilized Silver-Catalyzed 5-Endo-Cyclization Of Alkynes
    参考文献:World Intellectual Property Organization]

    495-71-6 = 955-83-9
    反应条件:1.1 Catalysts: Phosphoric Acid; 3 H,140 °C1.2 Reagents: Sodium Bicarbonate Solvents: Water; Neutralized
    标题:Synthesis Of Arylfurans By Organic-Solvent-Free Method Using Phosphoric Acid As A Solvent And Catalyst
    作者:Ajibola,Ibrahim Yusuf; Ai,Liankun; Li,Baolin
    参考文献:Chemistryselect 日期:2021 卷标:6(36) 页码:9559-9564]

    143536-16-7 + 1191988-22-3 = 955-83-9
    反应条件:1.1 Reagents: Sodium Dodecyl Sulfate Catalysts: 2770985-69-6,2770985-87-8 Solvents: Water; 3 H,Rt
    标题:Recyclable Polyethylene Glycol Ubiquinol Succinate-Bound N-Heterocyclic Carbene-Gold(I) Complexes: Sustainable Micellar Catalysis In Water
    作者:Ballmann,Monika; Ruer,Paul C.; Hofnagel,Oliver; Hiller,Wolf; Krause,Norbert
    参考文献:Acs Sustainable Chemistry & Engineering 日期:2022 卷标:10(22) 页码:7288-7298]

    886-66-8 = 955-83-9
    反应条件:1.1 Reagents: Water Catalysts: Potassium Hydroxide Solvents: Dimethyl Sulfoxide; 4 H,80 °C
    标题:A General Approach To Arylated Furans,Pyrroles,And Thiophenes
    作者:Zheng,Qingwei; Hua,Ruimao; Jiang,Jianhua; Zhang,Lei
    参考文献:Tetrahedron 日期:2014 卷标:70(44) 页码:8252-8256]

    495-71-6 = 955-83-9
    反应条件:1.1 Reagents: Trifluoromethanesulfonic Acid Solvents: Acetonitrile; 1 H,85 °C
    标题:Synthesis Of 1,4-Dicarbonyl Compounds By Visible-Light-Mediated Cross-Coupling Reactions Of α-Chlorocarbonyls And Enol Acetates
    作者:Liu,Qiang; Wang,Rui-Guo; Song,Hong-Jian; Liu,Yu-Xiu; Wang,Qing-Min
    参考文献:Advanced Synthesis & Catalysis 日期:2020 卷标:362(20) 页码:4391-4396]

    73758-48-2 = 955-83-9
    反应条件:1.1 Catalysts: Sodium Tetrakis[3,5-Bis(Trifluoromethyl)Phenyl]Borate,[5-[2-[bis(Tricyclo[3.3.1.13,7]Dec-1-Yl)Phosphino-Kp]Phenyl]-1,2,3,4-Tetrahydro-... Solvents: 1,2-Dichloroethane; 2 H,60 °C
    标题:Bifunctional Phosphine Ligand-Enabled Gold-Catalyzed Direct Cycloisomerization Of Alkynyl Ketones To 2,5-Disubstituted Furans
    作者:Hu,Xiaojun; Zhou,Bingwei; Jin,Hongwei; Liu,Yunkui; Zhang,Liming
    参考文献:Chemical Communications (Cambridge 日期:2020 卷标:56(53) 页码:7297-7300]

    495-71-6 = 955-83-9
    反应条件:1.1 1.5 H,130 °C
    标题:Polyphosphoric Acid
    作者:Dodd,John H.
    参考文献:E-Eros Encyclopedia Of Reagents For Organic Synthesis 日期:2001 卷标:1 页码:1-6
📜(碘乙炔基)苯置于copper(L) Iodide,1,10-菲罗啉,水,Potassium Hydroxide体系中,用 二甲基亚砜 作为反应溶剂,化学反应 6.0H,以90%的收率获得产物2,5-二苯基呋喃
参考文献:铜(i)催化从卤代炔烃或1,3-二炔烃合成2,5-二取代的呋喃和噻吩
标题:铜(i)催化从卤代炔烃或1,3-二炔烃合成2,5-二取代的呋喃和噻吩
摘要:已经报道了使用一锅法从卤代炔烃中使用铜(i)催化剂进行区域选择性合成2,5-二取代的呋喃.该化学过程是通过1,3-二炔的水合反应进行的,这很容易从卤代炔在cui存在下的偶联反应中制备.该方法还可用于2,5-二取代噻吩的简便合成.
DOI:10.1021/jo300692D

海关参考信息

专利信息


专利号:US-4761413-A
优先权日:1986-12-22
标 题:1,5-epoxy-2,3,4,5-tetrahydro-1H-3-benzazepins and use in treatment of ulcers
发明人：WACHTER MICHAEL P; KARANEWSKY DONALD S
权利人:ORTHO PHARMA CORP
摘要:The synthesis of epoxybenzazepin compounds is described. The novel compounds have anti-ulcer activity.

专利号:US-4855426-A
优先权日:1986-12-22
标题:Process of preparing 1,5-epoxy-2,3,4,5-tetrahydro-1H-3-benzazepins
发明人：WACHTER MICHAEL P; KARANEWSKY DONALD S
权利人:ORTHO PHARMA CORP
摘要:The synthesis of epoxybenzazepin compounds is described. The novel compounds have anti-ulcer activity.

