CAS: 80376-66-5; N'-Tert-Butyl-N-Methyl-N-(Trimethylsilylmethyl)Methanimidamide

英文名称N'-Tert-Butyl-N-Methyl-N-(Trimethylsilylmethyl)Methanimidamide
中文名称N-甲基-N-三甲基硅甲基-N’-叔丁基脒
其它别名N-METHYL-N-TRIMETHYLSILYLMETHYL-N'-TERT-BUTYLFORMAMIDINE; meyers' tms form; N-Methyl-N-trimethylsilylmethyl-N'-tert-butylformamidine,; N-Methyl-N-trimethylsilylmethyl-N'-tert-butylformamidineMeyers' TMS form reagent
CAS编号80376-66-5
MFCD编号:MFCD00272687
分子式:C10H24N2Si分子量:200.4
产品CID: 1799104
产品分类化学试剂 → 有机试剂 → 亚氨、脒

相似结构搜索
InChIKey: MFQDMLNXILAMOB-DHZHZOJOSA-N
1S/C10H24N2Si/c1-10(2,3)11-8-12(4)9-13(5,6)7/h8H,9H2,1-7H3
计算化学: 氢键受体数1.0氢键供体数*可旋转键数4.0

MSDS等安全信息

危险品标志Xn
安全声明36/37
危险类别码20/21/22

上下游产品

chloro-trimethyl-silane (E)-N′-tert-butyl-N,N-dimethylformimidamideN'-tert-Butyl-N-methyl-N-((1E,3E)-4-phenyl-buta-1,3-dienyl)-formamidine racem. 2,6-Dimethyl-1-cyan-cyclohexan N'-tert-Butyl-N-(2,2-diphenyl-vinyl)-N-methyl-formamidine cyclohex-2-enecarbonitrile

合成工艺路线路线简述

75-77-4 + 23314-06-9 + 598-30-1 = 80376-66-5 [标题:Reaction Conditions
标题:Enamidines. Versatile Vehicles For Homologation Of Carbonyl Compounds
作者:Meyers,A. I.; Et Al
参考文献:Journal Of The American Chemical Society 日期:1982 卷标:104(3) 页码:877-9]

4637-24-5 + 75-64-9 = 80376-66-5
反应条件:1.1 Reagents: Dimethyl Sulfate2.1 Reagents: Sec-Butyllithium2.2 -
标题:N'-Tert-Butyl-N-Methyl-N-Trimethylsilylmethylformamidine
作者:Nelson,Todd D.; Et Al
参考文献:E-Eros Encyclopedia Of Reagents For Organic Synthesis 日期:2001 卷标:1 页码:1-2]

75-64-9 = 80376-66-5
反应条件:1.1 Catalysts: Dimethyl Sulfate2.1 Catalysts: Sec-Butyllithium
标题:N'-T-Butyl-N-Methyl-N-Trimethylsilylmethylformamidine
作者:Nelson,Todd D.; Et Al
参考文献:E-Eros Encyclopedia Of Reagents For Organic Synthesis 日期:2001]

75-64-9 = 80376-66-5
反应条件:1.1 Reagents: Dimethyl Sulfate2.1 Reagents: Sec-Butyllithium2.2 -
标题:N'-Tert-Butyl-N-Methyl-N-Trimethylsilylmethylformamidine
作者:Nelson,Todd D.; Et Al
参考文献:E-Eros Encyclopedia Of Reagents For Organic Synthesis 日期:2001 卷标:1 页码:1-2]

75-77-4 + 23314-06-9 = 80376-66-5
反应条件:1.1 Reagents: Sec-Butyllithium1.2 -
标题:N'-Tert-Butyl-N-Methyl-N-Trimethylsilylmethylformamidine
作者:Nelson,Todd D.; Et Al
参考文献:E-Eros Encyclopedia Of Reagents For Organic Synthesis 日期:2001 卷标:1 页码:1-2]

75-77-4 + 119044-70-1 = 80376-66-5
反应条件:1.1 Catalysts: Sec-Butyllithium
标题:N'-T-Butyl-N,N-Dimethylformamidine
作者:Nelson,Todd D.; Et Al
参考文献:E-Eros Encyclopedia Of Reagents For Organic Synthesis 日期:2001]

75-77-4 + 119044-70-1 = 80376-66-5
反应条件:1.1 Catalysts: Sec-Butyllithium
标题:N'-T-Butyl-N-Methyl-N-Trimethylsilylmethylformamidine
作者:Nelson,Todd D.; Et Al
参考文献:E-Eros Encyclopedia Of Reagents For Organic Synthesis 日期:2001]

4637-24-5 + 75-64-9 = 80376-66-5
反应条件:1.1 Catalysts: Dimethyl Sulfate2.1 Catalysts: Sec-Butyllithium
标题:N'-T-Butyl-N,N-Dimethylformamidine
作者:Nelson,Todd D.; Et Al
参考文献:E-Eros Encyclopedia Of Reagents For Organic Synthesis 日期:2001]

4637-24-5 + 75-64-9 = 80376-66-5
反应条件:1.1 -2.1 Catalysts: Sec-Butyllithium
标题:N'-T-Butyl-N-Methyl-N-Trimethylsilylmethylformamidine
作者:Nelson,Todd D.; Et Al
参考文献:E-Eros Encyclopedia Of Reagents For Organic Synthesis 日期:2001]

75-64-9 = 80376-66-5
反应条件:1.1 Catalysts: Dimethyl Sulfate2.1 Catalysts: Sec-Butyllithium
标题:N'-T-Butyl-N,N-Dimethylformamidine
作者:Nelson,Todd D.; Et Al
参考文献:E-Eros Encyclopedia Of Reagents For Organic Synthesis 日期:2001

📜三甲基氯硅烷,N,N-Dimethyl Tert-Butylamino-Formamidine 在仲丁基锂体系中,用四氢呋喃作为反应溶剂,以89.2%的收率获得n'-Tert-Butyl-N-Methyl-N-(Trimethylsilylmethyl)Methanimidamide
参考文献:Enamidines. Versatile Vehicles For Homologation Of Carbonyl Compounds
标题:Enamidines. Versatile Vehicles For Homologation Of Carbonyl Compounds
摘要:
Doi:10.1021/Ja00367A052