📜对二叔丁基苯置于硝酸,乙酸酐,镍,溶剂黄146,异丙醇体系中,30.0~100.0 °C,7.84 Mpa 条件下,反应生成2,5-二叔丁基苯胺 参考文献:Alkylbenzenes From Benzene And Isobutene. I.1A Preparation,Identification Of Several Fractions 标题:Alkylbenzenes From Benzene And Isobutene. I.1A Preparation,Identification Of Several Fractions 摘要: Doi:10.1021/ja01201A001
专利号:US-8318427-B2 优先权日:2005-12-29 标 题 :Use of acid scavengers for the synthesis of standard length and long-mer nucleic acid arrays 发明人:KUIMELIS ROBERT G; MCGALL GLENN H; GOLDBERG MARTIN J; XU GUANGYU 权利人:KUIMELIS ROBERT G; MCGALL GLENN H; GOLDBERG MARTIN J; XU GUANGYU; AFFYMETRIX INC 摘要:Protective groups which may be cleaved with an activatable deprotecting reagents are employed to achieve a highly sensitive, high resolution, combinatorial synthesis of pattern arrays of diverse polymers. In preferred embodiments of the instant invention, the activatable deprotecting reagent is a photoacid generator and the protective groups are DMT for nucleic acids and tBOC for amino acids. This invention has a wide variety of applications and is particularly useful for the solid phase combinatorial synthesis of polymers.
专利号:US-6916982-B2 优先权日:2000-07-21 标题:Synthesis of perylene-porphyrin building blocks and polymers thereof for the production of light-harvesting arrays 发明人:LOEWE ROBERT S; TOMIZAKI KIN-YA; LINDSEY JONATHAN S 权利人:UNIV NORTH CAROLINA STATE 摘要:The present invention provides methods, compounds, and compositions for the synthesis of light harvesting arrays, such arrays comprising: (a) a first substrate comprising a first electrode; and (b) a layer of light harvesting rods electrically coupled to said first electrode, each of said light harvesting rods comprising a polymer of Formula I:n nX 1 X m+1 ) m   (I)n nwherein m is at least 1; X 1 is a charge separation group, and X 2 through X m+1 are chromophores. At least one of X 2 through X m+1 has at least one perylene group coupled thereto.
专利号:US-2005181421-A1 优先权日:2000-08-03 标题 :Methods of array synthesis 发明人:TRULSON MARK; MCGALL GLENN; FIDANZA JACQUELINE 权利人:AFFYMETRIX INC 摘要:Radiation-activated catalysts (RACs), autocatalytic reactions, and protective groups are employed to achieve a highly sensitive, high resolution, radiation directed combinatorial synthesis of pattern arrays of diverse polymers When irradiated, RACs produce catalysts that can react with enhancers, such as those involved in autocatalytic reactions The autocatalytic reactions produce at least one product that removes protecting groups from synthesis intermediates This invention has a wide variety of applications and is particularly useful for the solid phase combinatorial synthesis of polymers
专利号:US-6887665-B2 优先权日:1996-11-14 标题 :Methods of array synthesis 发明人:TRULSON MARK; MCGALL GLENN; FIDANZA JACQUELINE 权利人:AFFYMETRIX INC 摘要:Radiation-activated catalysts (RACs), autocatalytic reactions, and protective groups are employed to achieve a highly sensitive, high resolution, radiation directed combinatorial synthesis of pattern arrays of diverse polymers. When irradiated, RACs produce catalysts that can react with enhancers, such as those involved in autocatalytic reactions. The autocatalytic reactions produce at least one product that removes protecting groups from synthesis intermediates. This invention has a wide variety of applications and is particularly useful for the solid phase combinatorial synthesis of polymers.
专利号:US-7271231-B2 优先权日:1995-01-24 标 题 :Polymerization of olefins 发明人:BROOKHART MAURICE S; JOHNSON LYNDA KAYE; KILLIAN CHRISTOPHER MOORE 权利人:DU PONT 摘要:Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The polymerizations are catalyzed by selected transition metal compounds, and sometimes other co-catalysts. Since some of the polymerizations exhibit some characteristics of living polymerizations, block copolymers can be readily made. Many of the polymers produced are often novel, particularly in regard to their microstructure, which gives some of them unusual properties. Numerous novel catalysts are disclosed, as well as some novel processes for making them. The polymers made are useful as elastomers, molding resins, in adhesives, etc. Also described herein is the synthesis of linear α-olefins by the oligomerization of ethylene using as a catalyst system a combination a nickel compound having a selected α-diimine ligand and a selected Lewis or Bronsted acid, or by contacting selected α-diimine nickel complexes with ethylene.
专利号:US-8258199-B2 优先权日:2006-01-18 标题:Photoacid generators for the synthesis of oligo-DNA in a polymer matrix 发明人:MCGALL GLENN H; CUPPOLETTI ANDREA 权利人:MCGALL GLENN H; CUPPOLETTI ANDREA; AFFYMETRIX INC 摘要:Compounds represented by the following structural formulas can be used as photoacid generators: n n n n n n n n n n Such compounds are useful, for example, in fabricating arrays of polymers.
[参考文献]: Christopher Elam, Et Al. Discovery Of Novel Serca Inhibitors By Virtual Screening Of A Large Compound Library. Eur J Med Chem. 2011 May;46(5):1512-23.
合成参考文献
参考文献:10.1038/s41529-025-00649-9 摘要:Vignesh K, Sujithra S, Vajjiravel M, Duraimurugan R, Narenkumar J, Devanesan S, Wadaan MA, Rajamohan R, Rajasekar A, Malik T. Dual-function of N-substituted tetrabromophthalic inhibitors for eco-friendly control of microbiologically influenced corrosion in industrial cooling systems. npj Mater Degrad. 2025 Aug 05;9(1). doi: 10.1038/s41529-025-00649-9.