CAS: 10124-86-4; 1,8-Diisocyanatooctane

该化合物是一种化学化合物,其特征是附于八甲基乙烯链的两个异丙氰酸功能组;一种无色的黄色液体,其发光味通常用于生产聚氨酯弹性体,涂层和粘合剂.OMDI因其反应性而闻名,特别是酒精和氨等核素,导致形成聚氨酯联系.这种化合物的处理通常谨慎,因为其潜在的健康危害,包括呼吸刺激和敏化.它也被列为危险物质,在储存和处理过程中需要采取适当的安全措施. OMDI的独特结构允许开发具有理想机械特性和热稳定性的材料,使其在各种工业应用中具有价值.此外,必须指出,应当实行适当的环境控制,以减少与使用该物质有关的任何风险,因为异氰酸盐会助长空气污染,并对人类健康和环境造成有害影响.

结构式图片

欧盟法规

ECHA物质C&L通报

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sebacic acid dihydrazide phosgene 1,8-diamino°Ctan di-tert-butyl tricarbonate 1,8-diamino°Ctan

合成工艺路线路线简述

    📜癸二酸置于sodium Azide,三氯化磷体系中,化学反应生成1,8-二异氰基辛烷
    参考文献:Synthesis Of Aliphatic Hydroxyethyl-Substituted Ureas
    标题:Synthesis Of Aliphatic Hydroxyethyl-Substituted Ureas
    摘要:
    Doi:10.1134/s1070428015010212

    专利信息


    专利号:US-2019211134-A1
    优先权日:2016-08-19
    标 题 :Thiourethane polymers, method of synthesis thereof and use in fused filament fabrication printing
    发明人:ELLSON GREGORY T; LUND BENJAMIN R; VOIT WALTER
    权利人:BOARD OF REGENTS THE UNIV OF TEXAS; ADAPTIVE 3D TECH
    摘要:A thermoplastic thiourethane polymer comprising a sequential chain of a first type of monomer covalently bonded to a second type of monomer via thiourethane linkages. The first type of monomer includes two or more thiol functional groups and the type of monomer includes two or more isocyanate functional groups. The first and second types of monomers are polymerized together in an anhydrous aprotic solvent-dissolved anionic step-growth polymerization reaction that is catalyzed by a non-nucleophillic base having a pKa greater than 7.

    专利号:US-6174956-B1
    优先权日:1995-06-02
    标题 :Synthesis of condensation polymers in densified fluids
    发明人:KERSCHNER JUDITH LYNNE; JURELLER SHARON HARRIOTT; THOMAIDES JOHN SOCRATES; HUMPHREYS ROBERT WILLIAM; IOVINE CARMINE PHILLIP
    权利人:NAT STARCH CHEM INVEST
    摘要:A polyurethane polymer and method of preparing it is described. The process requires the combination of a soluble polyol with a di- or polyisocyanate under densified fluid conditions. The process to prepare a waterborne polyurethane involves the utilization of a polyol containing ionic or latent ionic groups which must undergo preneutralization before combining with the di- or polyisocyanate under densified fluid conditions. The resulting polyurethane is substantially free of an organic solvent.

    专利号:US-10899072-B2
    优先权日:2016-03-15
    标题:Thiourethane polymers, method of synthesis thereof and use in additive manufacturing technologies
    发明人:ELLSON GREGORY T; LUND BENJAMIN R; VOIT WALTER
    权利人:UNIV TEXAS; ADAPTIVE 3D TECH; BOARD OF RESENTS THE UNIV OF TEXAS SYSTEM
    摘要:A semi-crystalline thiourethane polymer. The semi-crystalline thiourethane polymer comprises a sequential chain of a first type of monomer covalently bonded to a second type of monomer via thiourethane linkages. Each of the first type of monomer includes two or more thiol functional groups and each of the second type of monomer includes two or more isocyanate functional groups. The first and second types of monomers are polymerized together in an anionic step-growth polymerization reaction that is catalyzed by a non-nucleophillic base having a pKa greater than 7, produced by photo-initiated decomposition of a photolatent base. A method of synthesizing, and polymer jetting and stereolithography methods of manufacturing a polymer part, are also disclosed.

