CAS: 951-87-1; Meso-1,2-Diphenylethane-1,2-Diamine

该化合物是一种有机化合物,其独特结构特征为两组联苯,附于中央乙烯二胺脊柱上;该化合物被归类为手性二胺,尽管以中间形态存在,但意味着它有...

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Diphenylglyoxime H-imidazole-2-thiol4,5-diphenyl-2,5-dihydro-1H-imidazole-2-thiol benzil dioxime erythro-N-benzoyl-N'-phenylmethylidene-1,2-diamino-1,2-diphenylethanecis-5,6-diphenyl-piperazin-2-onecis-5,6-diphenyl-piperazin-2-one meso-N,N'-diacetyl-1,2-diamino-1,2-diphenylethane 2,3,5,6-tetraphenylpyrazine meso-N,N'-((E,E)-dibenzylidene)-bibenzyl-α,α'-diyldiaminemeso-N,N'-((E,E)-dibenzylidene)-bibenzyl-α,α'-diyldiamine

合成工艺路线路线简述

  • 100-52-7 = 951-87-1
    反应条件:1.1 Reagents: Ammonium Hydroxide Solvents: Dichloromethane; < 25 °C1.2 Reagents: 4,4,4′,4′,6,6,6′,6′-Octamethyl-2,2′-Bi-1,3,2-Dioxaborinane
    标题:Green Preparation Of Racemic 1,2-Diphenylethylenediamine
    参考文献:China]

    1781251-41-9 = 951-87-1
    反应条件:1.1 Reagents: Trifluoroacetic Acid Solvents: Dichloromethane; 2 H,0 °C1.2 Reagents: Sodium Hydroxide Solvents: Water; 0 °C
    标题:Enantio- And Diastereoselective Nitro-Mannich Reaction Of α-Aryl Nitromethanes With Amidosulfones Catalyzed By Phase-Transfer Catalysts
    作者:Lu,Ning; Li,Ruxu; Wei,Zhonglin; Cao,Jungang; Liang,Dapeng; Et Al
    参考文献:Journal Of Organic Chemistry 日期:2017 卷标:82(9) 页码:4668-4676]

    33577-29-6 = 951-87-1
    反应条件:1.1 Reagents: Sulfuric Acid Solvents: Water; 24 H,Reflux1.2 -
    标题:Reaction Of Aromatic Aldehydes With Ammonium Acetate
    作者:Proskurnina,M. V.; Lozinskaya,N. A.; Tkachenko,S. E.; Zefirov,N. S.
    参考文献:Russian Journal Of Organic Chemistry (Translation Of Zhurnal Organicheskoi Khimii) 日期:2002 卷标:38(8) 页码:1149-1153]

    2071676-41-8 = 951-87-1
    反应条件:1.1 Reagents: Naphthalene,Radical Ion(1-),Sodium (1:1) Solvents: Tetrahydrofuran; 0 °C; 8 H,Rt1.2 Solvents: Water; 0 °C
    标题:Synergistic Copper-Tempo Catalysis Of Intermolecular Vicinal Diamination Of Styrenes
    作者:Weng,Shiue-Shien; Hsieh,Kun-Yi; Zeng,Zih-Jian; Zhang,Jia-Wei
    参考文献:Tetrahedron Letters 日期:2017 卷标:58(7) 页码:670-673]

    100-52-7 = 951-87-1
    反应条件:1.1 Reagents: Ammonium Acetate; 3 H,120 °C; 120 °C -> Rt1.2 Reagents: Sodium Hydroxide Solvents: Water; Ph 10,Rt1.3 Reagents: Sulfuric Acid Solvents: Water; 12 H,170 °C
    标题:Lipase-Catalyzed Desymmetrization Of Meso-1,2-Diaryl-1,2-Diaminoethanes
    作者:Mendez-Sanchez,Daniel; Rios-Lombardia,Nicolas; Garcia-Granda,Santiago; Montejo-Bernardo,Jose; Fernandez-Gonzalez,Alfonso; Et Al
    参考文献:Tetrahedron: Asymmetry 日期:2014 卷标:25(4) 页码:381-386]

    3190-18-9 = 951-87-1
    反应条件:1.1 Reagents: Hydrochloric Acid
    标题:Reactions Of Trimethylsilyl Cyanide And N-(Trimethylsilyl)Diphenylmethyleneamine With Nitrones And Thermal Decompositions Of Their Adducts
    作者:Tsuge,Otohiko; Urano,Satoshi; Iwasaki,Takahiko
    参考文献:Bulletin Of The Chemical Society Of Japan 日期:1980 卷标:53(2) 页码:485-9]

