📜癸二酸置于sodium Azide,三氯化磷体系中,化学反应生成1,8-二异氰基辛烷 参考文献:Synthesis Of Aliphatic Hydroxyethyl-Substituted Ureas 标题:Synthesis Of Aliphatic Hydroxyethyl-Substituted Ureas 摘要: Doi:10.1134/s1070428015010212
专利信息
专利号:US-2019211134-A1 优先权日:2016-08-19 标 题 :Thiourethane polymers, method of synthesis thereof and use in fused filament fabrication printing 发明人:ELLSON GREGORY T; LUND BENJAMIN R; VOIT WALTER 权利人:BOARD OF REGENTS THE UNIV OF TEXAS; ADAPTIVE 3D TECH 摘要:A thermoplastic thiourethane polymer comprising a sequential chain of a first type of monomer covalently bonded to a second type of monomer via thiourethane linkages. The first type of monomer includes two or more thiol functional groups and the type of monomer includes two or more isocyanate functional groups. The first and second types of monomers are polymerized together in an anhydrous aprotic solvent-dissolved anionic step-growth polymerization reaction that is catalyzed by a non-nucleophillic base having a pKa greater than 7.
专利号:US-6174956-B1 优先权日:1995-06-02 标题 :Synthesis of condensation polymers in densified fluids 发明人:KERSCHNER JUDITH LYNNE; JURELLER SHARON HARRIOTT; THOMAIDES JOHN SOCRATES; HUMPHREYS ROBERT WILLIAM; IOVINE CARMINE PHILLIP 权利人:NAT STARCH CHEM INVEST 摘要:A polyurethane polymer and method of preparing it is described. The process requires the combination of a soluble polyol with a di- or polyisocyanate under densified fluid conditions. The process to prepare a waterborne polyurethane involves the utilization of a polyol containing ionic or latent ionic groups which must undergo preneutralization before combining with the di- or polyisocyanate under densified fluid conditions. The resulting polyurethane is substantially free of an organic solvent.
专利号:US-10899072-B2 优先权日:2016-03-15 标题:Thiourethane polymers, method of synthesis thereof and use in additive manufacturing technologies 发明人:ELLSON GREGORY T; LUND BENJAMIN R; VOIT WALTER 权利人:UNIV TEXAS; ADAPTIVE 3D TECH; BOARD OF RESENTS THE UNIV OF TEXAS SYSTEM 摘要:A semi-crystalline thiourethane polymer. The semi-crystalline thiourethane polymer comprises a sequential chain of a first type of monomer covalently bonded to a second type of monomer via thiourethane linkages. Each of the first type of monomer includes two or more thiol functional groups and each of the second type of monomer includes two or more isocyanate functional groups. The first and second types of monomers are polymerized together in an anionic step-growth polymerization reaction that is catalyzed by a non-nucleophillic base having a pKa greater than 7, produced by photo-initiated decomposition of a photolatent base. A method of synthesizing, and polymer jetting and stereolithography methods of manufacturing a polymer part, are also disclosed.
专利号:US-8816125-B2 优先权日:2006-12-23 标 题 :Process for the continuous preparation of (cyclo)aliphatic diisocyanates 发明人:MICHALCZAK HANS-WERNER; KOHLSTRUK STEPHAN; KRECZINSKI MANFRED; GRUND GERDA; LOMOELDER RAINER 权利人:MICHALCZAK HANS-WERNER; KOHLSTRUK STEPHAN; KRECZINSKI MANFRED; GRUND GERDA; LOMOELDER RAINER; EVONIK DEGUSSA GMBH 摘要:The invention relates to a multi-stage process for the continuous, phosgene-free preparation of (cyclo)aliphatic diisocyanates that comprises the conversion of (cyclo)aliphatic diamines into the corresponding (cyclo)alkylene biscarbamates and the thermal cleaving of the latter into the (cyclo)alkylene diisocyanates and alcohol. The urea used in accordance with the invention and also the urea employed for the preparation of urea equivalents (e.g. alkyl carbonates, alkyl carbamates) as a possible precursor for the synthesis of the (cyclo)aliphatic biscarbamates is unconditioned.