    专利号:US-8816125-B2
    优先权日:2006-12-23
    标 题 :Process for the continuous preparation of (cyclo)aliphatic diisocyanates
    发明人:MICHALCZAK HANS-WERNER; KOHLSTRUK STEPHAN; KRECZINSKI MANFRED; GRUND GERDA; LOMOELDER RAINER
    权利人:MICHALCZAK HANS-WERNER; KOHLSTRUK STEPHAN; KRECZINSKI MANFRED; GRUND GERDA; LOMOELDER RAINER; EVONIK DEGUSSA GMBH
    摘要:The invention relates to a multi-stage process for the continuous, phosgene-free preparation of (cyclo)aliphatic diisocyanates that comprises the conversion of (cyclo)aliphatic diamines into the corresponding (cyclo)alkylene biscarbamates and the thermal cleaving of the latter into the (cyclo)alkylene diisocyanates and alcohol. The urea used in accordance with the invention and also the urea employed for the preparation of urea equivalents (e.g. alkyl carbonates, alkyl carbamates) as a possible precursor for the synthesis of the (cyclo)aliphatic biscarbamates is unconditioned.

    专利号:US-10385167-B2
    优先权日:2015-02-13
    标题:Process for the synthesis of polyoxazolidinone compounds with high stability
    发明人:MÜLLER THOMAS ERNST; Gürtler Christoph; BASU SUSMIT; RANGHEARD CLAUDINE; RIVILLO DAVID; LEITNER WALTER; Köhler Burkhard
    权利人:COVESTRO DEUTSCHLAND AG
    摘要:The present invention relates to polyoxazolidinone compounds, a method for the production of polyoxazolidinone compounds, comprising the step of reacting a biscarbamate compound with a bisepoxide compound in the presence of a mono-carbamate, a mono-isocyanate and/or a mono-epoxide compound as chain regulator and a suitable base having a pK b value of ≤9 as catalyst. The invention further relates to the use of polyoxazolidinone compounds with high thermal stability.

    专利号:US-11326018-B2
    优先权日:2016-08-19
    标 题:Process for the synthesis of polyoxazolidinone compounds
    发明人:WEBER ANNA; RANGHEARD CLAUDINE; KESSLER MICHAEL; LEITNER WALTER; Gürtler Christoph; KOOPMANS CARSTEN; MÜLLER THOMAS ERNST
    权利人:COVESTRO DEUTSCHLAND AG
    摘要:A method for the production of polyoxazolidinone compounds, comprising the step of reacting an isocyanate compound (A) with an epoxide compound (B) in the presence of a catalyst (C), wherein the isocyanate compound (A) comprises a isocyanate compound (A 1 ) wherein the a isocyanate compound (A1) comprising at least two isocyanate groups (I 1 ≥2), preferred two isocyanate groups (I 1 =2), wherein the epoxide compound (B) comprises a epoxide compound (B 1 ) and an epoxide compound (B 2 ), wherein the epoxide compound (B 2 ) is different from the epoxide compound (B 1 ) wherein the epoxide compound (B 1 ) comprising at least two terminal epoxide groups (F1≥2), preferred two terminal epoxide groups (F 1 =2), linked together by a linking group (L1) and the epoxide compound (B 2 ) comprising at least two terminal epoxide groups (F 2 ≥2)), preferred two terminal epoxide groups (F 2 =2), linked together by a linking group (L 2 ), wherein the linking group (L 2 ) comprises acyclic and covalent bonds to each other free of conjugated multiple bonds within the main chain, wherein the epoxide compound (B 2 ) is present in the epoxide compounds B 1 and B 2 , in an amount of ≥0.01 mol-% to <10 mol-%, preferred 1-9 mol-% more preferred 3-8 mol-% based on the molar ratio the terminal epoxide groups in the epoxide compound (B 1 ) and of the sum of the terminal epoxide groups in the epoxide compound (B 1 ) and terminal epoxide groups in the epoxide compound (B 2 ).

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    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    主要参考文献

    参考标题:Aminimides. I. A General Synthesis Of Aminimides From Acyl Hydrazides And Their Pyrolysis
    作者:William J. Mckillip,Lawrence M. Clemens,Richard Haugland |发布日期:1967.11.1
    摘要:Acyclic, Alicyclic, And Aromatic Bis-Trimethylaminimides And A Keto-Substituted Trimethylaminimide Have Been Synthesized By A Stepwise Route Of General Applicability. Pyrolysis Of The Aliphatic Aminimides Resulted In A Rearrangement To Trimethylamine And Isocyanate. The Keto-Isocyanate Herein Reported Was Synthesized In A Convenient Four-Step Sequence From Dimethyl Ketene Dimer In A Good Yield, And Provides An Attractive New Route To This Type Of Difunctional Compound. Pyrolysis Of The Bis-Aminimides In The Presence Of Polyhydroxylic Materials Gave Polyurethanes.

    合成参考文献


    摘要:Braverman, S.; Cherkinsky, M.; Birsa, M. L., Science of Synthesis, (2005) 18, 135.
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