CAS: 17083-68-0; Tetrabromoauric Acid

该化合物是黄金的协调化合物,特别是在+3氧化状态下,与溴皮条结壳复合的三氯氧化状态下,该物质一般是晶状固体,其特点是深色,视特定水合状态和其他离子的存在而不同.该化合物在极地溶剂中溶解,特别是水,由于存在氢离子和四溴环十二酸化合物的离子性质,该化合物由于四溴环十二酸化合物的离子和离子性质,因此溶解.它经常用于各种化学用途,包括催化和作为黄金纳米粒子合成的前体.四溴环十二酸盐具有有趣的电子特性,在研究和工业应用中具有价值.在处理该化合物时,应当采取安全防范措施,因为它含有黄金和溴矿,这两种化合物都可能以某种形式造成健康风险.适当的储存和处置方法对于减轻环境影响至关重要.

结构式图片

MSDS等安全信息

    合成工艺路线路线简述

      📜金置于hbr,Br2体系中,化学反应生成四溴氢金(III)水合物
      参考文献:Ito,Yukari; Asaji,Tetsuo; Ikeda,Ryuichi,Berichte Der Bunsen-Gesellschaft,1988,Vol. 92,P. 885-891
      标题:Ito,Yukari; Asaji,Tetsuo; Ikeda,Ryuichi,Berichte Der Bunsen-Gesellschaft,1988,Vol. 92,P. 885-891

      专利信息


      专利号:US-8641798-B2
      优先权日:2010-07-13
      标 题 :One-step synthesis of monodisperse AU-CU nanocubes
      发明人:HIGHT-WALKER ANGELA R; LIU YONGLIN
      权利人:HIGHT-WALKER ANGELA R; LIU YONGLIN; US OF AMERICA AS REPRESENTED BY THE SECRETARY OF COMMERCE NIST
      摘要:A one-step process for synthesizing gold-copper bimetallic nanocubes. The process comprises the step of simultaneously reducing a copper II salt and a gold halide by 1,2-hexadecanediol in diphenyl ether, and 1-dodecanethiol as well as surfactants 1-adamantanecarboxylic acid and 1-hexadecylamine. The copper II salt may be copper (II) acetylacetonate, copper chloride, copper sulfate, or copper phosphate. The gold halide may be chloroauric acid, gold chloride, gold bromide, or tetrabromoauric acid. The reduction may occur at a temperature between about 160 and 180 degrees Celsius. The copper II salt may be copper (II) acetylacetonate and the gold halide may be chloroauric acid.

      专利号:US-9822053-B2
      优先权日:2016-01-28
      标题:Single step conversion of N-butyraldehyde to 2-ethylhexanal
      发明人:BOPPANA Venkata Bharat; HAMPTON JR KENNETH WAYNE; LIU ZHUFANG; SUMNER JR CHARLES EDWAN; TUSTIN GERALD C; STEINMETZ GUY RALPH; STEFFEY MELISSA PAGE
      权利人:EASTMAN CHEM CO
      摘要:Disclosed is a method of making and using a titania supported palladium catalyst for the single step synthesis of 2-ethylhexanal from a feed of n-butyraldehyde. This titania supported palladium catalyst demonstrates high n-butyraldehyde conversion but also produces 2-ethylhexanal in an appreciable yield with maintained activity between runs. This method provides a single step synthesis of 2-ethylhexanal from n-butyraldehyde with a catalyst that can be regenerated that provides cleaner downstream separations relative to the traditional caustic route.

      专利号:EP-0530187-B1
      优先权日:1990-05-01
      标 题 :Synthesis of dialkyl gold (iii) beta-diketonates

      专利号:US-5023360-A
      优先权日:1990-05-01
      标题:Simplified synthesis of dialkylgold(III) β-diketonates
      发明人:BAUM THOMAS H; BROCK PHILLIP J; DAWSON DANIEL J
      权利人:IBM
      摘要:Dialkyl gold(III) β-diketonates are synthesized in a two-step, one-pot process using a gold trihalide, an alkyl lithium compound and a β-diketone.

      专利号:US-2011283834-A1
      优先权日:2010-07-13
      标题:One-step synthesis of monodisperse au-cu nanocubes

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      品牌试剂参考报价(招募中)

      📌 第三方产品分析报告

      ✅ COA系统入驻 | 共享模式

      合成参考文献


      参考文献:10.3109/14756368909030361
      摘要:Lee MT, Ahmed T, Friedman ME. Inhibition of hydrolytic enzymes by gold compounds. I. beta-Glucuronidase and acid phosphatase by sodium tetrachloroaurate (III) and potassium tetrabromoaurate (III). J Enzyme Inhib. 1989;3(1):23–33. doi: 10.3109/14756368909030361.
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