CAS: 111-81-9; Methyl Undec-10-Enoate

该化合物是非十二-十-十甲基酸的甲基酯,其特征是其终端双倍结合和酯性功能,该化合物主要用作有机合成的多用途中间体,特别是用于生产香气,调味剂和特殊聚合物,其不饱和结构允许进一步功能化,如天花或聚合化,使其在工业应用中具有价值.该酯组增加了有机溶液中的溶解性,便于其在配制化学中的使用.

结构式图片

相似化合物

112-38-9 112-43-6 112-45-8

欧盟法规

REACH注册ECHA物质C&L通报REACH预注册

上下游产品

CAS号67-56-1 甲醇 | CAS号112-38-9 十一烯酸 | CAS号74-88-4 碘甲烷 | CAS号112-62-9 油酸甲酯 | CAS号54509-73-8 ethene | CAS号1227261-77-9 methyl 11-(benz... | CAS号38460-95-6 10-十一碳烯酰氯 | CAS号2777-66-4 甲基-10-十一烷酸 | CAS号5332-51-4 10-Undecenamide | CAS号109636-19-3 methyl 4-(11-me... | CAS号112065-19-7 d°Cosane-11,12-diol | CAS号104828-34-4 methyl 11-(9-bo... | CAS号35153-15-2 (Z)-9-十四碳烯-1-醇 | CAS号56683-54-6 顺式-11-十六烯-1-醇 | CAS号141023-04-3 1,1,1-三氟-11-十二烯-2-酮 | CAS号1731-86-8 十一酸甲酯 | CAS号112-42-5 十一醇 | CAS号112-43-6 10-十一烯醇

合成工艺路线路线简述

  • 合成目标产物 Methyl 10-Undecenoate 主要起始原料 Methanol And Undecenoic Acid
  • (文献来源)合成步骤主要原料 Methanol 和 Undecenoic Acid
📜2-十一烯酸 反应生成10-烯酸甲酯
参考文献:Jovtscheff,A.,Journal Fur Praktische Chemie (Leipzig 1954),1965,Vol. 28,P. 186-198
标题:Jovtscheff,A.,Journal Fur Praktische Chemie (Leipzig 1954),1965,Vol. 28,P. 186-198

海关参考信息

专利信息


专利号:US-8569560-B2
优先权日:2006-10-13
标题 :Synthesis of terminal alkenes from internal alkenes via olefin metathesis
发明人:SCHRODI YANN; PEDERSON RICHARD L; KAIDO HIROKI; TUPY MICHAEL J
权利人:ELEVANCE RENEWABLE SCIENCES
摘要:This disclosure relates generally to olefin metathesis, and more particularly relates to the synthesis of terminal alkenes from internal alkenes using a cross-metathesis reaction catalyzed by an olefin metathesis catalyst. According to one aspect, for example, a method is provided for synthesizing a terminal olefin, the method comprising contacting, in the presence of a ruthenium alkylidene metathesis catalyst, an olefinic substrate comprised of at least one internal olefin with a cross metathesis partner comprised of an alpha olefinic reactant, under reaction conditions effective to allow cross-metathesis to occur, wherein the reaction conditions include a reaction temperature of at least 35° C. The methods, compositions, reactions and reaction systems herein disclosed have utility in the fields of catalysis, organic synthesis, and industrial chemistry.

专利号:US-2014194584-A1
优先权日:2013-01-07
标题 :Process for the synthesis of w-Unsaturated nitrile-acid/ester in which two types of cross metathesis are alternated consecutively swing process
发明人:DUBOIS JEAN-LUC; COUTURIER JEAN-LUC
权利人:ARKEMA FRANCE
摘要:The invention relates to a process for the synthesis of a monounsaturated nitrile-ester (acid) by cross metathesis starting from an unsaturated compound I comprising at least one trivalent nitrile, acid or ester functional group, characterized in that it comprises a stage in which two types of cross metathesis are alternated consecutively:n a first type of cross metathesis cm1 with an acrylic compound II chosen from acrylonitrile, acrylic acid or an acrylic ester, one of the compounds I or II comprising a nitrile functional group and the other of these compounds II or I comprising an acid or ester functional group, and a second type of cross metathesis cm2 with a light C 2 to C 4 alkene compound III, preferably with ethylene. nn The invention also relates to a process for the synthesis of an α,ω-amino ester (acid) obtained by a process comprising a stage in which the two types of cross metathesis defined above are alternated consecutively, followed by a hydrogenation stage.