专利号:US-9827555-B2
优先权日:2013-07-31
标 题:Catalyst for conversion of synthesis gas
发明人：KARIM KHALID; RAKIB MOHAMMAD ABDUR; KHAN ASAD AHMAD; AL-SEMAHI MOHAMMED
权利人:SAUDI BASIC IND CORP
摘要:The disclosed subject matter presents a catalyst or catalyst composition as well as the methods of making and using the catalyst or catalyst composition. In one aspect, the disclosed subject matter relates to a catalyst comprising CoMn a Si b X c Y d O x wherein in X comprises an element from Group 11; Y comprises an element from Group 12; a ranges from 0.8 to 1.2; b ranges from 0.1 to 1; c ranges from 0.01 to 0.05; d ranges from 0.01 to 0.05; x is a number determined by the valency requirements of the other elements present; and wherein the catalyst converts synthesis gas to at least one olefin.

专利号:US-7745456-B2
优先权日:2000-11-06
标题 :Synthesis and antimicrobial activity of novel dicationic “reversed amidinesâ€?
发明人：BOYKIN DAVID W; TIDWELL RICHARD R; WILSON W DAVID; PERFECT JOHN R; STEPHENS CHAD E
权利人:UNIV NORTH CAROLINA; UNIV DUKE; UNIV GEORGIA STATE RES FOUND
摘要:The present invention relates to novel 2,5-bis{[alkyl (or aryl) imino] aminophenyl}furans and thiophenes of the general formula n nin which R 1 , R 2 , R 3 and R 4 are each independently selected from the group consisting of H, alkyl, alkoxy, halide, and alkylhalide groups; R 5 is H, alkyl or aryl; R 6 is H, alkyl, aryl, or NR 7 R 8 , in which R 7 and R 8 are each independently selected from the group consisting of H, alkyl and aryl; and X is O, S or NR 9 , in which R 9 is H or alkyl, and to the use of such compounds.

专利号:US-2010240770-A1
优先权日:2005-03-11
标 题:Synthesis and use of colloidal III-V nanoparticles
发明人：QI JIFA; BELCHER ANGELA M; SHI AMY; JAFFAR SAEEDA
权利人:QI JIFA; BELCHER ANGELA M; SHI AMY; JAFFAR SAEEDA
摘要:A colloidal suspension of III-V semiconductor nanoparticles.

专利号:US-9486785-B2
优先权日:2013-07-31
标题 :Catalyst and process for the production of olefins from syngas
发明人：KARIM KHALID; KHAN ASAD AHMAD; RAKIB MOHAMMAD ABDUR; AL-SEMAHI MOHAMMED; BAROCHIA JAYEN
权利人:SAUDI BASIC IND CORP
摘要:The present disclosures and inventions relate to a catalyst or catalyst composition and the methods of making and using the catalyst or catalyst composition. In one aspect, the present disclosure relates to a catalyst composition that includes a catalyst having the formula C A C B O x and a catalyst support; a) C A is Co a Mn b X d , wherein X comprises Si, Ti, Cu, Zns Pd, or La or a combination thereof; a ranges from 0.8 to 1.2; b ranges from 0.1 to 1; and d ranges from 0 to 0.5; and b) C B is Ni e Cu f Mg h Si m , wherein e ranges from about 0.8 to 1.2; f ranges from 0 to 1; h ranges from 0 to 0.5; and m ranges from 0 to 0.5; wherein O x is determined by the valence requirements of the other elements present, wherein in the catalyst support consists essentially of magnesia, alumina, silica, titanic, carbon, or zeolite, or a combination thereof; and wherein the catalyst composition converts synthesis gas to at least one olefin.

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主要参考文献

参考标题:Hexafluoroisopropanol As Solvent And Promotor In The Paal-Knorr Synthesis Of N-Substituted Diaryl Pyrroles
作者:Robert H.E. Schirmacher,Daniel Rösch,Franziska Thomas |发布日期:2021.3
摘要:An Additive-Free Synthesis Of Challenging N-Substituted Aryl Pyrroles From The Often Poorly Soluble Corresponding 1,4-Diketones By Means Of The Paal-Knorr Pyrrole Synthesis Is Reported, Which Makes Use Of The Unique Properties Of 1,1,1,3,3,3-Hexafluoroisopropanol (Hfip) As A Solvent And Reaction Promotor. Our Procedure Offers Simple Execution And Purification As Well As Easy Scale-Up And Can Be Applied

合成参考文献


摘要:Shinmyozu, T.; Shibahara, M., Science of Synthesis, (2010) 45, 1302.
摘要:Hou, X.-L.; Peng, X.-S.; Yeung, K.-S.; Wong, H. N. C., Science of Synthesis Knowledge Updates, (2011) 2, 289.
摘要:Joule, J. A., Science of Synthesis Knowledge Updates, (2018) 2, 50.
摘要:Hou, X.-L.; Peng, X.-S.; Yeung, K.-S.; Wong, H. N. C., Science of Synthesis Knowledge Updates, (2011) 2, 318.
摘要:Sainsbury, M., Science of Synthesis Knowledge Updates, (2010) 1, 209.
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