CAS: 18151-53-6; Trichloro(2,3-Dimethylbutan-2-yl)Silane

该化合物是一种有机硅化合物,其特点是存在三氯原子的硅原子,以及一个分支的烷基化合物,特别是一个甲状腺组,该化合物一般没有颜色,可粉色黄色,有刺鼻味,具有反应性,特别是在水解中,可与空气水分发生反应,以产生硅醇和盐酸;二氯硅烷主要用于硅酮聚合物的合成,并在各种化学工艺中用作混合剂;其特性包括相对低温的沸点和高挥发性,在需要准确控制化学反应的应用中非常重要;由于氯化性质,该化合物也被认为是危险的,需要小心处理和储存,以防止接触和环境污染;总的来说,三氯氟烷在材料科学和化学制造领域发挥着重要作用.

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2,3-Dimethyl-2-butene sulfuric acid trichlorosilane 1,1'-azobis (cyclohexanecarbonitrile)dichlorophenyl(1,1,2-trimethylpropyl)silane

合成工艺路线路线简述

    📜2,3-二甲基-2-丁烯置于偶氮二异丁腈,三氯硅烷体系中,化学反应 23.0H,以77%的收率获得三氯化-1,1,2-三甲基丙基化硅烷
    参考文献:Photoinduced Direct Synthesis Of Silylene-Bridged Dinuclear Iron Complexes [(η5-C5H5)2Fe2(Co)2(μ-Co)(μ-Sihr)] From [(η5-C5H5)Fe(Co)2Sime3] And Rsih3(R =t-Bu,(Cme2)2H)
    标题:Photoinduced Direct Synthesis Of Silylene-Bridged Dinuclear Iron Complexes [(η5-C5H5)2Fe2(Co)2(μ-Co)(μ-Sihr)] From [(η5-C5H5)Fe(Co)2Sime3] And Rsih3(R =t-Bu,(Cme2)2H)
    摘要:在rsih3(r = T-Bu,(Cme2)2H)的存在下,光解[ Cpfe(Co)2Sime3](cp = η5-C5H5)生成了硅基桥联的二核配合物[ Cp2Fe2(Co)2(μ-Co)(μ-Sihr)].配合物[ Cp2Fe2(Co)2(μ-Co)(μ-Sihbut)]的结构通过x射线晶体学确定.
    Doi:10.1246/cl.1987.2247

    专利信息


    专利号:US-2022355262-A1
    优先权日:2019-07-22
    标题 :System and method for manufacturing water-based hydrophobic aerogels and aerogel composites
    发明人:SACHITHANADAM MAHESH; KHORASGANI SOGHRATI ELMIRA; NATARAJAN GAYATHRI
    权利人:KROSSLINKER PTE LTD
    摘要:Embodiments of the present invention provide users with a system and method for manufacturing water-based hydrophobic aerogels and aerogel composites. The system and method can be carried out in a manner which is more rapid than typical ways and can be readily scalable. The method of manufacture is useful for producing water based hydrophobic aerogels and aerogel composites on a large scale with good homogeneity and consistency. Advantageously, the method of manufacture also has the benefit of a shorter processing time due to the vacuum homogenizing and mixing processes, the use of microwave assisted vacuum freeze drying for ease of synthesis of water-based hydrophobic aerogels.

    专利号:US-9416147-B2
    优先权日:2014-04-03
    标题 :Preparation of silazane compound
    发明人:TONOMURA YOICHI; KUBOTA TOHRU
    权利人:SHINETSU CHEMICAL CO
    摘要:A silazane compound useful as synthesis intermediates for paint additives, polymer modifiers, pharmaceuticals and agricultural chemicals is efficiently prepared by reaction of a halosilane compound with an amino-containing compound in a solvent which is the same silazane compound as the target product.

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    合成参考文献


    参考文献:10.1007/s11356-020-07712-9
    摘要:Sturm MT, Herbort AF, Horn H, Schuhen K. Comparative study of the influence of linear and branched alkyltrichlorosilanes on the removal efficiency of polyethylene and polypropylene-based microplastic particles from water. Environmental Science and Pollution Research. 2020 Jan 17;27(10):10888–98. doi: 10.1007/s11356-020-07712-9.
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