专利号:US-9382189-B2
优先权日:2013-02-08
标题:Synthesis of a branched unsaturated compound by means of cross metathesis
发明人:DUBOIS JEAN-LUC; COUTURIER JEAN-LUC
权利人:ARKEMA FRANCE
摘要:The invention relates to a method for the synthesis of a branched unsaturated fatty compound, said method comprising the metathesis, in the presence of a metathesis catalyst, of a linear unsaturated fatty compound and a branched olefin. The branched unsaturated fatty compound is used in particular for the production of at least one of the following products: dielectric fluids, specialty surfactants, emulsifiers, frictions agents, antistatic additives, antifogging additives, mould release agents, pigment dispersants, high-performance lubricants, waxes and wax emulsifiers, polymer conversion additives, PVC stabilizing agents, inks, resins, paints, varnishes, solvents, lipsticks, creams for the skin, deodorants, particularly stick deodorants, hair dyes, shampoos and other liquid soaps, shaving foam, laundry detergents, cleaning agents, fabric softeners, and mixtures of same.

专利号:US-8642792-B2
优先权日:2007-02-15
标题 :Method for the synthesis of omega-amino-alkanoic acids
发明人:DUBOIS JEAN-LUC
权利人:DUBOIS JEAN-LUC; ARKEMA FRANCE
摘要:The invention relates to a method for the synthesis of amino acids/esters of general formula NH 2 —(CH 2 ) n —COOR in which n is an integer between 5 and 14, and R is either H or an alkyl radical including from 1 to 4 carbon atoms, from natural long-chain mono-unsaturated fatty acids or esters including at least 10 adjacent carbon atoms per molecule, said method comprising: first converting, if necessary, said natural long-chain fatty acid or ester into a monounsaturated fatty acid/ester of general formula R 1 —(CH 2 ) m —CHâ•?CH—(CH 2 ) p —COOR in which R 1 is H, CH 3 or a COOR radical, m is an integer between 0 and 14 and p is an integer between 2 and 11, then submitting the latter to a crossed catalytic metathesis reaction with a compound of formula R 2 —CHâ•?CH—R 3 in which R 2 is either H or CN and R 3 is CN or CH 2 NH 2 , provided that if R 2 is CN, R 3 can be only CN, and finally converting the resulting product of the general formula R 3 —CHâ•?CH—(CH 2 ) p —COOR into an amino-acid, either by hydrogenation, or by hydrogenation of the trple terminal bond, or by amination of the double terminal bond.

专利号:US-2023174477-A1
优先权日:2021-12-03
标题:Methods for synthesis of the tricyclic prostaglandin d2 metabolite methyl ester
发明人:DAI MINGJI; SIMS HUNTER
权利人:PURDUE RESEARCH FOUNDATION
摘要:Methods for the synthesis of a tricyclic-prostaglandin D 2 metabolite methyl ester or a pharmaceutically acceptable salt thereof.

专利号:US-9567293-B2
优先权日:2013-02-08
标题 :Combined synthesis of a nitrile-ester/acid and of a diester/diacid
发明人:DUBOIS JEAN-LUC; COUTURIER JEAN-LUC; BRANDHORST MARKUS
权利人:ARKEMA FRANCE
摘要:A method for the combined synthesis of a mono-unsaturated nitrile-ester(acid) and of a bi-functional carbonyl compound, wherein it includes a step including the cross metathesis mc1 of an unsaturated fatty acid/ester compound with an unsaturated nitrile compound, in which mc1 is performed with partial conversion such as to obtain and recover, separately, at least the following products: a mono-unsaturated nitrile-ester/acid and a symmetrical compound, diester or diacid respectively including a double bond located in the middle of the molecular chain of compound, and subsequently a step including the oxidation cleavage cp2 of the double bond of compound, such as to form a single type of carbonyl compound having formula R2-(CH2)n-COR′, in which R′ is H or OH, depending on the operating conditions selected for the oxidation cleavage cp2. Also, the production of monomers for the polymer industry.

供应商参考报价(招募中)

品牌试剂参考报价(招募中)

📌 第三方产品分析报告

✅ COA系统入驻 | 共享模式

主要参考文献

[参考文献]: Anastasiya Rybak, Et Al. Acyclic Diene Metathesis With A Monomer From Renewable Resources: Control Of Molecular Weight And One-Step Preparation Of Block Copolymers. Chemsuschem. 2008;1(6):542-7.

合成参考文献


摘要:Black, D. A.; Fagnou, K., Science of Synthesis, (2010) 45, 644.
摘要:Baird, M. S., Science of Synthesis, (2010) 47, 1124.
摘要:Kantchev, E. A. B.; Organ, M. G., Science of Synthesis, (2009) 48, 63.
摘要:Li, Y.; Xie, W.; Jiang, X., Science of Synthesis Knowledge Updates, (2016) 2, 27.
摘要:Li, Y.; Xie, W.; Jiang, X., Science of Synthesis Knowledge Updates, (2016) 2, 48.
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