CAS: 17454-48-7; Cyclohexano-15-Crown-5

该化合物是属于皇冠醚家族的大型环状化合物,其特点是能够选择性地与电离提取,分离过程和作为阶段转移催化剂等用途,其结构由15个环组成,其中含有五醚联系,这增加了其在有机溶剂中的溶性及其形成稳定的复合体与金属离子的能力.该环状体有助于其僵硬性和符合性稳定,允许有效封装碳化.该复合物的特性包括某些离子的高选择性,使其在诸如离子提取,分离过程和作为阶段转移催化剂等应用中有用.此外,Cyclohexano-15-crown-5可影响有机合成中各种子质的溶解性和再活性,其独特性源于其循环结构的组合以及乙型氧的电饱和性,这有利于与金属离子的协调.

结构式图片

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上下游产品

2-(2-{2-[2-(2-Hydroxy-ethoxy)-ethoxy]-ethoxy}-ethoxy)-cyclohexanol 2,3,5,6,8,9,11,12-°Ctahydro-1,4,7,10,13-benzopentaoxacyclopentadecin Tetraethylene glycol cyclohexane-1,2-epoxideTetraethylene glycol dimethyl ether

合成工艺路线路线简述

    📜苯并-15-冠醚-5置于rh/al2O3 氢气体系中,用 乙醇 用作溶剂,100.0 °C,10.13 Mpa 条件下,反应 5.0H,以95%的收率获得环己酮-15-冠-5
    参考文献:Metal Ion Catalysis In Nucleophilic Substitution Reactions Promoted By Complexes Of Polyether Ligands With Alkali Metal Salts
    标题:Metal Ion Catalysis In Nucleophilic Substitution Reactions Promoted By Complexes Of Polyether Ligands With Alkali Metal Salts
    摘要:Metal Ion Effects Have Been Revealed On Nucleophilic Substitution Reactions Of N-octyl Sulfonates 1-3 Promoted By Complexes Of Polyether Ligands (Pegs,Crown Ethers,Cryptands) With Alkali Metal Salts My (M = Li,Na,K; Y = I,Br) In Low Polarity Solvents (Chlorobenzene,O-Dichlorobenzene,Toluene) At 60 Degrees C. Rate Constants Increase,In The Order K+ < Na+ ''Electrophilic="" Catalysis'').<="" Div="">

    海关参考信息

    专利信息


    专利号:US-4365094-A
    优先权日:1979-12-28
    标 题 :Process for the synthesis of tertiary phosphine oxides, and new tertiary phosphine oxides
    发明人:BOILEAU SYLVIE L; N GUYEN THANH-DUNG; GAUTIER JEAN-CLAUDE C
    权利人:POUDRES & EXPLOSIFS STE NALE
    摘要:The invention relates to the synthesis of tertiary phosphine oxides and also to certain tertiary phosphine oxides. According to the invention, an organic phase containing a halogenomethyl derivative, a secondary phosphine oxide and a phase transfer catalyst in an organic medium is reacted with an aqueous phase containing an inorganic base. The halogenomethyl derivative can be a micromolecule or a macromolecule. The tertiary phosphine oxides are substances which are useful, in particular, in fireproofing, in hydrometallurgy and in the field of plant health.

    专利号:US-8049026-B2
    优先权日:2003-12-31
    标 题 :Synthesis of ionic liquids
    发明人:DAI SHENG; LUO HUIMIN
    权利人:UT BATTELLE LLC
    摘要:Ionic compounds which are liquids at room temperature are formed by the method of mixing a neutral organic ligand with the salt of a metal cation and its conjugate anion. The liquids are hydrophobic, conductive and stable and have uses as solvents and in electrochemical devices.

    专利号:US-2006211871-A1
    优先权日:2003-12-31
    标题 :Synthesis of ionic liquids

    专利号:US-2008146849-A1
    优先权日:2003-12-31
    标题:Synthesis of Ionic Liquids

    专利号:CA-2552189-A1
    优先权日:2003-12-31
    标题:Synthesis of ionic liquids

    专利号:US-7423164-B2
    优先权日:2003-12-31
    标 题 :Synthesis of ionic liquids

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    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    合成参考文献


    参考文献:10.1631/jzus.2005.b0069
    摘要:Song M, Zhu L, Gao X, Dou J, Sun D. Microcalorimetric study on host-guest complexation of naphtho-15-crown-5 with four ions of alkaline earth metal. Journal of Zhejiang University-SCIENCE B. 2005 Jan 01;6(1):69–73. doi: 10.1631/jzus.2005.b0069.
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