    100-52-7 = 951-87-1
    反应条件:1.1 Reagents: Sodium Hydride Solvents: Diethyl Ether1.2 Reagents: Lithium Perchlorate Solvents: Diethyl Ether1.3 Reagents: Lithium
    标题:Ultrasound Accelerated Reductive Coupling Of Imine Or Iminium Ion Generated In 5 M Lithium Perchlorate Solution By Lithium Metal
    作者:Mojtahedi,Mohammad M.; Saidi,Mohammad R.; Shirzi,Jafar S.; Bolourtchian,Mohammad
    参考文献:Synthetic Communications 日期:2001 卷标:31(23) 页码:3587-3592]

    144489-93-0 = 951-87-1
    反应条件:1.1 Reagents: Sodium Hydroxide Solvents: Ethanol,Water1.2 Reagents: Lead Tetraacetate Solvents: Water1.3 Reagents: Hydrochloric Acid Solvents: Water1.4 Reagents: Sodium Hydroxide Solvents: Water
    标题:Synthesis Of Nitrogen-Containing Macrocycles With Reductive Intramolecular Coupling Of Aromatic Diimines
    作者:Kise,Naoki; Oike,Hideaki; Okazaki,Eiichi; Yoshimoto,Masami; Shono,Tatsuya
    参考文献:Journal Of Organic Chemistry 日期:1995 卷标:60(13) 页码:3980-92]

    = 951-87-1 [标题:Reaction Conditions
    标题:Preparative Synthesis Of The Corey Chiral Controller For Enantioselective Dihydroxylation Of Olefins
    作者:Lapitskaya,M. A.; Pivnitsky,K. K.
    参考文献:Russian Chemical Bulletin (Translation Of Izvestiya Akademii Nauk 日期:1997 卷标:46(1) 页码:96-100]

    = 951-87-1 [标题:Reaction Conditions
    标题:Intramolecular Imine Cross-Coupling In Dibenzylidene Sulfamides: Synthesis Of Unsymmetrical 1,2-Diaryl Ethanediamines
    作者:Pansare,Sunil V.; Malusare,Mahesh G.
    参考文献:Tetrahedron Letters 日期:1996 卷标:37(16) 页码:2859-62]

    1781251-21-5 = 951-87-1
    反应条件:1.1 Reagents: Trifluoroacetic Acid Solvents: Dichloromethane; 2 H,0 °C
    标题:Chiral Ammonium Betaine-Catalyzed Highly Stereoselective Aza-Henry Reaction Of α-Aryl Nitromethanes With Aromatic N-Boc Imines
    作者:Uraguchi,Daisuke; Oyaizu,Keigo; Noguchi,Haruhiro; Ooi,Takashi
    参考文献:Chemistry - An Asian Journal 日期:2015 卷标:10(2) 页码:334-337]

    = 951-87-1
    反应条件:1.1 Reagents: Sulfuric Acid
    标题:The Diaza-Cope Rearrangement
    作者:Voegtle,Fritz; Goldschmitt,Ernst
    参考文献:Chemische Berichte 日期:1976 卷标:109(1) 页码:1-40]

    91044-05-2 = 951-87-1
    反应条件:1.1 Reagents: Sulfuric Acid
    标题:1,2-Diarylethylenediamines. A Preparation Via Trisubstituted 2-Imidazolines And Conversion To Some New Stilbenediamine Tetraacetic Acids
    作者:Zupanc,S.; Karaman,B.; Jakopcic,K.
    参考文献:Glasnik Hemicara I Tehnologa Bosne I Hercegovine 日期:1983 卷标:27 页码:27-28]

    1201275-76-4 = 951-87-1
    反应条件:1.1 Reagents: Hydrogen Bromide Solvents: Acetic Acid,Water; 4 D,Rt -> 373 K; Cooled
    标题:Meso-4,5-Diphenylimidazolidin-2-One
    作者:Galas,Henry; Viirre,Russell D.; Lough,Alan J.
    参考文献:Acta Crystallographica 日期:2009 卷标:65(12)]

    1414364-68-3 = 951-87-1
    反应条件:1.1 Reagents: Sulfuric Acid Solvents: Water; 1 H,Reflux1.2 Reagents: Sodium Hydroxide Solvents: Water
    标题:Synthesis,Characterization And Biological Studies Of A Sterically Hindered Symmetrical Nitrogen Donor Ligand And Its Metal Complexes
    作者:Shiju,C.; Arish,D.; Bhuvanesh,N.; Kumaresan,S.
    参考文献:Polyhedron 日期:2021 卷标:205]

