CAS: 251984-08-4; Tris(Tetramethylcyclopentadienyl)Cerium(Iii)

该化合物是一种有机金属化合物,其成分为,是一种稀土元素,与三种四甲基环戊基离心体相协调.该化合物的特点是其独特的结构,其中四甲基环戊基环乙酰聚二烯基团在中心周围提供消毒保护,影响其再活性和稳定性.它通常表现出一种亮色,表明其电子结构,并且可溶于有机溶剂中,使之适合于有机合成和材料科学的各种应用.由于有中心的存在,因此可以进行有趣的红氧化学,可在催化和新材料的开发中加以利用.此外,该化合物的稳定性和再活性可能受到温度和其他化学物种的存在等因素的影响.

结构式图片

上下游产品

cerium chloride cerium(III) chloride

合成工艺路线路线简述

    海关参考信息

    专利信息


    专利号:US-10954139-B2
    优先权日:2015-12-11
    标 题:Oleophilic foams for oil spill mitigation
    发明人:DARLING SETH B; ELAM JEFFREY W; MANE ANIL U
    权利人:UCHICAGO ARGONNE LLC
    摘要:A method of fabricating an oleophilic foam includes providing a foam comprising a base material. The base material is coated with an inorganic material using at least one of an atomic layer deposition (ALD), a molecular layer deposition (MLD) or sequential infiltration synthesis (SIS) process. The SIS process includes at least one cycle of exposing the foam to a first metal precursor for a first predetermined time and a first partial pressure. The first metal precursor infiltrates at least a portion of the base material and binds with the base material. The foam is exposed to a second co-reactant precursor for a second predetermined time and a second partial pressure. The second co-reactant precursor reacts with the first metal precursor, thereby forming the inorganic material on the base material. The inorganic material infiltrating at least the portion of the base material. The inorganic material is functionalized with an oleophilic material.

    专利号:US-11351478-B2
    优先权日:2018-09-06
    标题 :Oil skimmer with oleophilic coating
    发明人:DARLING SETH B; ELAM JEFFREY W
    权利人:UCHICAGO ARGONNE LLC
    摘要:A method of fabricating an coating includes providing a coating comprising a base material. The base material is coated with an inorganic material using at least one of an atomic layer deposition (ALD), a molecular layer deposition (MLD), or sequential infiltration synthesis (SIS) process. The SIS process includes at least one cycle of exposing the coating to a first metal precursor for a first predetermined time and a first partial pressure. The first metal precursor infiltrates at least a portion of the base material and binds with the base material. The coating is exposed to a second co-reactant precursor for a second predetermined time and a second partial pressure. The second co-reactant precursor reacts with the first metal precursor, thereby forming the inorganic material on the base material. The inorganic material infiltrating at least the portion of the base material. The inorganic material is functionalized with a material.

    专利号:US-10870917-B2
    优先权日:2016-07-08
    标 题:Functionalized foams
    发明人:DARLING SETH B; ELAM JEFFREY W; MANE ANIL U; SNYDER SETH W
    权利人:UCHICAGO ARGONNE LLC
    摘要:A method of fabricating an foam includes providing a foam comprising a base material. The base material is coated with an inorganic material using at least one of an atomic layer deposition (ALD), a molecular layer deposition (MLD), or sequential infiltration synthesis (SIS) process. The SIS process includes at least one cycle of exposing the foam to a first metal precursor for a first predetermined time and a first partial pressure. The first metal precursor infiltrates at least a portion of the base material and binds with the base material. The foam is exposed to a second co-reactant precursor for a second predetermined time and a second partial pressure. The second co-reactant precursor reacts with the first metal precursor, thereby forming the inorganic material on the base material. The inorganic material infiltrating at least the portion of the base material. The inorganic material is functionalized with a material.

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    ✅ COA系统入驻 | 共享模式

    合成参考文献

    合成方法参考DOI号:10.1021/ic061485g
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