CAS: 19894-97-4; (-)-Myrtenol

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相似化合物

515-00-4 18486-69-6 19250-17-0

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上下游产品

rac-α-pinene (1R/S,5R/S)-6,6-dimethyl-2-methylenebicyclo[3.1.1]heptane (+/-)-(1S,5R)-6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde β-pinene oxide O-(2-Carboxy-benzoyl)-myrtenol(+/-)-O-(2-Carboxy-benzoyl)-myrtenol trans-myrtanol ((1S*,2R*,5S*)-6,6-dimethylbicyclo[3.1.1]heptan-2-yl)methanol (+/-)-(1S,5R)-6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde

合成工艺路线路线简述

    📜[1R-(1Alpha,2Alpha,5Alpha)]-6,6-二甲基螺[双环[3.1.1]庚烷-2,2'-环氧乙烷]置于diborane(6)体系中,用 四氢呋喃 用作溶剂,化学反应生成(-)-桃金娘烯醇
    参考文献:Bessiere-Chretien,Y. Et Al.,Bulletin De La Societe Chimique De France,1972,P. 1000-1008
    标题:Bessiere-Chretien,Y. Et Al.,Bulletin De La Societe Chimique De France,1972,P. 1000-1008

    海关参考信息

    专利信息


    专利号:US-7390926-B2
    优先权日:2006-03-27
    标 题:Process for the diastereoselective alkylation of an ether oxime of the compound nopinone and novel intermediates for the synthesis of diastereospecific 2-amino-nopinone derivatives substituted on carbon 3
    发明人:CAILLE JEAN-CLAUDE; MAUDUIT MARC
    权利人:ZACH SYSTEM
    摘要:The invention provides the diastereoselective alkylation of optically active nopinone to form the compound of formula (I) according to scheme A below: n nin which:n —R is a C 5-15 alkyl group; —R1 is especially a C 1-15 alkyl, C 2-15 alkenyl or C 2-15 alkynyl group or a C 5-15 aryl, each group optionally being substituted; and —X is a halogen atom; and the configuration of the compound of formula (I) is either (E) or (Z) or a mixture of the two. nn The compound of formula (I) is a valuable synthetic intermediate.

    专利号:US-2004053999-A1
    优先权日:1997-09-17
    标题 :Novel compounds and methods for synthesis and therapy
    发明人:BISCHOFBERGER NORBERT W; DAHL TERRENCE C; HITCHCOCK MICHAEL J M; KIM CHOUNG U; LEW WILLARD; LIU HONGTAO; MILLS ROGER G; WILLIAMS MATTHEW A
    摘要:Novel compounds are described. The compounds generally comprise an acidic group, a basic group, a substituted amino or N-acyl and a group having an optionally hydroxylated alkane moiety. Pharmaceutical compositions comprising the inhibitors of the invention are also described. Methods of inhibiting neuraminidase in samples suspected of containing neuraminidase are also described. Antigenic materials, polymers, antibodies, conjugates of the compounds of the invention with labels, and assay methods for detecting neuraminidase activity are also described.

    专利号:US-6225341-B1
    优先权日:1995-02-27
    标 题:Compounds and methods for synthesis and therapy
    发明人:BISCHOFBERGER NORBERT W; KIM CHOUNG U; LEW WILLARD; LIU HONGTAO; WILLIAMS MATTHEW A
    权利人:GILEAD SCIENCES INC
    摘要:Novel compounds are described. The compounds generally comprise an acidic group, a basic group, a substituted amino or N-acyl and a group having an optionally hydroxylated alkane moiety. Pharmaceutical compositions comprising the inhibitors of the invention are also described. Methods of inhibiting neuraminidase in samples suspected of containing neuraminidase are also described. Antigenic materials, polymers, antibodies, conjugates of the compounds of the invention with labels, and assay methods for detecting neuraminidase activity are also described.

    专利号:US-2007225516-A1
    优先权日:2006-03-27
    标题:Process for the diastereoselective alkylation of an ether oxime of the compound nopinone and novel intermediates for the synthesis of diastereospecific 2-amino-nopinone derivatives substituted on carbon 3

    专利号:FR-2898893-A1
    优先权日:2006-03-27
    标题 :METHOD FOR THE DIASTEREOSELECTIVE ALKYLATION OF NOPINONE COMPOUND OXIME ETHER AND NOVEL INTERMEDIATES FOR THE SYNTHESIS OF CARBON-SUBSTITUTED DIASTEREOSPECIFIC 2-AMINO-NOPINONE DERIVATIVES

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    主要参考文献

    参考标题:Efficient Syntheses Of Climate Relevant Isoprene Nitrates And (1R,5S)-(−)-Myrtenol Nitrate
    作者:Sean P Bew,Glyn D Hiatt-Gipson,Graham P Mills,Claire E Reeves
    摘要:Chemoselective Synthesis Of Several Important, Climate Relevant Isoprene Nitrates Using Silver Nitrate To Mediate A 'Halide For Nitrate' Substitution. Employing Readily Available Starting Materials, Reagents And Horner-Wadsworth-Emmons Chemistry The Synthesis Of Easily Separable, Synthetically Versatile 'Key Building Blocks' (E)- And (Z)-3-Methyl-4-Chlorobut-2-En-1-Ol As Well As (E)- And (Z)-1-((2-Met

    合成参考文献


    参考文献:10.1016/0031-9422(88)83114-5
    摘要:Feuerstein I, Danin A, Segal R. Constitution of the essential oil from an Artemisia herba-alba population of Spain. Phytochemistry. 1988 Jan;27(2):433–4. doi: 10.1016/0031-9422(88)83114-5.
    参考文献:10.1016/0305-1978(89)90100-2
    摘要:Coassini Lokar L, Moneghini M. Geographical variation in the monoterpenes of Valeriana officinalis Leaf. Biochemical Systematics and Ecology. 1989 Jan;17(7-8):563–7. doi: 10.1016/0305-1978(89)90100-2.
    参考文献:10.1007/978-981-15-4148-3_17
    摘要:Asakawa Y. Dietary Monoterpenoids. 2021. In: Handbook of Dietary Phytochemicals.
    参考文献:10.1007/s10340-023-01631-7
    摘要:Avosani S, Nieri R, Mazzoni V, Anfora G, Hamouche Z, Zippari C, Vitale ML, Verrastro V, Tarasco E, D’Isita I, Germinara S, Döring TF, Belusic G, Fereres A, Thompson V, Cornara D. Intruding into a conversation: how behavioral manipulation could support management of Xylella fastidiosa and its insect vectors. J Pest Sci. 2023 May 13;97(1):17–33. doi: 10.1007/s10340-023-01631-7.
    参考文献:10.1007/978-3-031-35205-8_5
    摘要:Ijinu TP, Prabha B, Pushpangadan P, George V. Essential Oil-Derived Monoterpenes in Drug Discovery and Development. 2023. In: Drug Discovery and Design Using Natural Products.
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