CAS: 76-63-1; Allyltriphenyltin

上下游产品

triphenyltin chloride allyl bromide allylmagnesium bromide allyltriethylgermane allylcyclohexane 3-cyclohexylbutyronitrile (1S,2R)-1-Methylsulfanyl-1-phenyl-pent-4-en-2-ol (1S,2S)-1-Methylsulfanyl-1-phenyl-pent-4-en-2-ol

📜丙二烯,三苯基氢化锡置于四(三苯基膦)钯体系中,用 四氢呋喃 作为反应溶剂,以40%的收率获得产物丙烯基三苯基锡
参考文献:Hydrostannation And Hydrogermylation Of Allenes
标题:Hydrostannation And Hydrogermylation Of Allenes
摘要:在 Pd(Pph3)4 催化剂存在下,用 Ph3Snh 或 Ph3Geh 处理烯烃,可以得到相应的烯丙基锡烷或烯丙基锗,产率很高.此外,还介绍了在 Et3B 诱导下 Ph3Snh 或 Ph3Geh 与烯烃的自由基加成.
DOI:10.1246/bcsj.61.2693

专利信息

专利号:US-6624116-B1
优先权日:1998-09-03
标 题 :On-line synthesis and regeneration of a catalyst used in autothermal oxidation
发明人：BHARADWAJ SAMEER S; MAJ JOSEPH J; SIDDALL JONATHAN H
权利人:DOW GLOBAL TECHNOLOGIES INC
摘要:An on-line method of synthesizing or regenerating catalysts for autothermal oxidation processes, specifically, the oxidation of paraffinic hydrocarbons, for example, ethane, propane, and naphtha, to olefins, for example, ethylene and propylene. The catalyst comprises a Group 8B metal, for example, a platinum group metal and, optionally, a promoter, such as tin, antimony, or copper, on a support, preferably a monolith support. On-line synthesis or regeneration involves co-feeding a volatile Group 8B metal compound and/or a volatile promoter compound with the paraffinic hydrocarbon and oxygen into the oxidation reactor under ignition or autothermal conditions.

专利号:US-8329923-B2
优先权日:2010-06-17
标 题:4, 4′ disubstituted 4H-cyclopentadithiophene and new methods for synthesizing the same
发明人：VANDERZANDE DIRK; LUTSEN LAURENCE; VAN MIERLOO SARAH
权利人:VANDERZANDE DIRK; LUTSEN LAURENCE; VAN MIERLOO SARAH; IMEC; UNIV HASSELT
摘要:The present preferred embodiments relate to a method for the synthesis of a compound having the following general formula: n nthe method comprising the step of reacting, in presence of a diprotic acid having a negative pKa, a compound having the general formula:n n nwherein R 1 and R 2 are organic groups and wherein X and Y are independently selected from the group consisting of hydrogen, chloro, bromo, iodo, boronic acid, boronate esters, borane, pseudohalogen and organotin. It further relates to compounds so obtained and to compounds resulting from the ring closure of compound (II).

专利号:WO-0014037-A1
优先权日:1998-09-03
标题:On-line synthesis and regeneration of a catalyst used in autothermal oxidation

专利号:US-6166283-A
优先权日:1998-09-03
标题:On-line synthesis and regenerating of a catalyst used in autothermal oxidation

专利号:EP-1114013-A1
优先权日:1998-09-03
标 题:On-line synthesis and regeneration of a catalyst used in autothermal oxidation

专利号:EP-1114013-B1
优先权日:1998-09-03
标 题:On-line synthesis and regeneration of a catalyst used in autothermal oxidation