    33577-29-6 = 951-87-1
    反应条件:1.1 Reagents: Sulfuric Acid Solvents: Water; 24 H,Reflux
    标题:Enantioseparation Of 1-Arylethanols Via A Supramolecular Chiral Host Consisting Of N-(2-Naphthoyl)-L-Aspartic Acid And An Achiral Diamine
    作者:Kodama,Koichi; Kanno,Ayaka; Sekine,Eriko; Hirose,Takuji
    参考文献:Organic & Biomolecular Chemistry 日期:2012 卷标:10(9) 页码:1877-1882]

    33577-29-6 = 951-87-1
    反应条件:1.1 Reagents: Sulfuric Acid Solvents: Water; 24 H,160 °C
    标题:Triptycene-Based Chiral And Meso-N-Heterocyclic Carbene Ligands And Metal Complexes
    作者:Savka,Roman; Bergmann,Marvin; Kanai,Yuki; Foro,Sabine; Plenio,Herbert
    参考文献:Chemistry - A European Journal 日期:2016 卷标:22(28) 页码:9667-9675]

    1414364-68-3 = 951-87-1
    反应条件:1.1 Reagents: Sulfuric Acid Solvents: Water; 1 H,Reflux1.2 Reagents: Sodium Hydroxide
    标题:Synthesis,Characterization And Antimicrobial Activity Of Novel Platinum(Iv) And Palladium(Ii) Complexes With Meso-1,2-Diphenyl-Ethylenediamine-N,N'-Di-3-Propanoic Acid - Crystal Structure Of H2-1,2-Dpheddp.2HCL.H2O
    作者:Radic,Gordana P.; Glodjovic,Verica V.; Ratkovic,Zoran R.; Novakovic,Sladjana B.; Garcia-Granda,Santiago; Et Al
    参考文献:Journal Of Molecular Structure 日期:2012 卷标:1029 页码:180-186]

    100-52-7 = 951-87-1
    反应条件:1.1 Reagents: Ammonium Acetate; 3 H,120 °C; 120 °C -> Rt1.2 Reagents: Sulfuric Acid Solvents: Water; 3 H,180 °C
    标题:Design,Synthesis,And Biological Evaluation Of Imidazoline Derivatives As P53-Mdm2 Binding Inhibitors
    作者:Hu,Chunqi; Li,Xin; Wang,Weisi; Zhang,Lei; Tao,Lulu; Et Al
    参考文献:Bioorganic & Medicinal Chemistry 日期:2011 卷标:19(18) 页码:5454-5461]

    219915-90-9 = 951-87-1 [标题:Reaction Conditions
    标题:Product Subclass 4: N-Nitrogen- Or N-Phosphorus-Functionalized Alkylamines (N >=2)
    作者:Roy,K.-M.
    参考文献:Science Of Synthesis 日期:2009 卷标:40 页码:615-641

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主要参考文献

[参考文献]: Christian Rummey, Et Al. In Silico Fragment-Based Discovery Of Dpp-Iv S1 Pocket Binders. Bioorg Med Chem Lett. 2006 Mar 1;16(5):1405-9.
[参考文献]: Kimberley J Davis, Et Al. Synthesis And Characterisation Of Nickel Schiff Base Complexes Containing The Meso-1,2-Diphenylethylenediamine Moiety: Selective Interactions With A Tetramolecular Dna Quadruplex. Dalton Trans. 2015 Feb 21;44(7):3136-50.
[参考文献]: Koichi Kodama, Et Al. Enantioseparation Of 1-Arylethanols Via A Supramolecular Chiral Host Consisting Of N-(2-Naphthoyl)-L-Aspartic Acid And An Achiral Diamine. Org Biomol Chem. 2012 Mar 7;10(9):1877-82.
[参考文献]: M Tellier, Et Al. A New Fluorogenic Assay For Tyrosine-Containing Peptides. J Pharm Biomed Anal. 1991;9(7):557-63.
[参考文献]: Nobuko Mibu, Et Al. Synthesis And Antiviral Activities Of N-Mono- And/or N,N'-Di-Carbamoyl And Acyl Derivatives Of Symmetrical Diamines. Chem Pharm Bull (Tokyo). 2008 Jul;56(7):1052-8.

合成参考文献

合成方法参考DOI号:10.1021/acs.j°C.7b00306
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