CAS: 53915-69-8; Allenyltributyltin
该化合物是一种该化合物是一种高效的苯乙烯转移剂,它的稳定性和反应性使建立复杂的分子框架,包括含有所有元素的中间体具有价值.该化合物在普通有机溶剂中表现出良好的溶性,便于其在同质反应条件下使用.由于有机锡化合物的毒性,需要谨慎处理,其应用范围扩大到合成药品,农用化学品和高级材料,在这种合成中,对含有所有元素的中间体进行精确控制至关重要.
- 英文名称Allenyltributyltin
- 中文名称1,2-丙二烯三正丁基锡
- 其它别名Stannane,tributyl-1,2-propadienyl- (9CI); Allenyltri-n-butylstannane; Allenyltributylstannane; Allenyltributyltin; Tributyl(1,2-propadienyl)stannane
- CAS编号53915-69-8
- MFCD编号:MFCD00216952
- EINECS号:624-984-1
- 分子式:C15H30Sn分子量:329.11
- 产品CID: 2499060
- 产品分类有机原料 → 有机金属类化合物 → 有机锡
物理性质
MSDS等安全信息
- GHS象形图
- GHS符号GHS06 & GHS08 & GHS09;
注释: Skull and crossbones & Health hazard & Environment - 危险类别急性毒性 类别4(经皮)
急性毒性 类别3(经口)
特定目标器官毒性 - 单次接触 类别3
特定目标器官毒性-重复接触 类别1
皮肤腐蚀/刺激 类别2
严重眼刺激 类别2
水生急性毒性 类别1
水生慢性毒性 类别1
急性毒性 类别2(吸入) - 警示词Danger(危险)
- 危险描述H312 |皮肤接触有害.
H301 |吞咽会中毒.
H335 |可能引起呼吸道刺激.
H372 |长期或反复接触损害器官.
H315 |造成皮肤刺激.
H319 |造成严重眼刺激.
H400 |对水生生物毒性极大.
H410 |对水生生物毒性极大并具有长期持续影响.
H330 |吸入致命. - 防范说明P273-P280-P301+P310+P330-P302+P352+P312-P305+P351+P338-P501
- 危险等级6.1
- UN编号UN 2810 6.1/PG 3
- 危险品标志T,N
- 包装等级III
- 安全声明35-36/37/39-45-60-61
- 危险类别码21-25-36/38-48/23/25-50/53
- WGK Germany3
欧盟法规
C&L通报上下游产品
CAS号1461-22-9 三丁基氯化锡 | CAS号106-96-7 溴代丙炔 | CAS号6165-76-0 对甲苯磺酸丙炔酯 | CAS号688-73-3 三正丁基氢化锡 | CAS号7439-95-4 镁标准溶液 | CAS号10024-18-7 1-bromopropa-1,... | CAS号53915-69-8 1,2-丙二烯三正丁基锡 | CAS号19823-75-7 2-prop-2-ynylcy... | CAS号20810-18-8 non-1-yn-4-ol | CAS号22127-86-2 1-Undecyn-4-ol | CAS号2749-98-6 1-chloro-4-prop... | CAS号675-09-2 4,6-二甲基-2-吡喃酮 | CAS号53915-69-8 1,2-丙二烯三正丁基锡 | CAS号1008-74-8 5-甲基-3-苯基异噁唑 | CAS号1461-22-9 三丁基氯化锡 | CAS号1189-70-4 propargyltrichl... | CAS号112518-79-3 methyl 1-prop-2...合成工艺路线路线简述
📜Bromoallene,三丁基氯化锡置于magnesium体系中,用 Not Given 作为反应溶剂,化学反应生成 1,2-丙二烯三正丁基锡
参考文献:A Novel Mode Of Access To Polyfunctional Organotin Compounds And Their Reactivity In Stille Cross-Coupling Reaction
标题:A Novel Mode Of Access To Polyfunctional Organotin Compounds And Their Reactivity In Stille Cross-Coupling Reaction
摘要:Mono-,Di-,Tri-And Tetra-Functional Organotin Compounds Were Easily Prepared In A Sonicated Barbier Reaction Using Ultrasound Technology Via Coupling Reaction Of Organo Halides With Tin Halides (Bu3Sncl,Bu2Sncl2,Busncl3,Sncl4) Mediated By Magnesium Metal. The Di-And Tri-Functional Organotin Compounds Were Tested In A Stille Cross-Coupling Reaction In Order To Ascertain How Many Groups Were Transferred. (C) 2009 Elsevier B.V. All Rights Reserved.
DOI:10.1016/j.Jorganchem.2009.03.030
海关参考信息
- 2901210000-乙烯
- 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
供应商参考报价(招募中)
品牌试剂参考报价(招募中)
📌 第三方产品分析报告
主要参考文献
参考标题:Synthesis Of Exo- And Endocyclic Enamides Through Copper-Catalyzed Regioselective Intramolecular N -Halovinylation作者:Nicolas Gilbert,Simon Ricard,Jodrey Bergeron,Pierre Lambolez,Benoit Daoust |发布日期:2020.5.10
摘要:Copper‐catalyzed Cross‐coupling Of 1,2‐dihaloalkenes And Amides Leads To Cyclic β‐haloenamides, Which Can Participate In A Second Cross‐coupling Reaction To Efficiently Synthesize Highly Functionalized Cyclic Enamides. The Selectivity Of The Intramolecular Coupling Between Exo‐ And Endocyclic Regioisomers Is A Crucial Synthetic Factor And Can Be Influenced By The Structure Of The Substrate And The Reaction Conditions
合成参考文献
摘要:Wang, K. K., Science of Synthesis, (2008) 44, 263.
摘要:Bubnov, Yu. N.; Kolomnikova, G. D., Science of Synthesis Knowledge Updates, (2012) 3, 267.
摘要:Spivey, A. C.; Tseng, C.-C., Science of Synthesis Knowledge Updates, (2010) 1, 59.
摘要:Mérour, J.-Y.; Joseph, B., Science of Synthesis Knowledge Updates, (2016) 3, 117.
摘要:García-García, P., Science of Synthesis: Asymmetric Organocatalysis, (2012) 1, 851.
📝 需求与反馈
尽可能描述清楚需求与问题信息
