CAS: 722-27-0; Bis(4-Aminophenyl)Disulfide

上下游产品

4-thi°Cyanatoaniline di(p-nitrophenyl) disulfide bis(4-nitrophenyl)sulfide (4-acetamidophenyl)disulfide bis-{4-[bis-(2-hydroxy-ethyl)-amino]-phenyl}-disulfide trans-cinnamylidenamino-phenyl)-disulfidebis-(4-trans-cinnamylidenamino-phenyl)-disulfide bis-(4-is°Cyanato-phenyl)-disulfide bis-(4-lauroylamino-phenyl)-disulfide

📜4,4'-二硝基二苯二硫醚置于bis(Acetylacetonate)Nickel(II)体系中,用 1,4-二氧六环 作为反应溶剂,以88%的收率获得产物4,4'-二氨基二苯二硫醚
参考文献:镍催化的氢甲硅烷基化还原将硝基化合物选择性还原为伯胺†
标题:镍催化的氢甲硅烷基化还原将硝基化合物选择性还原为伯胺†
摘要:发现ni(acac)2和pmhs是硝基化合物化学选择性转移加氢成伯胺的出色催化体系.在温和的条件下,一系列含有各种敏感官能团(包括醛,酯,氰基和腈)的硝基化合物被还原成其相应的胺,收率非常好至优异,而没有副产物.
DOI:10.1039/c5Ra17731F

专利信息

专利号:US-5239052-A
优先权日:1990-08-30
标 题 :Process for synthesis of aromatic sulfides
发明人：HAY ALLAN S; WANG ZHI Y
权利人:HAY ALLAN S; WANG ZHI Y
摘要:Aromatic sulfides including diarylsulfides and poly(arylene sulfides) are produced in a novel synthesis in high yield under moderate conditions by heating an aromatic disulfide in the presence of aromatic halide, in which the halide is chloride, bromide or iodide; the diaryl sulfides are useful precursors and starting materials for a range of compounds and the poly(arylene sulfides) are important high temperature engineering thermoplastics.

专利号:US-5177183-A
优先权日:1990-08-30
标 题:Process for synthesis of aromatic sulfides
发明人：HAY ALLAN S; WANG ZHI Y
权利人:HAY ALLAN S; WANG ZHI Y
摘要:Aromatic sulfides including diarylsulfides and poly(arylene sulfides) are produced in a novel synthesis in high yield under moderate conditions by heating an aromatic disulfide in the presence of aromatic halide, in which the halide is chloride, bromide or iodide; the diaryl sulfides are useful precursors and starting materials for a range of compounds and the poly(arylene sulfides) are important high temperature engineering thermoplastics.

专利号:WO-2025004100-A1
优先权日:2023-06-26
标 题 :A crosslinker and carbon/glass fiber-reinforced epoxy composites therefrom
发明人：SAHOO SUSHANTA KUMAR; VIJAYAN ARYA; LAKSHMANAN VENKATASUBRAMANIAM; PUTHENPURACKAL RAVI RAJIMOL
权利人:COUNCIL SCIENT IND RES
摘要:The present invention relates to covalent network-based polymers derived from imine and disulphide based crosslinkers with the epoxy. The recyclability of the high-cost fibres is achieved by the synthesis of epoxy vitrimers based on dynamic imine and imine-disulphide bonds. Schiff base chemistry and condensation reaction are used to prepare the crosslinkers with imine linkages as well as imine-disulphide linkages. Various aromatic carbonyl compounds like divanillin, terepthaldehyde, vanillin, 4-hydroxy benzaldehyde, isatin etc. are used for the reaction with various aliphatic and aromatic amines like IPDA, 2-AFD, 4-AFD etc. The prepared epoxy vitrimers showed comparable thermal, mechanical and thermomechanical properties with the conventional DGEBA epoxy-amine system. The carbon/glass fiber-reinforced composite with the vitrimers showed superior mechanical properties beneficial for many engineering applications. The recycling of the vitrimers and composites can be achieved by simple immersion in a suitable solvent system with stirring or agitation at ambient temperature (30-60ºC) conditions. The fibers were easily recovered without losing their morphology, strength and structural integrity. With this invention, wastage of reinforcement carbon fibers and glass fibers can be minimized and the recovered fibers can be used for other applications with a circular economy approach.

专利号:CN-107620088-A
优先权日:2017-09-14
标 题 :A method for the synthesis of 3-mercaptoindole compounds by electrochemical catalytic oxidation

专利号:CN-107620088-B
优先权日:2017-09-14
标 题:A kind of method of electrochemical catalytic oxidation synthesis 3- sulfydryl indole class compound

专利号:CN-119081067-A
优先权日:2024-08-30
标 题:Epoxy resin containing dynamic covalent bond, synthesis method thereof and preparation method of self-repairing epoxy structural adhesive