对乙基苯甲酸置于盐酸,Amalgamated Zinc,Thorium Dioxide体系中,化学反应生成1,4-二乙基苯 参考文献:Birch Et Al.,Journal Of The American Chemical Society,1949,Vol. 71,P. 1362,1366 标题:Birch Et Al.,Journal Of The American Chemical Society,1949,Vol. 71,P. 1362,1366
专利号:US-8975358-B2 优先权日:2010-07-23 标题 :Compositions and methods for synthesis of organic-silica hybrid materials 发明人:SHEA KENNETH J; HU LI-CHIH 权利人:SHEA KENNETH J; HU LI-CHIH; UNIV CALIFORNIA 摘要:The present invention relates to compositions and methods for synthesis of organic-silica hybrid microparticles and nanoparticles. In particular, the present invention provides compositions and methods for particle size control during synthesis of organic-silica hybrid microparticles and nanoparticles.
专利号:US-4940803-A 优先权日:1988-05-23 标题:Process for synthesis of 1R,2R,5R-2-hydroxy-6-oxo-7-oxabicyclo[3.2.1]-octane 发明人:MILLS SANDER G; VOLANTE RALPH P; SHINKAI ICHIRO 权利人:MERCK & CO INC 摘要:A process is described for the synthesis of hydroxy lactone 3, being 1R, 2R, 5R-2-hydroxy-6-oxo-7-oxabicyclo[3.2.1]-octane, in optically pure form, which is useful as an intermediate in the synthesis of the C 20 -C 34 chain of the macrolide structure for the immunosuppressant FK-506. This compound is also useful as a precursor for producing an ultraviolet radiation absorber.
专利号:US-2003162992-A1 优先权日:2001-12-14 标 题 :Preparation of intermediates useful in the synthesis of antiviral nucleosides 发明人:WATANABE KYOICHI A; DU JINFA 摘要:The present invention is an efficient process for the manufacture of α-acyloxyacetaldehyde, a key intermediate in the synthesis of 1,3-oxathiolane and 1,3-dioxolane nucleosides.
专利号:US-5239023-A 优先权日:1990-10-24 标 题 :Process for the synthesis of crystallizable 3,4-polyisoprene and isoprene-butadiene copolymers having high vinyl contents 发明人:HSU WEN-LIANG; HALASA ADEL F 权利人:GOODYEAR TIRE & RUBBER 摘要:Crystallizable 3,4-polyisoprene and isoprene-butadiene copolymers having high vinyl contents can be synthesized in organic solvents to quantitative yields after short polymerization times by utilizing the catalyst systems of this invention. The 3,4-polyisoprene made utilizing this catalyst system is strain crystallizable and can be employed in tire treads which provide improved traction and improved cut growth resistance. This invention specifically discloses a process for the synthesis of 3,4-polyisoprene which comprises polymerizing isoprene monomer in an organic solvent at a temperature which is within the range of about -10 DEG C. to about 100 DEG C. in the presence of a catalyst system which is comprised of (a) an organoiron compound which is soluble in the organic solvent, wherein the iron in the organoiron compound is in the +3 oxidation state, (b) a partially hydrolyzed organoaluminum compound which was prepared by adding a protonic compound selected from the group consisting of water, alcohols and carboxylic acids to the organoaluminum compound, and (c) a chelating aromatic amine; wherein the molar ratio of the chelating amine to the organoiron compound is within the range of about 0.1:1 to about 1:1, wherein the molar ratio of the organoaluminum compound to the organoiron compound is within the range of about 5:1 to about 200:1, and wherein the molar ratio of the protonic compound to the organoaluminum compound is within the range of about 0.001:1 to about 0.2:1.
专利号:US-5061765-A 优先权日:1990-10-22 标题:Process for the synthesis of a high vinyl isoprene-butadiene copolymer 发明人:HSU WEN-LIANG; HALASA ADEL F 权利人:GOODYEAR TIRE & RUBBER 摘要:Isoprene-butadiene copolymers having high vinyl contents can be synthesized in organic solvents to high yields after short polymerization times by utilizing the process of this invention. The isoprene-butadiene copolymers made utilizing the process of this invention have a glass transition temperature which is within the range of about 0° C. to about -60° C. and can be employed in tire treads which provide improved traction and improved cut growth resistance. This invention specifically discloses a process for the synthesis of isoprene-butadiene copolymers having a high vinyl content which comprises copolymerizing isoprene monomer and butadiene monomer in an organic solvent at a temperature which is within the range of about -10° C. to about 100° C. in the presence of a catalyst system which is comprised of (a) an organoiron compound, (b) an organoaluminum compound, (c) a chelating aromatic amine, and (d) a protonic compound; wherein the molar ratio of the chelating amine to the organoiron compound is within the range of about 0.1:1 to about 1:1, wherein the molar ratio of the organoaluminum compound to the organoiron compound is within the range of about 5:1 to about 200:1, and wherein the molar ratio of the protonic compound to the organoaluminum compound is within the range of about 0.001:1 to about 0.2:1.
专利号:US-5151398-A 优先权日:1990-10-24 标 题 :Catalyst for the synthesis of crystalline 3,4-polyisoprene 发明人:HSU WEN-LIANG; HALASA ADEL F 权利人:GOODYEAR TIRE & RUBBER 摘要:Crystallizable 3,4-polyisoprene can be synthesized in organic solvents to quantitative yields after short polymerization times by utilizing the catalyst systems of this invention. The 3,4-polyisoprene made utilizing this catalyst system is strain crystallizable and can be employed in tire treads which provide improved traction and improved cut growth resistance. This invention specifically discloses a process for the synthesis of 3,4-polyisoprene which comprises polymerizing isoprene monomer in an organic solvent at a temperature which is within the range of about -10° C. to about 100° C. in the presence of a catalyst system which is comprised of (a) an organoiron compound, (b) an organoaluminum compound, (c) a chelating aromatic amine, and (d) a protonic compound; wherein the molar ratio of the chelating amine to the organoiron compound is within the range of about 0.1:1 to about 1:1, wherein the molar ratio of the organoaluminum compound to the organoiron compound is within the range of about 5:1 to about 200:1, and wherein the molar ratio of the protonic compound to the organoaluminum compound is within the range of about 0.001:1 to about 0.2:1.
参考标题:Inbr3-Catalyzed Reduction Of Ketones With A Hydrosilane: Deoxygenation Of Aromatic Ketones And Selective Synthesis Of Secondary Alcohols And Symmetrical Ethers From Aliphatic Ketones 作者:Norio Sakai,Ken Nagasawa,Reiko Ikeda,Yumi Nakaike,Takeo Konakahara |发布日期:2011.6 摘要:An Inbr3-Et3Sih Reducing System Was Developed To Selectively Convert Aliphatic Ketones To A Variety Of Secondary Alcohols In Moderate To Good Yields. An Initial Mixing Of Inbr3 And Phsih3 Was Followed By The Addition Of Aliphatic Ketones And A Solvent To Afford The Symmetrical Ether Derivatives.
合成参考文献
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