专利号:US-10385167-B2 优先权日:2015-02-13 标题:Process for the synthesis of polyoxazolidinone compounds with high stability 发明人:MÜLLER THOMAS ERNST; Gürtler Christoph; BASU SUSMIT; RANGHEARD CLAUDINE; RIVILLO DAVID; LEITNER WALTER; Köhler Burkhard 权利人:COVESTRO DEUTSCHLAND AG 摘要:The present invention relates to polyoxazolidinone compounds, a method for the production of polyoxazolidinone compounds, comprising the step of reacting a biscarbamate compound with a bisepoxide compound in the presence of a mono-carbamate, a mono-isocyanate and/or a mono-epoxide compound as chain regulator and a suitable base having a pK b value of ≤9 as catalyst. The invention further relates to the use of polyoxazolidinone compounds with high thermal stability.
专利号:US-11326018-B2 优先权日:2016-08-19 标 题:Process for the synthesis of polyoxazolidinone compounds 发明人:WEBER ANNA; RANGHEARD CLAUDINE; KESSLER MICHAEL; LEITNER WALTER; Gürtler Christoph; KOOPMANS CARSTEN; MÜLLER THOMAS ERNST 权利人:COVESTRO DEUTSCHLAND AG 摘要:A method for the production of polyoxazolidinone compounds, comprising the step of reacting an isocyanate compound (A) with an epoxide compound (B) in the presence of a catalyst (C), wherein the isocyanate compound (A) comprises a isocyanate compound (A 1 ) wherein the a isocyanate compound (A1) comprising at least two isocyanate groups (I 1 ≥2), preferred two isocyanate groups (I 1 =2), wherein the epoxide compound (B) comprises a epoxide compound (B 1 ) and an epoxide compound (B 2 ), wherein the epoxide compound (B 2 ) is different from the epoxide compound (B 1 ) wherein the epoxide compound (B 1 ) comprising at least two terminal epoxide groups (F1≥2), preferred two terminal epoxide groups (F 1 =2), linked together by a linking group (L1) and the epoxide compound (B 2 ) comprising at least two terminal epoxide groups (F 2 ≥2)), preferred two terminal epoxide groups (F 2 =2), linked together by a linking group (L 2 ), wherein the linking group (L 2 ) comprises acyclic and covalent bonds to each other free of conjugated multiple bonds within the main chain, wherein the epoxide compound (B 2 ) is present in the epoxide compounds B 1 and B 2 , in an amount of ≥0.01 mol-% to <10 mol-%, preferred 1-9 mol-% more preferred 3-8 mol-% based on the molar ratio the terminal epoxide groups in the epoxide compound (B 1 ) and of the sum of the terminal epoxide groups in the epoxide compound (B 1 ) and terminal epoxide groups in the epoxide compound (B 2 ).
参考标题:Aminimides. I. A General Synthesis Of Aminimides From Acyl Hydrazides And Their Pyrolysis 作者:William J. Mckillip,Lawrence M. Clemens,Richard Haugland |发布日期:1967.11.1 摘要:Acyclic, Alicyclic, And Aromatic Bis-Trimethylaminimides And A Keto-Substituted Trimethylaminimide Have Been Synthesized By A Stepwise Route Of General Applicability. Pyrolysis Of The Aliphatic Aminimides Resulted In A Rearrangement To Trimethylamine And Isocyanate. The Keto-Isocyanate Herein Reported Was Synthesized In A Convenient Four-Step Sequence From Dimethyl Ketene Dimer In A Good Yield, And Provides An Attractive New Route To This Type Of Difunctional Compound. Pyrolysis Of The Bis-Aminimides In The Presence Of Polyhydroxylic Materials Gave Polyurethanes.
合成参考文献
摘要:Braverman, S.; Cherkinsky, M.; Birsa, M. L., Science of Synthesis, (2005) 18, 135.